Cascade Polyketide and Polyene Cyclizations: Biomimetic Total Synthesis of Hongoquercin B
2014
Barrett, Tim N. | Barrett, Anthony G. M.
The total synthesis of hongoquercin B was carried out in 9 steps from trans,trans-farnesyl acetate using a palladium catalyzed decarboxylative π-farnesyl rearrangement of a diketo-dioxinone ester, aromatization and cationic diene-epoxide cyclization as key steps. This cascade tetracyclization simplifies the synthesis of terpenoid resorcylate natural products.
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书目信息
Journal of the American Chemical Society
卷
136
期
49
页码
17013
- 17015
ISSN
1520-5126
出版者
American Chemical Society
语言
英语
类型
Journal Article; Text
2024-02-28
MODS