Aromaticity can enhance the reactivity of P-donor/borole frustrated Lewis pairs
2019
Cabrera-Trujillo, Jorge Juan | Fernández, Israel
Geminal frustrated Lewis pairs (FLPs) having a borole fragment as the Lewis acid partner constitute really promising candidates to achieve facile small molecule activation reactions. The predicted enhanced reactivity of these species, as compared to more traditional FLPs, finds its origin in the loss of the antiaromatic character of the borole moiety along the reaction coordinate.
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书目信息
出版者
The Royal Society of Chemistry
其它主题
Moieties; Lewis acids
语言
英语
类型
Journal Article; Text
2024-02-28
MODS