Mechanism and origins of the directing group-controlled endo- versus exo-selectivity of iridium-catalysed intramolecular hydroalkenylation of 1,1-disubstituted alkenes
2018
Lang, Yanmin | Zhang, Mei | Cao, Yang | Huang, Genping
Density functional theory calculations were performed to investigate the iridium-catalysed intramolecular hydroalkenylation of 1,1-disubstituted alkenes. The detailed reaction mechanism is established, and the important role of directing groups in determining the experimentally observed endo- versus exo-selectivity is well rationalized by our calculations.
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书目信息
出版者
The Royal Society of Chemistry
其它主题
Alkenes; Density functional theory; Reaction mechanisms
语言
英语
类型
Journal Article; Text
2024-02-28
MODS