Hybrid membrane with controllable surface microroughness by micro-nano structure processing for diluted PM2.5 capture
2020
Liao, Juan | Zhang, Yi | Yang, Huaming
Tremendous efforts have been devoted by researchers on air particulate matter pollution for the increasing harm, however, the Air Pollution Index (API) from “good” to “excellent” is something hard to achieve. Here, halloysite nanotubes/polyvinyl alcohol (HNTs/PVA) hybrid membrane with surface micro-nano structure processing using a one-step method for efficient PM₂.₅ capture was prepared. The filtration efficiency is 45.35% and the pressure drop is 41.57 Pa of composite membrane with a 60 wt% halloysite dosage. Specially, it resulted in a relatively safer PM index value of about 16.54, which tends to be more stringent than the restriction by Government of China (PM₂.₅ < 35 μg/m³). The filtration performance was mainly attributed to the controllable microroughness surface as well as the hierarchical structure constructed by one-step method, which has a functional role in obstruction and adsorption for diluted PM₂.₅. The methodology can employ halloysite onto various polymers, like polyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP), polyacrylonitrile (PAN) and also polycaprolactone (PCL) to yield hybrid membranes with the similar modification of surface and structure. Such versatile membrane filters can be purposely designed and scaled up, which endows the existing hybrid membrane with great potentials in both residential and public areas pollution control to achieve a healthier living environment.
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