Synthesis of novel nonlinear optical chromophore containing bis(trifluoromethyl)benzene as an isolated group

Wang, Liang; Liu, Jialei; Bo, Shuhui; Zhen, Zhen; Liu, Xinhou

Synthesis of novel nonlinear optical chromophore containing bis(trifluoromethyl)benzene as an isolated group

2012

Wang, Liang | Liu, Jialei | Bo, Shuhui | Zhen, Zhen | Liu, Xinhou

Novel NLO chromophore with 3, 5-bis(trifluoromethyl) benzoyl as the isolated group in electron bridge was prepared for investigating the NLO character. Chromophore FTC-wl was characterized using UV–Visible spectra, nuclear magnetic resonance, and mass spectrometry and showed us excellent thermal stability. EO films prepared by poly(bisphenol A carbonate) polymer doped with this chromophore at different content had been poled to afford the highest electro optic coefficients (r₃₃) of 28pm/V.

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