Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Qurban, Jihan; Elsherbini, Mohamed; Wirth, Thomas

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

2017

Qurban, Jihan | Elsherbini, Mohamed | Wirth, Thomas

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

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