Ferrocene tagged functional polymer: a robust solid-phase reagent for O-demethylation

Kurane, Rajanikant; Gaikwad, Vipul; Jadhav, Jagannath; Salunkhe, Rajashri; Rashinkar, Gajanan

Ferrocene tagged functional polymer: a robust solid-phase reagent for O-demethylation

2012

Kurane, Rajanikant | Gaikwad, Vipul | Jadhav, Jagannath | Salunkhe, Rajashri | Rashinkar, Gajanan

Ferrocene tagged functional polymer was synthesized by exploiting the propensity of the Merrifield resin to undergo quaternization with N-ferrocenylmethyl benzimidazole followed by subsequent anion metathesis reaction. The synthesized polymer when employed as a solid-phase reagent for O-demethylation of aryl methyl ethers, showed TON in the range of 7373–8930 and TOF in the range of 279–494h⁻¹.

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