Catalytic C–C bond cleavage and C–Si bond formation in the reaction of RCN with Et₃SiH promoted by an iron complex

Nakazawa, Hiroshi; Kamata, Kouji; Itazaki, Masumi

Catalytic C–C bond cleavage and C–Si bond formation in the reaction of RCN with Et₃SiH promoted by an iron complex

2005

Nakazawa, Hiroshi | Kamata, Kouji | Itazaki, Masumi

Catalytic C–C bond cleavage of acetonitrile and C–Si bond formation have been attained in the photoreaction of MeCN with Et₃SiH in the presence of an iron complex, Cp(CO)₂FeMe. This catalytic system can be applied for arylnitrile C–C bond cleavage.

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