The first biosynthetic studies of the azinomycins: acetate incorporation into azinomycin B

Corre, Christophe; Lowden, Philip A. S.

The first biosynthetic studies of the azinomycins: acetate incorporation into azinomycin B

2004

Corre, Christophe | Lowden, Philip A. S.

¹³C-Labelled acetate efficiently labels the antitumour natural product azinomycin B, revealing a polyketide origin for the naphthoate fragment, that threonine is the probable precursor of the enol fragment, and that α-ketoglutarate is a probable precursor of the aziridine fragment.

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