Palladium-Catalyzed Hiyama Coupling of Benzylic Ammonium Salts via C–N Bond Cleavage
2019
Han, Chunyu | Zhang, Zhenming | Xu, Silin | Wang, Kai | Chen, Kaiting | Zhao, Junfeng
The first palladium-catalyzed Hiyama cross-coupling of arylsilanes with benzyltrimethylammonium salts is reported. The reaction proceeds smoothly to facilitate C(sp²)–C(sp³) bond formation via cleavage of the C–N bond and provides a useful approach to various diarylmethanes with a broad substrate scope and excellent functional group tolerance in good to excellent yields.
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书目信息
出版者
American Chemical Society
其它主题
Organic chemistry; Chemical bonding; Cross-coupling reactions; Ammonium salts; Moieties; Cleavage (chemistry); Reaction mechanisms
语言
英语
类型
Journal Article; Text
2024-02-28
MODS