Synthesis and characterization of phosphorescent three-coordinate Cu(i)–NHC complexes

Krylova, Valentina A.; Djurovich, Peter I.; Whited, Matthew T.; Thompson, Mark E.

Synthesis and characterization of phosphorescent three-coordinate Cu(i)–NHC complexes

2010

Krylova, Valentina A. | Djurovich, Peter I. | Whited, Matthew T. | Thompson, Mark E.

Cationic and neutral monomeric three-coordinate phosphorescent Cu(i) complexes were synthesized and characterized by XRD analysis, electrochemistry and photophysical studies in different environments. DFT calculations have aided the assignment of the electronic structure and excited state behavior of these complexes.

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