Metal-Free Three-Component Oxyalkynylation of Alkenes
2018
Li, Yangshan | Lu, Ran | Sun, Shutao | Liu, Lei
An unprecedented (NH₄)₂S₂O₈ mediated metal-free three-component alkene oxyalkynylation using H₂O or alcohol as oxygenation agent is described. Mechanistic studies suggested that the reversed regioselectivity should be dictated by an alkene radical cation intermediate.
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书目信息
出版者
American Chemical Society
其它主题
Alkenes; Regioselectivity
语言
英语
类型
Journal Article; Text
2024-02-28
MODS