[Ru(η³-2-C₃H₄Me)(CO)(dppf)][SbF₆]: a mononuclear 16e⁻ ruthenium(ii) catalyst for propargylic substitution and isomerization of HCCCPh₂(OH)

Cadierno, Victorio; Díez, Josefina; García-Garrido, Sergio E.; Gimeno, José

[Ru(η³-2-C₃H₄Me)(CO)(dppf)][SbF₆]: a mononuclear 16e⁻ ruthenium(ii) catalyst for propargylic substitution and isomerization of HCCCPh₂(OH)

2004

Cadierno, Victorio | Díez, Josefina | García-Garrido, Sergio E. | Gimeno, José

The 16e⁻ derivative [Ru(η³-2-C₃H₄Me)(CO)(dppf)][SbF₆] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl-2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn-1-ol into 3,3-diphenyl-2-propenal.

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