Soil-soil solution distribution coefficients of global fallout 239Pu and 237Np in Japanese paddy soils
2022
Zheng, Jian | Tagami, Keiko | Uchida, Shigeo | Shibutani, Sanae | Ishida, Keisuke | Hamamoto, Takafumi
²³⁹Pu and ²³⁷Np are long-lived radionuclides that emit alpha rays, and once released into the environment, they are present there for a long period of time. Therefore,²³⁹Pu and ²³⁷Np are important radionuclides in the safety assessment related to geological disposal of radioactive waste because of the possibility of long-term exposure to humans. Mobilities of these radionuclides in the environment are of particular interest; therefore, in this study, we have made the first-time determination of the soil-soil solution distribution coefficient (Kd, L/kg) using global fallout ²³⁹Pu and ²³⁷Np in soil. The Kd values were determined by extracting these radionuclides from 23 soil samples using a laboratory batch method. The desorption Kd values of ²³⁹Pu were found to vary from 3.2 × 10³ to 1.4 × 10⁵ L/kg, and their geometric mean (GM) and arithmetic mean (AM) were 2.3 × 10⁴ L/kg and 3.2 × 10⁴ L/kg, respectively. The desorption Kd values of ²³⁷Np ranged from 8.9 × 10² to 2.1 × 10⁴ L/kg, and their GM and AM were 4.1 × 10³ L/kg and 6.4 × 10³ L/kg, respectively. A comparison between the obtained Kd values of ²³⁹Pu and ²³⁷Np indicated that the former were about 6-fold higher than the latter in Japanese paddy field soils. Pearson's correlation analysis suggested that the main factors contributing to the sorption and desorption of Pu isotopes in Japanese paddy soils were related to the amounts of Fe and Mn oxides, while the sorption and desorption of ²³⁷Np in them would be controlled by an ion-exchange reaction, and/or complex-formation with organic matter, especially in Fluvisols.
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