Microemulsion-mediated preparation of Ce2(MoO4)3 nanoparticles for photocatalytic degradation of crystal violet in aqueous solution
2020
Dargahi, Maryam | Masteri-Farahani, Majid | Shahsavarifar, Samaneh | Feizi, Marzieh
Preparation of Ce₂(MoO₄)₃ nanoparticles is reported via the microemulsion method by using two different surfactants, i.e., cationic surfactant, cetyltrimethylammonium bromide (CTAB), and nonionic surfactant, Triton X-100. The water pools produced in the microemulsion systems behave as nanoreactors for reaction of the cerium (3+) and molybdate ions to produce Ce₂(MoO₄)₃ nanoparticles. The structure and morphology of the products were characterized by using Fourier-transform infrared (FT-IR) spectroscopy, energy-dispersive X-ray analysis (EDX), UV-Vis spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA-DTA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The prepared Ce₂(MoO₄)₃ nanoparticles were successfully utilized as photocatalysts to remove crystal violet from aqueous solution in which the maximum percentage of dye degradation was about 89% after 5 h under the visible light irradiation. Also, kinetic study of the photocatalytic degradation revealed that pseudo-second order model is the best one for describing kinetic of the reaction.
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