Improvement of desulfurization efficiency of Al-rich ladle furnace refining slag with an aqueous carbonation method by hydrothermal or ultrasound pretreatment
2021
Huang, Yi | Zeng, Zhiqiang
Ladle furnace (LF) slag is a type of steel slag, which has limited applications due to its high S content. Aqueous carbonation is a prospective method for desulfurization of the LF slag. However, the Al-rich LF raw slag has very low desulfurization efficiency with carbonation method. This study investigated the improvement of desulfurization efficiency of the Al-rich LF slag with carbonation method by hydrothermal (HP) or ultrasound pretreatment (UP). The results showed that C₃AHX was formed in pretreated slags because of C₁₂A₇ hydration, which could remove part of S. After carbonation, most of the C₃AHX in pretreated slags produced crystalline CaCO₃ bonded by amorphous Al(OH)₃ (the other reaction product) in 10 min. In the carbonation process, S removal was mainly determined by carbonation efficiency. The S content was reduced to about 0.40% for the pretreated slags from 1.04% in the raw slag. By contrast, the S content was reduced to only 0.93% for slag without pretreatment under the same carbonation conditions. The possible reason of the improvement of desulfurization efficiency by HP or UP was the formation of thin plate–like C₃AHₓ, which increased the surface area available for carbonation reaction. The UP slag presented slightly lower S content than the HP slag because high ultrasound energy increased the reactivity of Ca₂SiO₄.
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