Copper-Catalyzed Oxidative Alkynylation of Diaryl Imines with Terminal Alkynes: A Facile Synthesis of Ynimines
2012
Laouiti, Anouar | Rammah, Mohamed M. | Rammah, Mohamed B. | Marrot, Jérome | Couty, François | Evano, Gwilherm
An efficient copper-mediated method for the oxidative alkynylation of diaryl imines with terminal alkynes is reported. This reaction provides the first catalytic and general synthesis of ynimines and allows for an easy preparation of these useful building blocks. An improved copper-catalyzed oxidative dimerization of imines to azines and the synthesis of dienes and azadienes from ynimines are also described.
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书目信息
出版者
Nature Publishing Group
其它主题
Alkynes; Dimerization; Imines
语言
英语
类型
Journal Article; Text
2024-02-29
MODS