Asymmetric Synthesis and Sensory Evaluation of Sedanenolide
2011
OGURO, Daichi | WATANABE, Hidenori
The synthesis and sensory evaluation of enantiomeric sets of sedanenolide (1) and 3-butylphthalide (3) are described. The asymmetric synthesis was achieved via the intramolecular Diels-Alder reaction of chiral propargylester (5) which was prepared from optically active propargyl alcohol (4) and 2,4-pentadienoic acid. The sensory evaluation of these enantiomers revealed that there were distinct differences between their aroma character and odor threshold.
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书目信息
出版者
The Royal Society of Chemistry
其它主题
3-butylphthalide; Stereoselective synthesis; Sedanenolide; Enantiomers; Odors; Cycloaddition reactions
语言
英语
注释
Nal-ap-2-clean
类型
Journal Article; Text
2024-02-29
MODS