A Specific Nucleophilic Ring-Opening Reaction of Aziridines as a Unique Platform for the Construction of Hydrogen Polysulfides Sensors
2015
Chen, Wei | Rosser, Ethan W. | Zhang, Di | Shi, Wen | Li, Yilin | Dong, Wen-ji | Ma, Huimin | Hu, Dehong | Xian, Ming
A hydrogen polysulfide mediated aziridine ring-opening reaction was discovered. Based on this reaction, a novel H₂Sₙ-specific chemosensor (AP) was developed. AP showed high sensitivity and selectivity for H₂Sₙ. Notably, the fluorescent turn-on product (1) exhibited excellent two-photon photophysical properties, a large Stokes shift, and high solid state luminescent efficiency.
显示更多 [+] 显示较少 [-]AGROVOC关键词
书目信息
出版者
Elsevier Inc.
其它主题
Ethyleneimine; Hydrogen sulfide; Lewis bases
语言
英语
许可
//data.crossref.org/schemas/AccessIndicators.xsd:license_ref>http://purl.org/eprint/accessRights/OpenAccess | //data.crossref.org/schemas/AccessIndicators.xsd:program>//data.crossref.org/schemas/AccessIndicators.xsd:license_ref> | //data.crossref.org/schemas/AccessIndicators.xsd:program>
类型
Journal Article; Text
2024-02-29
MODS