Organocatalytic silyl transfer from silylborane to nitroalkenes for the synthesis of β-silyl nitroalkanes and β-silyl amines

Jiang, Chen-Ran; Zhao, Chun-Liang; Guo, Hui-Fang; He, Wei

Organocatalytic silyl transfer from silylborane to nitroalkenes for the synthesis of β-silyl nitroalkanes and β-silyl amines

2016

Jiang, Chen-Ran | Zhao, Chun-Liang | Guo, Hui-Fang | He, Wei

The silylation of a wide array of nitroalkenes is achieved by organocatalysts in yields up to 93%. The reaction is carried out in a toluene/water biphasic solvent under operationally simple conditions. Reduction of the nitro group provides efficient access to functionalized β-silyl amines.

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