The network of hydrogen bonding in kingite, as revealed by a neutron-diffraction investigation of its deuterated analogue, AL₃(PO₄)₂F₃·₇D₂O

Wallwork, K.; Pring, A.; Taylor, M.; Hunter, B.

The network of hydrogen bonding in kingite, as revealed by a neutron-diffraction investigation of its deuterated analogue, AL₃(PO₄)₂F₃·₇D₂O | The network of hydrogen bonding in kingite, as revealed by a neutron-diffraction investigation of its deuterated analogue, AL(3)(PO(4))(2)F(3)(.)(7)D(2)O

2004

Wallwork, K. | Pring, A. | Taylor, M. | Hunter, B.

The extensive hydrogen-bonding network of kingite is described for a specimen from Tom's Quarry, near Kapunda, South Australia. After deuteration, the triclinic structure was refined in space group P1̄, a 9.318(1), b 10.092(1), c 7.108(1) Å, α 97.61(1), β 100.56(1), γ 95.97(1)°, V 645.7(1) Å3, Z=2. The formula of this modified specimen of kingite, refined using neutron powder-diffraction data, has been established as Al3(PO4)2F3·7D2O. We were able to locate the three atoms of fluorine.

显示更多 [+]

Kia S. Wallwork, Allan Pring, Max R. Taylor and Brett A. Hunter

显示更多 [+]