The Limitation of the Combination of Transition State Theory and Thermodynamics for the Reactions of Proteins and Nucleic Acids
2021
Nobuo Shimamoto
When a reaction is accompanied by a change with the speed close to or slower than the reaction rate, a circulating reaction flow can exist among the reaction states in the macroscopic stationary state. If the accompanying change were at equilibrium in the timescale of the relevant reaction, the transition-state theory would hold to eliminate the flow.
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书目信息
Biomolecules
卷
12
期
1
页码
28
ISSN
2218-273X
出版者
MDPI AG
其它主题
Chemical ratchet; Reaction theory; Transition-state theory; Rate equation; Detailed balance
语言
英语
2024-12-11
DOAJ