Modeling of Phosphate Sorption Process on the Surface of Rockfos<sup>®</sup> Material Using Langmuir Isotherms
2024
Beata Zawadzka | Tadeusz Siwiec | Lidia Reczek | Michał Marzec | Krzysztof Jóźwiakowski
In this study, we aimed to develop a mathematical description of the process of phosphate sorption on Rockfos<sup>®</sup> material using the Langmuir isotherm and determine the basic parameters for modeling this process. The Rockfos<sup>®</sup> material was formed through the thermal treatment of opoka at 980 °C and is highly reactive due to its significant calcium and silicon compound content. This study included an evaluation of the phosphate retention efficiency on the material as a function of the phosphate concentration in the initial solution (0.5 mg/L, 1.0 mg/L, and 2.0 mg/L), sorbent grain size (1.0–1.6 mm, 1.6–2.5 mm, and 2.0–5.0 mm), and process temperature (5 °C, 10 °C, 15 °C, 20 °C, and 25 °C). It was found that an increase in the process temperature and the phosphate concentration in the solution favored sorption, while the effect of the sorbent grain size was ambiguous. It was determined that sorption can be described well using the Langmuir linearization of the Langmuir model. Thermodynamic analysis and the separation coefficient suggest that phosphorus sorption on Rockfos<sup>®</sup> material is primarily based on chemisorption, and the process is endothermic and spontaneous over the entire temperature range. The determined parameters of the tested material, especially the qmax (maximum sorption capacity), provide a basis for the design of a filter for removing phosphate from wastewater, assuming that the load is equal to the inflow to the filter and adheres to the specified requirements for treated wastewater.
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