Composition and origin of the aliphatic extractable hydrocarbons in the Puertollano (Spain) oil shale
1994
Río Andrade, José Carlos del | García Mollá, Joaquín | González-Vila, Francisco Javier | Martín Martínez, Francisco | Dirección General de Investigación Científica y Técnica, DGICT (España)
13 pages, 11 figures, 5 tables, 33 references.
显示更多 [+] 显示较少 [-]The composition of the saturated aliphatic fraction extractable from the Puertollano oil shale, the most important deposit of this material in the Iberian Peninsula, has been studied by GC and GC-MS. This fraction contained mainly n-alkanes, n-alkylcyclohexanes, and n-alkylmethylcyclohexanes. The cyclohexanes showed a distribution very similar to that of n-alkanes suggesting a common origin. Contributions from higher plant derived material (mainly conifers) were apparent, based on the presence of diterpenoid compounds. An angiosperm contribution was evidenced by the presence of des-A-triterpenoid hydrocarbons, derived from oleanane and ursane skeletons. Hopanes, 8,14-secohopanes, ring-D aromatized 8,14-secohopanes, benzohopanes, a Ca 17,21-secobopane and a C3~ hexacyclic saturated hopane were found in the extracts, showing the influence of microorganisms. Different pathways are suggested for the formation of benzobopanes, and the C3~ hexacyclic bopanoid found in the extracts.
显示更多 [+] 显示较少 [-]The authors wish to thank the DGICyT (PB87-0277) for financial support.
显示更多 [+] 显示较少 [-]Peer reviewed
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