Relating mineral-organic matter stabilization mechanisms to carbon quality and age distributions using ramped thermal analysis

24 páginas.- 4 figuras.- 2 tablas.- 118 referencias.- Electronic supplementary material is available online at https://doi.org/10.6084/m9.figshare.c.6845635. .- This article is part of the Theo Murphy meeting issue ‘Radiocarbon in the Anthropocene’.

Organic carbon (OC) association with soil minerals stabilizes OC on timescales reflecting the strength of mineral–C interactions. We applied ramped thermal oxidation to subsoil B horizons with different mineral–C associations to separate OC according to increasing temperature of oxidation, i.e. thermal activation energy. Generally, OC released at lower temperatures was richer in bioavailable forms like polysaccharides, while OC released at higher temperatures was more aromatic. Organic carbon associated with pedogenic oxides was released at lower temperatures and had a narrow range of 14C content. By contrast, N-rich compounds were released at higher temperatures from samples with 2 : 1 clays and short-range ordered (SRO) amorphous minerals. Temperatures of release overlapped for SRO minerals and crystalline oxides, although the mean age of OC released was older for the SRO. In soils with more mixed mineralogy, the added presence of older OC released at temperatures greater than 450°C from clays resulted in a broader distribution of OC ages within the sample, especially for soils rich in 2 : 1 layer expandable clays such as smectite. While pedogenic setting affects mineral stability and absolute OC age, mineralogy controls the structure of OC age distribution within a sample, which may provide insight into model structures and OC dynamics under changing conditions.

Open access funding provided by the Max Planck Society. Open Access funding enabled and organized by Projekt DEAL. This research has been supported by the Max Planck Institute for Biogeochemistry and the European Research Council (Horizon 2020 Research and Innovation Programme, Grant Agreement no. 695101).

Peer reviewed