The Content and Risk Assessment of Heavy Metals and Sulfur Dioxide in Herbs for Food and Medicine in Seoul Area (2019-2023)
2024
Han, S.H. | Park, S.H. | Kim, J.H. | Jang, H.J. | Kim, A.K. | Jung, J.H. | Yun, E.S. | Park, J.S.
This study investigated the content of heavy metals (Pb, Cd, As, and Hg) and SO₂ and conducted a risk assessment of 1,340 samples of 60 herbs used for food and medicine in Seoul between 2019 and 2023. The analysis was performed using inductively coupled plasma mass spectrometry (ICP-MS), a mercury analyzer, and the Monier–Williams method. The mean values and ranges of the heavy metals were as follows: Pb, 0.327 mg/kg (not detectable [ND]–36.933); Cd, 0.083 mg/kg (ND–1.700); As, 0.075 mg/kg (ND–2.200); and Hg, 0.004 mg/kg (ND–0.047). Pb exceeded the permissible limit of 36.933 mg/kg in one sample of Poria Sclerotium. Cd exceeded the permissible limit of 1.700 mg/kg and 0.650 mg/kg in the two samples of Chrysanthemi Zawadskii Herba. The mean and range of SO₂ was 0.75 mg/kg (ND–192.00), with two samples of Gastrodiae Rhizoma exceeding the permissible limit at 192.00 mg/kg and 42.00 mg/kg. Pb was highest in the perithecium (1.377 mg/kg), followed by Cd in the cortex (0.156 mg/kg) and caulis (0.144 mg/kg), As in leaves (0.149 mg/kg), and Hg in the herba (0.009 mg/kg) and leaves (0.009 mg/kg). SO₂ was the highest in the rhizomes (4.12 mg/kg). The Pb, Cd, and Hg levels did not differ significantly between the domestic, Chinese, and imported products; however, As and SO₂ levels were the highest in the Chinese products. As a result of the risk assessment, all the margins of exposure (MOE) values of Pb, except for Poria Sclerotium, were ≥1, indicating that most samples were safe. The hazard index (HI) for Cd, As, and Hg were <100%, indicating a safety level for food and medicine. In addition, the HI for SO₂ did not exceed 1 for any of the items, indicating safe levels.
显示更多 [+] 显示较少 [-]