Cyano-Substituted Oligo(p-phenylene vinylene) Derivatives with Aggregation-Induced Enhanced Emissions and Mechanofluorochromic Luminescence
2024
Xinju Zhu | Yaru Pan | Xinran Zhao | Yu Yuan | Zewen Zhai | Xiaoni Yu | Wenjing Zhang | Yuanyuan Chang | Bing Song | Linlin Shi | Xinqi Hao
Developing red fluorescence emitters with simple structures via convenient synthetic routes is highly desirable yet challenging. Herein, two novel donor&ndash:acceptor-type red emitters, DCFOPV-TPA and SCFOPV-TPA, featuring the intramolecular charge transfer effect were designed by integrating triphenylamine and trifluoromethyl into a CN-substituted oligo(p-phenylene vinylene) backbone. Both chromophores exhibited aggregation-induced enhanced emission and solvatochromic behavior. Moreover, DCFOPV-TPA also displayed reversible mechanofluorochromic properties under external force.
显示更多 [+] 显示较少 [-]