In Nigeria irrigated agriculture is an important tool for economic growth, food security, and poverty reduction during dry periods of rain-fed agriculture. The concentration and composition of dissolved constituents in water determines its quality for irrigation use. Water quality studies strongly suggest that agriculture is a leading source of water quality problems, due to pesticides and other agro-inputs, widely used by farmers to improve agricultural productivity. Poor quality irrigation water would therefore obviously affect soil quality and crop productivity. This study was carried out in 2015 to assess the presence of metals and physical properties of water, used for irrigation in Kwara state, Nigeria. Samples were randomly collected from thirty irrigation sources in three senatorial zones of Kwara State. The samples were analyzed for the presence of metals and water quality parameters, using standard procedures. Results showed that the highest concentration of Sulphate (7.0mg/L), Nitrate (8.9mg/L), Sodium (31.6mg/L), Calcium (3.1mg/L), and Magnesium (0.7) ions were within acceptable limits. The Sodium Adsorption Ratio, an indicator for water suitability in agricultural irrigation as well as a standard diagnostic parameter for the sodicity hazard of a soil, was significantly the highest (22.7) in Kwara North. Results of the study point to the need for an effective irrigation water quality assessment to curb nonpoint source pollution that could be caused by improper use of chemicals and pesticides by farmers.