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Source apportionment and human health risk assessment of trace metals and metalloids in surface soils of the Mugan Plain, the Republic of Azerbaijan
2021
Han, Junho | Lee, Seoyeon | Mămmădov, Zaman | Kim, Minhee | Mammadov, Garib | Ro, Hee-Myong
The Mugan Plain is the most productive area in the Republic of Azerbaijan, but a previous study confirmed trace metal and metalloid (TM&M) contamination with Cr, Ni and Pb, and the potential ecological risk of As was estimated. However, no industrial activity was previously reported in this area; thus, a source apportionment model using positive matrix factorization (PMF) was employed to identify pollution sources, and a human health risk assessment was conducted to evaluate noncarcinogenic and carcinogenic risks. Surface soil samples were collected from 349 sites, and six major elements (Si, Ca, Cl, P, S and Sr) and 8 TM&Ms (As, Cd, Cr, Co, Cu, Ni, Pb and Zn) were analyzed by X-ray fluorescence and employed for further apportionment and risk assessment. As a result, the PMF model showed 7 factors, assigned to natural activity (12.9%), dry riverbed (13.6%), surface accumulation (3.1%), desalinization activity (3.2%), residential activity (12.3%), fossil fuel combustion (35.5%) and agricultural activity (19.3%). The PMF model characterized certain areas with desalinization activity in the previous Soviet period and with surface accumulation of salt, and these findings were confirmed by additional field surveys and historical Landsat satellite images. The risk assessment results showed that there was no risk for the adults, while for children, there was a noncarcinogenic risk, but no carcinogenic risk. Dermal contact was estimated to be the primary pathway, and Ni and As were identified as the most problematic TM&Ms for noncarcinogenic and carcinogenic risks, respectively. According to the results, fossil fuel combustion associated with heating and vehicle transportation was estimated to be the main source of pollution, contributing 42.6% of the noncarcinogenic and 48.0% of the carcinogenic risks. These results can provide scientific guidance to understand and prevent the risk of TM&Ms on the Mugan Plain.
显示更多 [+] 显示较少 [-]HCH and lindane contaminated sites: European and global need for a permanent solution for a long-time neglected issue
2019
Vijgen, John | de Borst, Bram | Weber, Roland | Stobiecki, Tomasz | Forter, Martin
During the last 70 years 1, 2, 3, 4, 5, 6-Hexachlorocyclohexane (HCH) has been one of the most extensively used pesticides. Only the gamma-isomer has insecticidal properties. For the marketing of gamma-HCH (lindane) the other 85% HCH isomers which are formed as by-products during HCH production had to be separated and became finally hazardous waste. For each tonne of lindane 8–12 tonnes of waste HCH isomers were produced and production of the approximately 600,000 t of lindane has therefore generated 4.8 to 7.2 million tonnes of HCH/POPs waste. These waste isomers were mostly buried in uncontrolled dumps at many sites around the world. The stockpiles and the large contaminated sites can be categorized as “mega-sites”. Countries with HCH legacy problems include Albania, Argentina, Austria, Azerbaijan, Brazil, China, Croatia, Czech Republic, France, Germany, Hungary, India, Italy, Japan, Macedonia, Nigeria, Poland, Romania, Russia, Slovakia, South Africa, Spain, Switzerland, Turkey, The Netherlands, UK, Ukraine and the USA.As lindane and alpha- and beta-HCH have been listed as POPs in the Stockholm Convention since August 2010, the problem of stockpiles of HCH waste is now documented and globally acknowledged.This article describes briefly the legacy of HCH and lindane that has been created. Three of the mega-sites are being discussed and demonstrate the increase in pollution footprint over time. Recent developments in the EU (including the Sabinanigo project in Aragon/Spain) and on a global level are presented. A short overview is given on lack of activities and on actions of countries within their obligations as Parties of the Stockholm Convention. Furthermore, current country activities supported by the Global Environment Facility (GEF), the “financing mechanism” of the convention, are listed. Finally, conclusions and recommendations are formulated that will contribute to the solution of this problem over the next 25 years.
显示更多 [+] 显示较少 [-]The prevalence of toxic hotspots in former Soviet countries
2016
Sharov, P. O. (Petr O.) | Dowling, Russell | Gogishvili, Megi | Jones, Barbara | Caravanos, Jack | McCartor, Andrew | Kashdan, Zachary | Fuller, Richard
Using a global database of contaminated sites, toxic hotspots in eight former Soviet countries were analyzed to identify the prevalence, types and sources of toxic pollution, as well as their associated potential public health impacts. For this analysis, polluted sites in Armenia, Azerbaijan, Kazakhstan, Kyrgyzstan, Russia, Tajikistan, Ukraine, and Uzbekistan were compiled and analyzed. The levels of contamination of seven key pollutants were assessed in each country. 424 contaminated sites were identified using data from Blacksmith Institute. Pesticides, lead (Pb), radioactive metals, arsenic (As), mercury (Hg), chromium (Cr), and cadmium (Cd) were the most commonly identified key pollutants. Collectively, these sites pose health risks to an estimated 6.2 million residents. The existing data on toxic hotspots in former Soviet countries likely captures only a small percentage of actual contaminated sites, but suggests potentially severe public health consequences. Additional assessments are needed to understand the risks posed by toxic pollution in the region.
显示更多 [+] 显示较少 [-]Identifying the source of petroleum pollution in sediment cores of southwest of the Caspian Sea using chemical fingerprinting of aliphatic and alicyclic hydrocarbons
2017
Shirneshan, Golshan | Bakhtiari, Alireza Riyahi | Memariani, Mahmoud
In this study, the concentration and sources of aliphatic and petroleum markers were investigated in 105 samples of Anzali, Rezvanshahr and Astara cores from the southwest of Caspian Sea. Petroleum importation was diagnosed as a main source in most depths of cores by the results of unresolved complex mixture, carbon preference index and hopanes and steranes. From the chemical diagnostic parameters, petroleum inputs in sediment of cores were determined to be different during years and the sources of hydrocarbons in some sections differed than Anzali and Turkmenistan and Azerbaijan oils. Diagenic ratios in most sediments of upper and middle sections in Astara core were determined to be highly similar to those of Azerbaijan oil, while the presence of Turkmenistan and Anzali oils were detected in a few sections of Anzali and Rezvanshahr cores and only five layers of downer section in Anzali core, respectively.
显示更多 [+] 显示较少 [-]The impact of carbon pricing on international competitiveness in the case of Azerbaijan
2022
Mukhtarov, Shahriyar
This article examines the impact of carbon pricing on international competitiveness for Azerbaijan, utilizing different cointegration methods such as, ARDLBT, CCR, DOLS, and FMOLS to the data spanning from 2000 to 2019. The results of the various cointegration approaches are in line with each other. The estimation results revealed that domestic crude oil price as a proxy of carbon pricing has a positive and significant impact on the real effective exchange rate in Azerbaijan. This implies that a rise in domestic crude oil price raises the real effective exchange rate (appreciation of national currency). An increase in real effective exchange rate indicates a loss in international competitiveness. The study concludes that the Azerbaijani policymakers should implement carbon pricing measures (implicit) to decrease CO₂ emissions from energy heavy industries without harming the country's international competitiveness, as well as use more renewable energy in order to prevent higher pollution effects of fossil fuels.
显示更多 [+] 显示较少 [-]Comparison of concentrations of toxic elements in the hair of first-year students of RUDN University from different regions of the world: a cross-sectional study
2022
Galchenko, Alexey Vladimirovich | Sidorova, Elizaveta Ilinichna | Sherstneva, Anastasia Alekseevna | Skalny, Andrew Anatolevich | Lobanova, Julia Nikolaevna
Due to the development of the metallurgical and energy industries and the operation of incinerators, more and more environmental pollution is occurring. Toxic elements accumulate in the biosphere and affect the state of the population of the regions of large-scale production or the disposal of industrial waste. The main goal of this study was to compare the toxic elements hair composition in people from different regions of the world. The concentrations of toxic and potentially toxic elements (Al, As, Be, Cd, Hg, Pb, Sn) in 198 people, first-year students of People’s Friendship University of Russia, who arrived from different regions of the world, were measured with inductively coupled plasma mass spectrometry. Students were divided into 6 groups: from South and East Asia, from Latin America, from Arab countries, Central Asia and Afghanistan, from South and Central Africa, from Iran and Azerbaijan, and from Russia, Ukraine, and Moldova. Medians of the concentrations of elements in the hair in the general group were 5.8 μg/g for Al, 30 ng/g for As, 0.6 ng/g for Be, 9.0 ng/g for Cd, 0.11 μg/g for Hg, 0.24 μg/g for Pb, and 0.11 μg/g for Sn. All these values fall within the normal range. Students from Russia, Moldova, and Ukraine showed a significantly higher Sn content (0.28 μg/g) in their hair than subjects from other regions except for Latin America, p<0,05. Except for As, cases of exceeding their recommended concentrations in the hair were identified. However, the proportion of subjects with deviations in each group was not high — not more than 7%. In all regions, a positive correlation was found between Cd, Pb, and Sn, p<0.05, r>0.5 for all. Cases of exceeding the maximum permissible concentrations of various toxic elements in the hair were detected in people from all regions of the Earth included in the study. And although the overall picture of the content of toxic elements in the hair of students from all regions in our study does not look critical, the results of previous studies, as well as information about the total deterioration of the environmental situation throughout the Earth, necessitate further large-scale environmental studies.
显示更多 [+] 显示较少 [-]Distribution and origins of n-alkanes, hopanes, and steranes in rivers and marine sediments from Southwest Caspian coast, Iran: implications for identifying petroleum hydrocarbon inputs
2016
Shirneshan, Golshan | Bakhtiari, Alireza Riyahi | Memariani, Mahmoud
The occurrence of n-alkanes and biomarkers (hopane and sterane) in surface sediments from Southwestern coasts of Caspian Sea and 28 rivers arriving to this lake, determined with a gas chromatography–mass spectrometry method, was used to assess the impacts of anthropogenic activities in the studied area. The concentrations of total n-alkanes (Σ21 n-alkane) in costal and riverine sediments varied from 249.2 to 3899.5 and 56 to 1622.4 μg g⁻¹, respectively. An evaluation of the source diagnostic indices indicated that petroleum related sources (petrogenic) were mainly contributed to n-alkanes in costal and most riverine sediments. Only the hydrocarbons in sediment of 3 rivers were found to be mainly of biogenic origin. Principal component analysis using hopane diagnostic ratios in costal and riverine sediments, and Anzali, Turkmenistan, and Azerbaijan oils were used to identify the sources of hydrocarbons in sediments. It was indicated that the anthropogenic contributions in most of the costal sediment samples are dominated with inputs of oil spills from Turkmenistan and Azerbaijan countries.
显示更多 [+] 显示较少 [-]Panel estimation for renewable and non-renewable energy consumption, economic growth, CO2 emissions, the composite trade intensity, and financial openness of the commonwealth of independent states
2018
Rasoulinezhad, Ehsan | Saboori, Behnaz
This article investigates the long-run and causal linkages between economic growth, CO₂ emissions, renewable and non-renewable (fossil fuels) energy consumption, the Composite Trade Intensity (CTI) as a proxy for trade openness, and the Chinn-Ito index as a proxy for financial openness for a panel of the Commonwealth of Independent States (CIS) region including Armenia, Azerbaijan, Belarus, Georgia, Kazakhstan, Kyrgyzstan, Moldova, Russia, Tajikistan, Turkmenistan, Ukraine, and Uzbekistan over the period of 1992–2015. It is the first time that CTI and the Chinn-Ito indexes are used in an economic-pollution model. Employing three panel unit root tests, panel cointegration estimation methods (DOLS and FMOLS), and two panel causality tests, the main empirical results provided evidence for the bidirectional long-run relationship between all the variables in all 12 sampled countries except for economic growth-renewable energy use linkage. The findings of causality tests indicated that there is a unidirectional short-run panel causality running from economic growth, financial openness, and trade openness to CO₂ emissions and from fossil fuel energy consumption to renewable energy use.
显示更多 [+] 显示较少 [-]The legacy of persistent organic pollutants in Azerbaijan: an assessment of past use and current contamination
2013
Aliyeva, Gulchohra | Halsall, Crispin | Alasgarova, Khoshgadam | Avazova, Matanat | Ibrahimov, Yaqub | Aghayeva, Roya
Azerbaijan has a history of production and heavy use of organochlorine pesticides (OCPs) with use focused in the main agricultural lowland region centred on the Kur River. Using a number of data sources, including archived reports from several government ministries, we attempt to construct production and use inventories for dichlorodiphenyltrichloroethane (DDT) and HCHs and compare these to scientific estimates of production and use of these chemicals in the 1960s to the 1980s. Notable discrepancies are evident particularly for DDT, with Azeri government records indicating much higher use (147-fold) than that estimated by the international scientific community. Soil and river sediment data from the 1980s and 2000s are also presented. While it is recognised that analytical uncertainties remain high for these older data (generated by GC–ECD), there is some evidence to show a decline in concentrations for some OCPs over this period. Extremely high concentrations of OCPs are evident for soils sampled in the vicinity of obsolete pesticide storage sites (found in numerous locations around the agricultural lowlands) and these levels may pose a health risk to wildlife and humans. River sediment data indicate high levels of both OCPs and polychlorinated biphenyls (PCBs), particularly downstream of the confluence of the two main rivers, the Kur and Araz. Particle-bound annual fluxes from the Kur River into the Caspian Sea are estimated for PCBs and OCPs and these are likely to influence levels observed in local coastal sediments, with agreement between river sediment data generated in the early 2000s and coastal marine sediment data generated from separate studies. We recommend that monitoring efforts should focus on soils in agricultural areas and around pesticide storage and production facilities as these soils will continue to provide a source of POPs to the regional environment.
显示更多 [+] 显示较少 [-]Re-evaluating the environmental impacts of tourism: does EKC exist?
2019
Mikayilov, Jeyhun I. | Mukhtarov, Shahriyar | Mammadov, Jeyhun | Äzizov, Mayis
The study investigates the long-run impact of tourism development on ecological footprint by employing the time-varying coefficient cointegration approach (TVC), in addition to the conventional cointegration techniques in the case of Azerbaijan for the period of 1996–2014. Based on the TVC estimation results, the coefficient of tourism development, which is the income elasticity of environmental degradation, was found to be time invariant. The paper uses energy consumption, trade, urbanization, and institutional quality indicators as control explanatory variables. The estimation results revealed that trade and energy consumption have statistically significant and positive impact on ecological footprint, while the coefficients of the other explanatory variables were found to be insignificant. Both the conventional estimation methods and the TVC concluded that, for the relationship between ecological footprint and tourism development, the EKC hypothesis is not present in Azerbaijan. Policy implications for the resource-rich economies have been discussed.
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