Bio-based plastics have been developed as alternative materials to solve the energy crisis brought by plastic production, but their impacts on soil ecosystems (e.g. plant and microorganisms) remain largely unknown. Here, we conducted study on the impacts of polyethylene 2,5-furan-dicarboxylate (PEF), a new bio-based plastic, on the plant-soil ecosystem, with comparison of fossil-based plastic polyethylene terephthalate (PET). Our investigation showed that, after 21 days exposure to microplastics (MPs) at doses of 0.5%, 1% and 2%, both PEF and PET MPs inhibited the growth of lettuce, where chlorophyll was found to be the most sensitive index. According to the comprehensive stress resistance indicators, PET MPs showed more severe phytotoxicity than PEF MPs. Although both PEF and PET MPs could inhibit soil enzyme activities, PET MPs exhibited significantly reduction on the diversity of rhizosphere soil bacterial community and changed the relative abundance of dominant species. Our study gave insights into the effects of PEF and PET MPs on the plant-soil system, where bio-based PEF MPs showed more friendly interaction with plant and soil than fossil-based PET MPs. Our results provided scientific data for risk assessment and useful information for the prospective application of bio-based plastics.

If biodegradable plastics tackle the marine plastic pollution problem sufficiently remains questionable. To gain more insight in degradability, performance, and the impact of degradation on the toxicity, commercial bags made from two biodegradable plastics and one conventional plastic (PE) were exposed for 120 days in a mesocosm featuring benthic, pelagic, and littoral habitat simulations. Degradability was assessed as weight loss, and specimens were tested for toxicity using Paracentrotus lividus sea-urchin larvae after different exposure times. Both biodegradable bags showed degradation within 120 days, with the littoral simulation showing the highest and the pelagic simulation the lowest decay. Disregarding habitat, the home-compostable plastic showed higher marine degradation than the industrial-compostable material. The relevant initial toxicity of both biopolymers was lost within 7 days of exposure, pointing towards easily leachable chemical additives as its cause. Interestingly, littoral exposed specimens gained toxicity after 120 days, suggesting UV- induced modifications that increase biopolymer toxicity.

Bioplastics have emerged to minimize the ecological footprint of non-degradable plastics. However, the effect of their degradation in aquatic systems, including the interaction with toxic metals, is still unexplored. In this work, the influence of UV-aging on structure, chemistry, wettability, rigidity, and Hg-sorption of commercially available bioplastic (BIO)- and polyethylene (PE)-based films was studied. To mimetize the materials disposal in fresh-/saltwaters, non-saline/saline aqueous solutions were used in Hg-sorption studies. ATR-FTIR spectra revealed that the BIO film was a coblended starch/polyester-based material, whose microstructure, physicochemical, and mechanical properties changed after UV-aging to a higher extent than in PE film. AFM and kinetic modelling pointed out electrostatic interactions/complexation as the mechanisms involved in the increased Hg-sorption by the UV-aged BIO film. An increased salinity did not impair its Hg-sorption. Therefore, when disposed in aquatic systems, starch/polyester-based bioplastics can play a potential vector for amplifying Hg along the food chain.

Plastic pollution has become a serious transboundary challenge to nature and human health, with estimation of reports published — predicting a twofold increase in plastic waste by 2030. However, due to the COVID-19 pandemic, the excessive use of single-use plastics (including face masks, gloves and personal protective equipment) would possibly exacerbate such forecasts. The transition towards eco-friendly alternatives like bio-based plastics and new emerging sustainable technologies would be vital to deal with future pandemics, even though the use or consumption of plastics has greatly enhanced our quality of life; it is however critical to move towards bioplastics. We cannot deny the fact that bioplastics have some challenges and shortcomings, but still, it is an ideal option for opt. The circular economy is the need of the hour for waste management. Along with all these practices, individual accountability, corporate intervention and government policy are also needed to prevent us from moving from one crisis to the next. Only through cumulative efforts, we will be able to cope up with this problem. This article collected scattered information and data about accumulation of plastic during COVID-19 worldwide. Additionally, this paper illustrates the substitution of petroleum-based plastics with bio-based plastics. Different aspects are discussed, ranging from advantages to challenges in the way of bioplastics.

The dairy market is one of the most important sectors worldwide, and milk packaging contributes to over one-third of the global dairy packaging demand. The end of life of the disposable packages is a critical stage of their life cycle, as demonstrated by the fact that disposable bottles are one of the litter items that are most found on beach shores. The aim of this paper is to analyse the performance of bioplastic bottles compared to other alternatives currently in use in the milk packaging sector, using the life cycle assessment (LCA) methodology. Bio-compostable plastic can be a powerful means to create a circular economy for disposable items. A PLA-based bottle is compared to a PET bottle, a HDPE bottle, a multilayer carton, and a glass bottle. In the analysis, also secondary and tertiary packaging is included. The functional unit chosen is “the packaging needed to contain 1 L of ESL milk and to guarantee a shelf life of 30 days”. Two sensitivity analyses are also performed in order to assess the influence of the end-of-life stage on the total impact. The results show that, in accordance with the assumptions of an ideal scenario, bioplastic system has a better performance than fossil-based systems and multilayer carton in the categories of climate change, ozone depletion, human toxicity, freshwater eutrophication, particular matter, and land use. The recycling scenario strongly changes the impact of the glass packaging system in the considered categories.

Strategic valorization of readily available sugarcane bagasse (SB) is very important for waste management and sustainable biorefinery. Conventional SB pretreatment methods are ineffective to meet the requirement for industrial adaptation. Several past studies have highlighted different pretreatment procedures which are lacking environmentally benign characteristics and effective SB bioconversion. This article provides an in-depth review of a variety of environmentally acceptable thermochemical and biological pretreatment techniques for SB. Advancements in the conversion processes such as pyrolysis, liquefaction, gasification, cogeneration, lignin conversion, and cellulose conversion via fermentation processes are critically reviewed for the formation of an extensive array of industrially relevant products such as biofuels, bioelectricity, bioplastics, bio adsorbents, and organic acids. This article would provide comprehensive insights into several crucial aspects of thermochemical and biological conversion processes, including systematic perceptions and scientific developments for value-added products from SB valorization. Moreover, it would lead to determining efficient pretreatment and/or conversion processes for sustainable development of industrial-scale sugarcane-based biorefinery.

The increase in demand of fossil fuel uses for developmental activity and manufacturing of goods have resulted a huge emission of global warming gases (GWGs) in the atmosphere. Among all GWGs, CO₂ is the major contributor that inevitably causes global warming and climate change. Mitigation strategies like biological CO₂ capture through sequestration and their storage into biological organic form are used to minimize the concentration of atmospheric CO₂ with the goal to control climate change. Since increasing atmospheric CO₂ level supports microbial growth and productivity thus microbial-based CO₂ sequestration has remarkable advantages as compared to plant-based sequestration. This review focuses on CO₂ sequestration mechanism in bacteria through different carbon fixation pathways, involved enzymes, their role in calcite, and other environmentally friendly biomaterials such as biofuel, bioplastic, and biosurfactant.