Polycyclic aromatic hydrocarbons (PAHs) are formed by the incomplete combustion of fossil fuels and forest or biomass burning. PAHs undergo long-range atmospheric transport, as evidenced by in situ observations across the Arctic. However, monitored atmospheric concentrations of PAHs indicate that ambient PAH levels in the Arctic do not follow the declining trend of worldwide anthropogenic PAH emissions since the 2000s, suggesting missing sources of PAHs in the Arctic or other places across the Northern Hemisphere. To trace origins and causes for the increasing trend of PAHs in the Arctic, the present study reconstructed PAH emissions from forest fires in the northern boreal forest derived by combining forest carbon stocks and MODIS burned area. We examined the statistical relationships of forest biomass, MODIS burned area, emission factors, and combustion efficiency with different PAH congeners. These relationships were then employed to construct PAH emission inventories from forest biomass burning. We show that for some PAH congeners, for example, benzo[a]pyrene (BaP)—the forest-fire-induced air emissions are almost one order of magnitude higher than previous emission inventories in the Arctic. A global-scale atmospheric chemistry model, GEOS-Chem, was used to simulate air concentrations of BaP, a representative PAH congener primarily emitted from biomass burning, and to quantify the response of BaP to wildfires in the northern boreal forest. The results showed that BaP emissions from wildfires across the northern boreal forest region played a significant role in the contamination and interannual fluctuations of BaP in Arctic air. A source-tagging technique was applied in tracking the origins of BaP pollution from different northern boreal forest regions. We also show that the response of BaP pollution at different Arctic monitoring sites depends on the intensity of human activities.

Soil acidification has been expanding in many areas of Asia due to increasing reactive nitrogen (N) inputs and industrial activities. While the detrimental effects of acidification on forests have been extensively studied, less attention has been paid to grasslands, particularly alpine grasslands. In a soil pH manipulation experiment in the Qinghai-Tibet Plateau, we examined the effects of soil acidification on plant roots, which account for the major part of alpine plants.After three years of manipulation, soil pH decreased from 6.0 to 4.7 with the acid-addition gradient, accompanied by significant changes in the availability of soil nitrogen, phosphorus and cations. Plant composition shifted with the soil acidity, with graminoids replacing forbs. Differing from findings in forests, soil acidification in the alpine grassland increased root biomass by increasing the fraction of coarse roots and the production of fine roots, corresponding to enhanced sedge and grass biomass, respectively. In addition, litter decomposability decreased with altered root morphological and chemical traits, and soil acidification slowed root decomposition by reducing soil microbial activity and litter quality.Our results showed that acidification effect on root dynamics in our alpine grassland was significantly different from that in forests, and supported similar results obtained in limited studies in other grassland ecosystems. These results suggest an important role of root morphology in mediating root dynamics, and imply that soil acidification may lead to transient increase in soil carbon stock as root standing biomass and undecomposed root litter. These changes may reduce nutrient cycling and further constrain ecosystem productivity in nutrient-limiting alpine systems.

Condensed organic matters (COM) with black carbon-like structures are considered as long-term carbon sinks because of their high stability. It is difficult to distinguish COM from general organic matter by conventional chemical analysis, thus the contribution by and interaction mechanisms of organo-mineral complexes in COM stabilization are unclear and generally neglected. Molecular markers related to black carbon-like structures, such as benzene polycarboxylic acids (BPCAs), are promising tools for the qualitative and quantitative analysis of COM. In this study, one natural soil and two cultivated soils with 25 y- or 55 y-tillage activities were collected and the distribution characteristics of BPCAs were detected. All the investigated soils showed similar BPCA distribution pattern, and over 60% of BPCAs were detected in clay fraction. The extractable BPCA contents were substantially increased after mineral removal. The ratios of BPCA contents before and after mineral removal indicate the extent of COM-mineral particle interactions, and our results suggested that up to 73% COM were protected by mineral particles, and more stronger interactions were noted on clay than on silt. The initial cultivation dramatically decreased COM-clay interactions, and this interaction was recovered only slowly after 55-y cultivation. Kaolinite and muscovite are important for COM protection. But a possible negative correlation between BPCAs and reactive iron oxides of the cultivated soils suggested that iron may promote COM degradation when disturbed by tillage activities. This study provided a new angle to study the stabilization of COM and emphasized the importance of organo-mineral complexes for COM stabilization.

Climate Change solutions include CO₂ extraction from atmosphere and water with burial by living habitats in sediment/soil. Nowhere on the planet are blue carbon plants which carry out massive carbon extraction and permanent burial more intensely concentrated than in SE Asia. For the first time we make a national and total inventory of data to date for “blue carbon” buried from mangroves and seagrass and delineate the constraints. For an area across Southeast Asia of approximately 12,000,000 km², supporting mangrove forests (5,116,032 ha) and seagrass meadows (6,744,529 ha), we analyzed the region's current blue carbon stocks. This estimate was achieved by integrating the sum of estuarine in situ carbon stock measurements with the extent of mangroves and seagrass across each nation, then summed for the region. We found that mangroves ecosystems regionally supported the greater amount of organic carbon (3095.19Tg Cₒᵣg in 1st meter) over that of seagrass (1683.97 Tg Cₒᵣg in 1st meter), with corresponding stock densities ranging from 15 to 2205 Mg ha⁻¹ and 31.3 to 2450 Mg ha⁻¹ respectively, a likely underestimate for entire carbon including sediment depths. The largest carbon stocks are found within Indonesia, followed by the Philippines, Papua New Guinea, Myanmar, Malaysia, Thailand, Tropical China, Viet-Nam, and Cambodia. Compared to the blue carbon hotspot of tropical/subtropical Gulf of Mexico's total carbon stock (480.48 Tg Corg), Southeast Asia's greater mangrove–seagrass stock density appears a more intense Blue Carbon hotspot (4778.66 Tg Corg). All regional Southeast Asian nation states should assist in superior preservation and habitat restoration plus similar measures in the USA & Mexico for the Gulf of Mexico, as apparently these form two of the largest tropical carbon sinks within coastal waters. We hypothesize it is SE Asia's regionally unique oceanic–geologic conditions, placed squarely within the tropics, which are largely responsible for this blue carbon hotspot, that is, consistently high ambient light levels and year-long warm temperatures, together with consistently strong inflow of dissolved carbon dioxide and upwelling of nutrients across the shallow geological plates.

Global climate change has attracted worldwide attention. The ocean is the largest active carbon pool on the planet and plays an important role in global climate change. However, marine plastic pollution is getting increasingly serious due to the large consumption and mismanagement of global plastics. The impact of marine plastics on ecosystem responsible for the gas exchange and circulation of marine CO₂ may cause more greenhouse gas emissions. Consequently, in this paper, threats of marine microplastics to ocean carbon sequestration are discussed. Marine microplastics can 1) affect phytoplankton photosynthesis and growth; 2) have toxic effects on zooplankton and affect their development and reproduction; 3) affect marine biological pump; and 4) affect ocean carbon stock. Phytoplankton and zooplankton are the most important producer and consumer of the ocean. As such, clearly, further research should be needed to explore the potential scale and scope of this impact, and its underlying mechanisms.

The carbon stored as soil organic carbon (SOC) and tree biomass is typically the highest carbon pool of the forest and is impacted by degradation and deforestation. The impact of “C” stocks on climate change at different altitudes can have vital implications for the conservation and management of “C” sinks. This study was undertaken in subtropical belt of Tehri Garhwal, Uttarakhand, India, to understand the carbon-storing potential of Anogeissus latifolia tree and its soil properties in three altitudes, i.e., lower (LA: 790–824 m), middle (MA: 825–960 m), and upper (UA: 1168–1212 m), which provide fuel, fodder, and small timber for life support purposes. Results of the study suggested that soil moisture and pH increase with increasing depth and altitude, whereas SOC and soil nitrogen show reverse patterns. Moreover, bulk density (BD) does not follow any trend (i.e., BD increases with soil depth and altitude until 960 m and further decreases with an increase in altitude). Tree density, biomass, and carbon stock reported highest in MA compared with UA and LA because of dense forest and greater tree diameter. Looking into the soil carbon stock, nitrogen, C/N ratio (C/N: < 10), and climatic drivers supportive to microbial degradation, it is concluded that A. latifolia forest has played an important role in carbon reduction and mitigating climate change at regional and global levels. The study will help environmentalists, foresters, and policy-makers to stimulate the combined effect of degradation of forest species on climate change and socioeconomic development at regional and global scale.

The Loess Plateau is the largest apple cultivation region in the world. However, the role of rain-fed apple orchards as carbon sinks or sources, including the dynamic variation and influencing factors, are still unclear. In this study, the net ecosystem CO₂ exchange (NEE) was monitored by an eddy covariance (EC) system in Loess Plateau apple orchards during 2016–2017. The results demonstrated that the annual NEE was higher in 2016 (− 698.0 g C m⁻² year⁻¹) than in 2017 (− 554.0 g C m⁻² year⁻¹). Particularly, the amount of orchard CO₂ uptake was significantly greater in 2016 (− 772.0 g C m⁻²) than in 2017 (− 642.1 g C m⁻²) during the carbon sink period. This difference may be attributed to the higher NEE in 2016 compared to 2017 during the fast and slow growth periods. In addition, a higher daily NEE occurred to the higher air temperature (Tₐ), which promoted early sprouting in 2016 (− 3.91 g C m⁻² day⁻¹) compared to 2017 (− 2.86 g C m⁻² day⁻¹) during the fast growth period. The daily NEE in 2016 (− 2.59 g C m⁻² day⁻¹) was remarkably higher than that in 2017 (− 1.41 g C m⁻² day⁻¹) during the slow growth period, owing to the greater number of cloudy and rainy days and lower temperatures in 2017. Overall, the present study demonstrated the key role played by the amount of precipitation and temperature in regulating the NEE during the growth season and provided accurate quantitative information on the carbon budget in apple orchards. Graphical abstract

Rising global population would force farmers to amplify food production substantially in upcoming 3–4 decades. The easiest way to increase grain production is through expanding cropping area by clearing uncultivated land. This is attained by permitting deadly loss of carbon (C) stocks, jeopardizing ecosystem biodiversity and deteriorating environmental quality. We aim to propose key agronomical tactics, livestock management strategy and advance approaches for aquaculture to increase productivity and simultaneously reduce the environmental impacts of farming sector. For this, we considered three major sectors of farming, i.e. agriculture, fishery and dairy. We collected literatures stating approaches or technologies that could reduce GHG emission from these sectors. Thereafter, we synthesized strategies or options that are more feasible and accessible for inclusion in farm sector to reduce GHG emission. Having comprehensively reviewed several publications, we propose potential strategies to reduce GHG emission. Agronomic practices like crop diversification, reducing summer fallow, soil organic carbon sequestration, tillage and crop residue management and inclusion of N₂-fixing pulses in crop rotations are some of those. Livestock management through changing animals’ diets, optimal use of the gas produced from manures, frequent and complete manure removal from animal housing and aquaculture management strategies to improve fish health and improve feed conversion efficiency could reduce their GHG emission footprint too. Adapting of effective and economic practices GHG emission footprint reduction potential of farming sector could make farming sector a C neutral enterprise. To overcome the ecological, technological and institutional barriers, policy on trade, tax, grazing practice and GHG pricing should be implemented properly.

In recent years, climate change and carbon sinks have been widely studied by the academic community, and relevant research results have emerged in abundance. In this paper, a scientometric analysis of 747 academic works published between 1991 and 2018 related to climate change and carbon sinks is presented to characterize the intellectual landscape by identifying and revealing the basic characteristics, research power, intellectual base, research topic evolution, and research hotspots in this field. The results show that ① the number of publications in this field has increased rapidly and the field has become increasingly interdisciplinary; ② the most productive authors and institutions in this subject area are in the USA, China, Canada, Australia, and European countries, and the cooperation between these researchers is closer than other researchers in the field; ③ 11 of the 747 papers analyzed in this study have played a key role in the evolution of the field; and ④ in this paper, we divide research hotspots into three decade-long phases (1991–1999, 2000–2010, and 2011–present). Drought problems have attracted more and more attention from scholars. In the end, given the current trend of the studies, we conclude a list of research potentials of climate change and carbon sinks in the future. This paper presents an in-depth analysis of climate change and carbon sink research to better understand the global trends and directions that have emerged in this field over the past 28 years, which can also provide reference for future research in this field.

The purpose of this study was to assess the water quality and variations in stable carbon and nitrogen isotopes of particulate organic matter (δ¹³CPOM and δ¹⁵NPOM), as well as to evaluate the sources of carbon and nitrogen that contribute to the POM pools in lakes and reservoirs located in the water-receiving area of the Eastern Route of South-to-North Water Transfer Project (SNWTP) in Northern China. During each season from October 2013 to July 2014, samples of POM from 14 lakes and reservoirs in Northern China were collected. The lakes and reservoirs were meso-eutrophic with considerably high brackish ions (SO₄²⁻, 173 mg/L; Cl⁻, 296 mg/L) in Yangtze River lake, and high total nitrogen: total phosphorus ratio (averaged with 772) or dissolved inorganic nitrogen: soluble reactive phosphorus molar ratios (averaged with 1077) in mountainous reservoirs. The δ¹³CPOM, δ¹⁵NPOM, carbon to nitrogen (C/N) ratios showed significant seasonal variation, with ranges of − 32.5 to − 17.4‰, − 3.6 to 13.5‰, and 5.1–13.2, respectively, while they were hard to be distinguished among types of water sources. Principal component analysis (PCA) indicated that brackish ions, nutrients, and their molar ratios were the main factors influencing variations in δ¹³CPOM and δ¹⁵NPOM. δ¹³CPOM and C/N ratios suggested autochthonous primary production mainly contributed to POM during from April to October, while exogenous organic matter might mainly contribute these carbon pools in January. The low values of δ¹⁵NPOM (< 0‰) and negative correlation between δ¹⁵NPOM and TN suggested discharge of agricultural waste water (e.g., fertilizers, irrigation tailwater) in Bailanghe, Xinan, and Taihe Reservoir during the fertilization season, while higher values indicated domestic sewage input to waterbodies (e.g., Mishan, Gengjing, Donghai Reservoir). Our results suggested that the aquatic ecosystem in water-receiving area of SNWTP would be potentially affected by the inter-basin water diversion, and thus, ecosystem-based strategies were also presented accordingly.