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Endocrine disruptors : Status and regulatory aspects
1999
Basler, Armin | Lebsanft, Jörg
Numerous scientific publications have stirred a political debate about the impact of synthetic chemicals on the endocrine system of humans and animals. In an parliamentary inquiry, the Federal Government of Germany was requested to give its opinion on currently available information, to describe the measures taken so far and to outline the challenges for the future.The government’s reply — an abridged, translated version is published here — reviews crucial aspects of the present scientific debate. The main focus is on the critical examination of the request for immediate legal action (e.g. restricting the production or use of certain substances) to reduce exposure to endocrine disruptors. Furthermore, an overview is given on national and international measures taken so far to refine the assessment of the potential hazards emanating from these chemicals, to gain more insight into the underlying biological mechanisms and to improve the basis for targeted and adequate legal action.
显示更多 [+] 显示较少 [-]Identification of oxidized TNT metabolites in soil samples of a former ammunition plant
1999
Bruns-Nagel, Dirk | Schmidt, Torsten C. | Drzyzga, Oliver | Löw, Eberhard v | Steinbach, Klaus
Water extracts of soil samples of the former ammunition plant “Tanne” near Clausthal-Zellerfeld, Lower Saxony, Germany, were investigated for highly polar oxidized 2,4,6-trinitrotoluene (TNT) metabolites. 0.4 to 9.0 mg/kg dry soil 2,4,6-trinitrobenzoic acid (TNBA) and 5.8 to 544 mg/kg dry soil 2-amino-4,6-dinitrobenzoic acid (2-ADNBA) were found. In addition to the oxidized metabolites, TNT, 4- and 2-aminodinitrotoluene (4- and 2-ADNT), and 2,4-dinitrotoluene (2,4-DNT) were extractable with water. Most interestingly, in one sample, 2-ADNBA represented the main contaminant.The origin of the oxidized nitroaromatics is unknown at this time. They might be generated chemically or photochemically. Furthermore, a biological synthesis seems possible.
显示更多 [+] 显示较少 [-]Anthropogenic platinum fluxes: Quantification of sources and sinks, and outlook
1999
Helmers, Eckard | Kümmerer, Klaus
Employing the data available to date, anthropogenic Pt fluxes are calculated for Germany with special emphasis on the Pt emitted by cars equipped with catalytic converters. Pt fluxes are quantified using five different methods (street deposition, automobile emission rate, sewage sludges, atmospheric load, industrial consumption). During the first and the second methods, approx. 100 kg of emitted Pt are seen to result for both for the mid 1990’s. Up to the year 2018, a total of 2100 kg of Pt will be emitted by cars equipped with catalytic converters. The diffuse atmospheric Pt deposition amounts to 0.73 – 4.4 μg/m²y or 260 kg Pt/year. Industrial sources emitting Pt into the atmosphere are likely but difficult to quantify. The enrichment of Pt in soils during agriculture fertilization with sewage sludges and during diffuse atmospheric deposition result in a level of 46 – 460 ng/kg up to the year 2018. Although this is slightly below the geogenic background, a comparison with the pollution history of Pb implies that forthcoming environmental Pt enrichment should not be neglected.
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