This study investigates changes in air quality conditions during the restricted COVID-19 lockdown period in 2020 across 21 metropolitan areas in the Middle East and how these relate to surface urban heat island (SUHI) characteristics. Based on satellite observations of atmospheric gases from Sentinel-5, results indicate significant reductions in the levels of atmospheric pollutants, particularly nitrogen dioxide (NO₂), sulfur dioxide (SO₂), and carbon monoxide (CO). Air quality improved significantly during the middle phases of the lockdown (April and May), especially in small metropolitan cities like Amman, Beirut, and Jeddah, while it was less significant in “mega” cities like Cairo, Tehran, and Istanbul. For example, the concentrations of NO₂ in Amman, Beirut, and Jeddah decreased by −56.6%, −43.4%, and −32.3%, respectively, during April 2020, compared to April 2019. Rather, there was a small decrease in NO₂ levels in megacities like Tehran (−0.9%) and Cairo (−3.1%). Notably, during the lockdown period, there was a decrease in the mean intensity of nighttime SUHI, while the mean intensity of daytime SUHI experienced either an increase or a slight decrease across these locations. Together with the Gulf metropolitans (e.g. Kuwait, Dubai, and Muscat), the megacities (e.g. Tehran, Ankara, and Istanbul) exhibited anomalous increases in the intensity of daytime SUHI, which may exceed 2 °C. Statistical relationships were established to explore the association between changes in the mean intensity and the hotspot area in each metropolitan location during the lockdown. The findings indicate that the mean intensity of SUHI and the spatial extension of hotspot areas within each metropolitan had a statistically significant negative relationship, with Pearson's r values generally exceeding - 0.55, especially for daytime SUHI. This negative dependency was evident for both daytime and nighttime SUHI during all months of the lockdown. Our findings demonstrate that the decrease in primary pollutant levels during the lockdown contributed to the decrease in the intensity of nighttime SUHIs in the Middle East, especially in April and May. Changes in the characteristics of SUHIs during the lockdown period should be interpreted in the context of long-term climate change, rather than just the consequence of restrictive measures. This is simply because short-term air quality improvements were insufficient to generate meaningful changes in the region's urban climate.

Polycyclic aromatic hydrocarbons (PAHs) are a byproduct of combustion processes. They are common pollutants in oil-producing countries because fossil fuel processing generates PAHs that associate with dust. Airborne particles containing PAHs are transported into houses during dust storms, which are common in the arid oil-producing countries, and consequently the children and adults in the household are exposed to PAHs in indoor house dust. The goal of this study was to present a systematic survey of PAHs in indoor house dust in Kuwait. The PAHs concentrations and composition of indoor house dust was determined, along with their probable source and the potential carcinogenic risks. Total PAHs concentrations (ƩPAH) were, on average (±standard deviation) 1112 ± 347 μg/kg and ranged from 450 to 2242 μg/kg. Heavier congeners (4–6 ring PAHs) represented 61% of the ƩPAH. Petroleum combustion and traffic emissions were the major source of PAHs, based on the isomeric ratios of PAHs in indoor house dust. The incremental lifetime cancer risks (ILCRs) of exposure to PAHs in indoor house dust was 2.23 × 10⁻³ (95% CI: 1.99 × 10⁻³ – 2.48 × 10⁻³) for children and 2.15 × 10⁻³ (95% CI: 1.94 × 10⁻³ – 2.37 × 10⁻³) for adults, exceeding the US EPA safe limit of 1 × 10⁻⁶. Therefore, exposure to PAHs present in indoor house dust increases the cancer risk for children and adults in Kuwait.

This study reports concentrations of PBDEs in surface soil samples collected along a 140km transect across Kuwait to assess the role of urban centers as sources of persistent organic pollutants to the surrounding environment. The ΣPBDE concentrations varied by a factor of ∼250 and ranged from 289 to 80,078pgg⁻¹d.w. The concentrations of PBDEs in Kuwait City were significantly higher (p<0.01) than those collected from sites outside the city supporting the hypothesis that urban centers are sources of PBDEs. The congener profiles were dominated by BDE-209, accounting for 93% of the PBDEs in the soil samples. The concentrations of all congeners (except BDE-209) were highly correlated with percent organic carbon (%OC) (p>0.05) when the data from Kuwait City was omitted from the analysis. These findings suggest that soil concentrations outside the urban centers were close to equilibrium with the atmosphere.

This study provides an insight into the polychlorinated biphenyls (PCBs) inventories in the sediments of the northwestern Arabian/Persian Gulf. PCBs can be used as chemical markers that correlate with historical events in the region, to estimate the sedimentation rates in the northern Gulf, and to determine the sources of pollutants in the study area. The concentrations of PCBs were generally patchy in sediments. At Station 1 the ΣPCB concentrations generally fluctuated between 0.100 and 0.400 ng g⁻¹ dw throughout the depositional history measured in a sediment core. There were four peaks in the ΣPCB profile corresponding to 1969, 1979, 1983 and 1991. Station 2 showed a prominent peak at depth of 25 cm. The concentrations of the ΣPCBs and ΣICE congeners at this depth were 28 and 12 ng g⁻¹ dw respectively. Concentrations then dropped dramatically thereafter by a factor of 4. The ΣPCB concentrations at Station 3 were very low compared to the concentrations measured at Stations 1 and 2. The PCB concentration in Core 4 which was taken from open waters was 2–3 orders of magnitude lower than those in the other coastal cores. However, a 1990–91 peak was omnipresent in these cores. There is no record of PCB production within the Gulf region, and PCB releases into the Kuwait marine environment are likely to originate from their use in products. These maxima in early-1990s can be correlated to inputs from war-related activities, including the reported destruction of PCB-containing transformers and military equipment during the occupation of Kuwait. None of the recent sediment core sections at the four stations had a ΣPCB concentration near the effects range-median (ERM) concentration of 180 ng g⁻¹, or permissible exposure limits (PEL) of 189 ng g⁻¹, or were above the effect range-low (ERL) values of 22.7 ng g⁻¹.

This study was carried out to provide baseline information on the concentrations of pharmaceuticals in Kuwait's coastal waters. Samples were collected over four sampling campaigns from various outfalls that occasionally discharged water into the marine environment and analyzed for a range of pharmaceuticals including analgesic/anti-inflammatories, antibiotics, anticoagulant, antidiabetic, antihelmintics, antihypertensives, antiplatelet agent, asthma medication, β-blocking agent, calcium channel blocker, diuretic, histamine H1 and H2 receptor antagonist, lipid regulators/cholesterol-lowering, prostatic hyperplasia, psychiatric drug, sedation and muscle relaxant, synthetic glucocorticoid, tranquilizer and x-ray contrast media. The levels varied between the detection limits of the method and a maximum of 28,183 ng/L for analgesics/anti-inflammatories. The highest pharmaceutical concentrations were in samples collected during the September campaign, possibly linked to the increased prescription of these medications to treat infectious diseases and flu prevalent in Kuwait during the winter months. The spatial variation is concentration is evident with KISR site being most polluted as hospital wastewater is discharged at the site. This study provides the first dataset on the concentrations of pharmaceuticals in the seawater in Kuwait and possibly the wider Arabian Gulf. Kuwait's coastal water pharmaceutical concentrations derived from this study exceed those reported from the Spanish coast, the Hong Kong harbour, the Bohai and the Yellow seas. More studies are needed to evaluate the environmental impact that these residues may have on non-target organisms.

Copepods are the most abundant metazoans, forming a vital food chain link between the primary producers the phytoplankton and fish. This study presents baseline information on the concentration of ²¹⁰Po among calanoid copepods isolated from the Kuwait marine area. The concentration of ²¹⁰Po in six species of copepod, including Subeucalanus flemingeri, Parvocalanus crassirostis, Acartia pacifica, Calanopia elliptica, Acrocalanus gibber, and Euterpina acutifrons were 151.3–158.8 Bq kg⁻¹ wwt, 121.1–129.5 Bq kg⁻¹ wwt, 51.23–54.91 Bq kg⁻¹ wwt, 38.88–40.09 Bq kg⁻¹ wwt, 38.07–38.29 Bq kg⁻¹ wwt, and 33.46–36.50 Bq kg⁻¹ wwt, respectively.The ²¹⁰Po concentration in seawater shows a seasonal variation, with a higher concentration range of 0.58–0.70 mBq L⁻¹ during summer and autumn, while a lower concentration is found (0.30–0.38 mBq L⁻¹) during winter and spring. The concentration factor among the copepods varies between 8 ∗ 10⁴ and 5 ∗ 10⁵ that is an order of magnitude higher than the diatoms and dinoflagellates.

This study focuses on creating a baseline for ⁴⁰K, ²¹⁰Pb, ¹³⁷Cs, ⁹⁰Sr, ²²⁶Ra, ²²⁸Ra, ²³⁸U, ²³⁵U, ²³⁴U, ²³⁹⁺²⁴⁰Pu and ²³⁸Pu in marine sediments in the northwestern Gulf. The respective measured concentration ranges were 386–489, 32.3–48.8, 1.5–2.9, 4.53–5.42, 18.3–23.1, 18.8–23.0, 22.3–30.5, 0.99–1.33, 25.6–34.8, 0.30–0.93, and 0.0008–0.00018Bqkg⁻¹. The levels of these radionuclides are generally comparable to values reported for other marine waters in the northern hemisphere. The ¹³⁷Cs activity in the Gulf sediments offshore Kuwait is an order of magnitude lower compared to sediments from northeastern Iran. Other than that finding, no hot spots were observed in sediments adjacent to power and desalination plants, oil and gas industrial activities or wastewater treatment facilities. These data will serve as a baseline to gauge possible future inputs of radionuclides in the northern Gulf. The calculated average ratio of ²³⁵U/²³⁸U activity in the area is in agreement with the reported figure of the natural uranium ratio, suggesting the absence of depleted uranium (DU) at all the stations. The low concentration of ²³⁹⁺²⁴⁰Pu suggests that there is no significant source of plutonium except that from atmospheric fallout from weapon testing and possible dry deposition via long-range dust transport.

Hydrodynamics and associated environmental processes have always been of major concern to coastal-dependent countries, such as Kuwait. This is due to the environmental impact that accompanies the economic and commercial activities along the coastal areas. In the current study, a three-dimensional numerical model is utilized to unveil the main dynamic and physical properties of Kuwait Bay during the critical season. The model performance over the summer months (June, July and August 2012) is assessed against comprehensive field measurements of water levels, velocity, temperature and salinity data before using the model to describe the circulation as driven by tides, gravitational convection and winds. The results showed that the baroclinic conditions in the Bay are mainly determined by the horizontal salinity gradient and to much less extent temperature gradient. The gradients stretched over the southern coast of the Bay where dense water is found at the inner and enclosed areas, while relatively lighter waters are found near the mouth of the Bay. This gradient imposed a reversed estuarine circulation at the main axis of the Bay, particularly during neap tides when landward flow near the surface and seaward flow near the bed are most evident. The results also revealed that the shallow areas, including Sulaibikhat and Jahra Bays, are well mixed and generally flow in the counter-clockwise direction. Clockwise circulations dominated the northern portion of the Bay, forming a sort of large eddy, while turbulent fields associated with tidal currents were localized near the headlands.

The sources and levels of endocrine disrupting compounds in Kuwait's coastal areas were investigated. Phthalates, alkylphenols and estrogens were measured in the inflows and outflows of three sewage treatment plants as well as in the seawater and sediments from the sewage impacted coastal areas. Phthalate levels in the inflow of the treatment plants ranged from 8.9 to 78.3μg/l; alkylphenols from 0.7 to 279ng/l and estrogens from 30 to 368ng/l. On average, the treatment plants removed about 80% of these compounds. The outflows, however, contained significant levels of all three classes of compounds. The seawater from the sewage impacted area also contained detectable levels of these compounds. Sediment samples from these locations contained elevated levels of phthalates (ranging from 2145 to 15,722μg/kg) and lower levels of alkylphenols (ranging from 2.49 to 15.14μg/kg) and estrogens (ranging from 4.1 to 214μg/kg, dry wt.).