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Volatile organic compounds in urban rivers and their estuaries in Osaka, Japan.
1997
Yamamoto K. | Fukushima M. | Kakutani N. | Kuroda K.
Polycyclic aromatic hydrocarbons in Norwegian forest soils: impact of long range atmospheric transport.
1996
Aamot E. | Steinnes E. | Schmid R.
Persistence and fate of polychlorinated biphenyls (PCBs) in sewage sludge-amended agricultural soils.
1996
Alcock R.E. | Bacon J. | Bardget R.D. | Beck A.J. | Haygarth P.M. | Lee R.G.M. | Parker C.A. | Jones K.C.
Microbiological remediation of waste-oil polluted soils -Ecotoxicological and toxicological considerations.
1994
Rippen G. | Held T. | Ripper P.
A waste-oil contaminated site situated near a river is supposed to be cleaned-up by means of different but complementary methods. On the basis of a research project, target values have been developed in close cooperation between the participant parties for the saturated and the unsaturated soil layers. The clean-up targets are introduced and discussed.
显示更多 [+] 显示较少 [-]Kinetic constraints on the in-situ remediation of soils contaminated with organic chemicals.
1995
Beck A.J. | Jones K.C.
Observations on long-term air-soil exchange of organic contaminants.
1994
Jones K.C.
Evidence for long-term changes in the soil composition of selected organic compounds, brought about by exchanges with the atmosphere, is briefly reviewed. In the case of some compounds - such as benzo(a)pyrene and octachlorodibenzo-p-dioxin, soils may be significant long-term environmental sinks for atmospherically-derived material. In other cases - such as phenanthrene and some of the lighter PCBs, de-gassing or volatilisation from soil back to the air can occur under certain conditions. Hence the soil may act as a "short-term" sink, and a potential source to atmosphere. Indeed, for some 'semi-volatile' compounds used in large quantities in the past - such as PCBs, soil outgassing may actually be an extremely important source to contemporary air. Furthermore, soil outgassing from areas of former high use may provide an important driving mechanism for continued "global cycling" of a range of semi-volatile organochlorine compounds.
显示更多 [+] 显示较少 [-]Chronic toxicity of an environmental contaminant mixture to young (or larval) striped bass.
1987
Mehrle P.M. | Cleveland L. | Buckler D.R.
The importance of total organic carbon and trihalomethane formation potential in monitoring of groundwater and surface water quality
1999
Ivancev-Tumbas, I. | Dalmacija, B. (Prirodno-matematicki fakultet, Novi Sad (Yugoslavia). Institut za hemiju)
Determination of total organic carbon content (TOC) and trihalomethane formation potential (THMFP) as well as correlation of those two parameters is recommended for monitoring of water bodies which are considered as drinking water resources. Those parameters would enable a categorization of water bodies from the protection point of view as well as from view of their usage as drinking water sources. Relationship between TOC and THMFP is dependent on the origin and the structure of organic matter in water. In this paper the correlation of TOC and THMFP is given for different kind of resources.
显示更多 [+] 显示较少 [-]Treatment of biodigested coffee processing wastewater using Fenton’s oxidation and coagulation/flocculation
2020
Gomes de Barros, Valciney | Rodrigues, Carmen S.D. | Botello-Suárez, Wilmar Alirio | Duda, Rose Maria | Alves de Oliveira, Roberto | da Silva, Eliana S. | Faria, Joaquim L. | Boaventura, Rui A.R. | Madeira, Luis M.
Biodigested coffee processing wastewater (CPW) presents a high organic load and does not meet the limits imposed by legislation (namely in Brazil) for discharge into water bodies. Anaerobic digestion generally cannot provide a satisfactory organic matter reduction in CPW as a significant fraction of recalcitrant compounds still persists in the treated effluent. So, this study aims to find alternative ways to remove refractory organic compounds from this wastewater in order to improve the biodegradability and reduce the toxicity, which will allow its recirculation back into the anaerobic digester. Three treatment approaches (Fenton’s oxidation - Approach 1, Coagulation/flocculation (C/F) - Approach 2, and the combination of C/F with Fenton’s process - Approach 3) were selected to be applied to the biodigested CPW in order to achieve that objective.The application of the Fenton process under the optimal operating conditions (initial pH = 5.0; T = 55 °C, [Fe³⁺] = 1.8 g L⁻¹ and [H₂O₂] = 9.0 g L⁻¹) increased the biodegradability (the BOD₅:COD ratio raised from 0.34 ± 0.02 in biodigested CPW to 0.44 ± 0.01 after treatment) and eliminated the toxicity (0.0% of Vibrio fischeri inhibition) along with moderate removals of organic matter (51.3%, 55.7% and 39.7% for total organic carbon – TOC, chemical oxygen demand – COD and biochemical oxygen demand - BOD₅, respectively). The implementation of a coagulation/flocculation process upstream from Fenton’s oxidation, under the best operating conditions (pH 10–11 and [Fe³⁺] = 250 mg L⁻¹), also allowed to slightly increase the biodegradability (from 0.34 to 0.47) and reduce the toxicity, whereas providing a higher removal of organic matter (TOC = 76.2%, COD = 76.5 and BOD₅ = 66.3% for both processes together). Approach 1 and Approach 3 showed to be the best ones, implying similar operating costs (∼74 R$ m⁻³/∼17 € m⁻³) and constitute an attractive option for managing biodigested CPW.
显示更多 [+] 显示较少 [-]NOx promotion of SO2 conversion to sulfate: An important mechanism for the occurrence of heavy haze during winter in Beijing
2018
Ma, Jinzhu | Chu, Biwu | Liu, Jun | Liu, Yongchun | Zhang, Hongxing | He, Hong
In this study, concentrations of NOₓ, SO₂, O₃ and fine particles (PM₂.₅) were measured at three monitoring stations in Beijing during 2015. For extreme haze episodes during 25 Nov. - 3 Dec. 2015, observation data confirmed that high concentrations of NOₓ promoted the conversion of SO₂ to sulfate. Annual data confirmed that this is an important mechanism for the occurrence of heavy haze during winter in Beijing. Furthermore, in situ perturbation experiments in a potential aerosol mass (PAM) reactor were carried out at Shengtaizhongxin (STZX) station during both clean and polluted days. The concentrations of SO₄²⁻, NH₄⁺, NO₃⁻ and organic aerosol were positively related to the concentration of added NO₂. These results provide definitive evidence that NO₂ can promote the conversion of SO₂ to sulfate. At the same time, we found that NO₂ can promote the formation of NH₄⁺ and organic compounds in the aerosols. Our results illustrate that strengthened controls of nitrogen oxides is a key step in reducing the fine particles level in China.
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