The subject of this research is the vertical migration of strontium-90 in peatlands of the European Subarctic region of Russia. The activity level of strontium-90 has been determined in peat samples, and the physicochemical parameters of peat deposits have been studied. The specific activity of the radionuclide has been determined using beta radiometric methods with radiochemical preparation according to the methodology. The physicochemical parameters of the peat have been determined using weight-based methods according to the specified procedures. The influence of physicochemical parameters on the vertical migration of the radionuclide in peatlands has been evaluated using correlation analysis. The results have shown that the specific activity of strontium-90 in peat deposits ranges from 0.25 to 7.7 Bq/kg. The results are consistent with typical values for all soils in Russia. The average value of the specific activity of strontium-90 in peat deposits is estimated to be 1.5±0.02 Bq/kg, which is below the established minimum values and average parameters for all soils in Russia. The pathways of vertical migration of strontium-90 in peat deposits demonstrate a downward direction with various trajectories. These pathways serve as a trace of past global atmospheric radioactive fallout. The vertical migration of strontium-90 in peat is associated with the organic matter content, ash content in peatlands, and recent local atmospheric fallout from nuclear fuel facilities. The research results provide valuable information for predicting the migration of strontium-90 into aquifers under changing environmental conditions due to the Arctic's rapid climate warming.

This study characterizes the impacts of transported peat-forest (PF) burning smoke on an urban environment and evaluates associated source burning conditions based on carbon properties of PM₂.₅ at the receptor site. We developed and validated a three-step classification that enables systematic and more rapid identification of PF smoke impacts on a tropical urban environment with diverse emissions and complex atmospheric processes. This approach was used to characterize over 300 daily PM₂.₅ data collected during 2011–2013, 2015 and 2019 in Singapore. A levoglucosan concentration of ≥0.1 μg/m³ criterion indicates dominant impacts of transported PF smoke on urban fine aerosols. This approach can be used in other ambient environments for practical and location-dependent applications. Organic carbon (OC) concentrations (as OC indicator) can be an alternate to levoglucosan for assessing smoke impacts on urban environments. Applying the OC concentration indicator identifies smoke impacts on ∼80% of daily samples in 2019 and shows an accuracy of 51–86% for hourly evaluation. Following the systematic identification of urban PM₂.₅ predominantly affected by PF smoke in 2011–2013, 2015 and 2019, we assessed the concentration ratio of char-EC/soot-EC as an indicator of smoldering- or flaming-dominated burning emissions. When under the influence of transported PF smoke, the mean concentration ratio of char-EC to soot-EC in urban PM₂.₅ decreased by >70% from 8.2 in 2011 to 2.3 in 2015 but increased to 3.8 in 2019 (p < 0.05). The reversed trend with a 65% increase from 2015 to 2019 shows stronger smoldering relative to flaming, indicating a higher level of soil moisture at smoke origins, possibly associated with rewetting and revegetating peatlands since 2016.

Little information exists concerning the long-term interactive effect of nitrogen (N) addition with phosphorus (P) and potassium (K) on Sphagnum N status. This study was conducted as part of a long-term N manipulation on Whim bog in south Scotland to evaluate the long-term alleviation effects of phosphorus (P) and potassium (K) on N saturation of Sphagnum (S. capillifolium). On this ombrotrophic peatland, where ambient deposition was 8 kg N ha−1 yr−1, 56 kg N ha−1 yr−1 of either ammonium (NH4+, Nred) or nitrate (NO3−, Nox) with and without P and K, were added over 11 years. Nutrient concentrations of Sphagnum stem and capitulum, and pore water quality of the Sphagnum layer were assessed. The N-saturated Sphagnum caused by long-term (11 years) and high doses (56 kg N ha−1 yr−1) of reduced N was not completely ameliorated by P and K addition; N concentrations in Sphagnum capitula for Nred 56 PK were comparable with those for Nred 56, although N concentrations in Sphagnum stems for Nred 56 PK were lower than those for Nred 56. While dissolved inorganic nitrogen (DIN) concentrations in pore water for Nred 56 PK were not different from Nred 56, they were lower for Nox 56 PK than for Nox 56 whose stage of N saturation had not advanced compared to Nred 56. These results indicate that increasing P and K availability has only a limited amelioration effect on the N assimilation of Sphagnum at an advanced stage of N saturation. This study concluded that over the long-term P and K additions will not offset the N saturation of Sphagnum.

In the Athabasca Oil Sands Region in northeastern Alberta, Canada, oil sands operators are testing the feasibility of peatland construction on the post-mining landscape. In 2009, Syncrude Canada Ltd. began construction of the 52 ha Sandhill Fen pilot watershed, including a 15 ha, hydrologically managed fen peatland built on sand-capped soft oil sands tailings. An integral component of fen reclamation is post-construction monitoring of water quality, including salinity, fluvial carbon, and priority pollutant elements. In this study, the effects of fen reclamation and elevated sulfate levels on mercury (Hg) fate and transport in the constructed system were assessed. Total mercury (THg) and methylmercury (MeHg) concentrations in the fen sediment were lower than in two nearby natural fens, which may be due to the higher mineral content of the Sandhill Fen peat mix and/or a loss of Hg through evasion during the peat harvesting, stockpiling and placement processes. Porewater MeHg concentrations in the Sandhill Fen typically did not exceed 1.0 ng L−1. The low MeHg concentrations may be a result of elevated porewater sulfate concentrations (mean 346 mg L−1) and an increase in sulphide concentrations with depth in the peat, which are known to suppress MeHg production. Total Hg and MeHg concentrations increased during a controlled mid-summer flooding event where the water table rose above the ground surface in most of the fen. The Hg dynamics during this event showed that hydrologic fluctuations in this system exacerbate the release of THg and MeHg downstream. In addition, the elevated SO42− concentrations in the peat porewaters may become a problem with respect to downstream MeHg production once the fen is hydrologically connected to a larger wetland network that is currently being constructed.

The objective of this research was to assess factors controlling peat and plant chemistry, and vegetation composition in 18 peatlands surrounding Sudbury after more than 30 years of large (>95%) pollution emission reductions. Sites closer to the main Copper Cliff smelter had more humified peat and the surface horizons were greatly enriched in copper (Cu) and nickel (Ni). Copper and Ni concentrations in peat were significantly correlated with that in the plant tissue of Chamaedaphne calyculata. The pH of peat was the strongest determining factor for species richness, diversity, and community composition, although percent vascular plant cover was strongly negatively correlated with surface Cu and Ni concentrations in peat. Sphagnum frequency was also negatively related to peat Cu and Ni concentrations indicating sites close to Copper Cliff smelter remain adversely impacted by industrial activities.

To quantify potential nitrogen (N) deposition impacts on peatland carbon (C) uptake, we explored temporal and spatial trends in N deposition and climate impacts on the production of the key peat forming functional group (Sphagnum mosses) across European peatlands for the period 1900–2050. Using a modelling approach we estimated that between 1900 and 1950 N deposition impacts remained limited irrespective of geographical position. Between 1950 and 2000 N deposition depressed production between 0 and 25% relative to 1900, particularly in temperate regions. Future scenarios indicate this trend will continue and become more pronounced with climate warming. At the European scale, the consequences for Sphagnum net C-uptake remained small relative to 1900 due to the low peatland cover in high-N areas. The predicted impacts of likely changes in N deposition on Sphagnum productivity appeared to be less than those of climate. Nevertheless, current critical loads for peatlands are likely to hold under a future climate.

Atmospheric deposition of trace metals and metalloids from anthropogenic sources has led to the contamination of many European peatlands. To assess the fate and behaviour of previously deposited arsenic and lead, we constructed catchment-scale mass budgets for a degraded peatland in Northern England. Our results show a large net export of both lead and arsenic via runoff (282 ± 21.3 gPb ha⁻¹ y⁻¹ and 60.4 ± 10.5 gAs ha⁻¹ y⁻¹), but contrasting controls on this release. Suspended particulates account for the majority of lead export, whereas the aqueous phase dominates arsenic export. Lead release is driven by geomorphological processes and is a primary effect of erosion. Arsenic release is driven by the formation of a redox-dynamic zone in the peat associated with water table drawdown, a secondary effect of gully erosion. Degradation of peatland environments by natural and anthropogenic processes has the potential to release the accumulated pool of legacy contaminants to surface waters.

European natural peatlands have undergone long-term anthropogenic drainage activities that have severely decreased their functions, such as carbon sequestration. Recent rewetting has been conducted to restore the ecosystem services of peatlands and mitigate the emissions of potent greenhouse gases such as nitrous oxide (N₂O). However, the magnitudes and spatial patterns of annual N₂O fluxes and their mitigation potentials across European peatlands remain unknown. Here, we synthesized 492 annual N₂O flux data points from 77 in situ studies across European peatlands and found that the soil annual N₂O fluxes varied extensively from −1.08 to 33.40 kg N₂O–N ha⁻¹ yr⁻¹; these results were significantly and interactively (P < 0.05) affected by the peatland status, climatic regime and nutrient supply type. Drainage significantly (P < 0.05) stimulated soil N₂O emissions from natural minerotrophic rather than ombrotrophic peatlands, regardless of the climatic regime. Similarly, rewetting significantly (P < 0.05) reduced soil N₂O emissions from drained minerotrophic rather than ombrotrophic peatlands, demonstrating that the high N₂O emissions were driven by a simultaneous decline in the water table depth and increase in the soil nitrogen (N) availability. Magnitudes of the increases or decreases in N₂O emissions due to drainage or rewetting were also significantly influenced by the land-use and drainage history before rewetting and in the years following drainage/rewetting, respectively. The estimated annual mean N₂O emission total was found to be 90.42 (95% confidence interval: 64.49–122.57) Gg N₂O–N in 2020 from European peatlands. Scenario analysis showed that drained peatlands should be rewetted expeditiously; postponing rewetting would cause larger emissions from continued N₂O emissions from drained peatlands. Fully rewetting the drained peatlands used for forestry and peat extraction and partially rewetting those used for agriculture and grassland comprise a strategy for mitigating drained peatland N₂O emissions without compromising food security.

The effects of atmospheric pollution on plant species richness (nₛₚ) are of widespread concern. We carried out a modelling exercise to estimate how nₛₚ in British semi-natural ecosystems responded to atmospheric deposition of nitrogen (Ndₑₚ) and sulphur (Sdₑₚ) between 1800 and 2010. We derived a simple four-parameter equation relating nₛₚ to measured soil pH, and to net primary productivity (NPP), calculated with the N14CP ecosystem model. Parameters were estimated from a large data set (n = 1156) of species richness in four vegetation classes, unimproved grassland, dwarf shrub heath, peatland, and broadleaved woodland, obtained in 2007. The equation performed reasonably well in comparisons with independent observations of nₛₚ. We used the equation, in combination with modelled estimates of NPP (from N14CP) and soil pH (from the CHUM-AM hydrochemical model), to calculate changes in average nₛₚ over time at seven sites across Britain, assuming that variations in nₛₚ were due only to variations in atmospheric deposition. At two of the sites, two vegetation classes were present, making a total of nine site/vegetation combinations. In four cases, nₛₚ was affected about equally by pH and NPP, while in another four the effect of pH was dominant. The ninth site, a chalk grassland, was affected only by NPP, since soil pH was assumed constant. Our analysis suggests that the combination of increased NPP, due to fertilization by Ndₑₚ, and decreased soil pH, primarily due to Sdₑₚ, caused an average species loss of 39% (range 23–100%) between 1800 and the late 20th Century. The modelling suggests that in recent years nₛₚ has begun to increase, almost entirely due to reductions in Sdₑₚ and consequent increases in soil pH, but there are also indications of recent slight recovery from the eutrophying effects of Ndₑₚ.

Mercury (Hg) concentrations in freshwater fish relates to aquatic Hg concentrations, which largely derives from soil stores of accumulated atmospheric deposition. Hg in catchment soils as a source for aquatic Hg is poorly studied. Here we test if i) peatland soils produce more methylmercury (MeHg) than forest soils; ii) total Hg (THg) concentrations in top soils are determined by atmospheric inputs, while MeHg is produced in the soils; and iii) soil disturbance promotes MeHg production. In two small boreal catchments, previously used in a paired-catchment forest harvest manipulation study, forest soils and peatlands were sampled and analysed for Hg species and additional soil chemistry. In the undisturbed reference catchment, soils were sampled in different vegetation types, of varying productivity as reflected in tree density, where historical data on precipitation and throughfall Hg and MeHg fluxes were available. Upper soil THg contents were significantly correlated to throughfall inputs of Hg, i.e. lowest in the tree-less peatland and highest in the dense spruce forest. For MeHg, top layer concentrations were similar in forest soils and peatlands, likely related to atmospheric input and local production, respectively. The local peatland MeHg production was documented through significantly higher MeHg-to-THg ratios in the deeper soil layer samples. In the disturbed catchment, soils were sampled in and just outside wheeltracks in an area impacted by forest machinery. Here, MeHg concentrations and the MeHg-to-THg ratios in the upper 5 cm were weakly significantly (p = 0.07) and significantly (p = 0.04) different in and outside of the wheeltracks, respectively, suggesting that soil disturbance promotes methylation. Differences in catchment Hg and MeHg streamwater concentrations were not explained by soil Hg and MeHg information, perhaps because hydrological pathways are a stronger determinant of streamwater chemistry than small variations in soil chemistry driven by disturbance and atmospheric inputs of Hg.