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Evaluation of heavy metal contamination in sediments of the Umayo Lagoon, Peru, and the behaviour of local actors
2024
Atilio Salas-Ávila, Dante | Chaiña Chura, Fermin | Belizario Quispe, German | Quispe Mamani, Edgar | Hurtado Chavez, Edgar | Rojas Chahuares, Felix | Quispe Borda, Wenceslao | Hermoza Gutierrez, Marian | Salas Mercado, Dante
Multidisciplinary studies that integrate socioenvironmental aspects into the assessment of water resources contamination significantly enhance the identification of its sources. In the present study, an assessment of heavy metal contamination in sediments of Umayo Lagoon and the behavior of local actors was conducted. The concentrations of As, Cd, Cu, Hg, Pb, and Zn were determined and evaluated using international regulations. These data enabled the creation of distribution maps to pinpoint accumulation zones of different metals and suggest their possible sources of origin. The results were compared with the behavior of local actors, addressing three analytical characteristics: feelings, thoughts, and attitudes. Evidence showed contamination by As (18.11 mg/kg), Hg (0.19 mg/kg), and Cd (0.96 mg/kg), likely originating from mining activities, cheese plants, and agriculture. In terms of social aspects, intense emotions were expressed due to the presence of diseases and livestock mortality associated with metal contamination, causing anxiety and fear in the population. The incorporation of socioenvironmental aspects in the contamination assessment aligned with the physicochemical results, achieving identification of the sources of Umayo Lagoon.
显示更多 [+] 显示较少 [-]Impact of Wastewater on Water Quality and Fish Community in the Tolych River, Perm Krai, Russia
2023
Ushakova, Evgeniya | Drobinina, Elena | Puzik, Alexey | Mikheev, Pavel
Boreal freshwater ecosystems are highly sensitive to pollution, but too little information is available on the use of both biotic and chemical indicators for estimation of the effect of wastewater on boreal rivers and streams. The purpose of this study was to assess the wastewater impact on the boreal river (Perm Krai, Russia). Physicochemical parameters of major ions and trace elements were detected with a field portable unit, capillary electrophoresis, and ICP-MS. Fish data was collected by gillnets. To evaluate the level of pollution from the Tolych River upstream to downstream, we calculated heavy metal evaluation index (HEI), ecological risk index (ERI), and index of biotic integrity (IBI). The anthropogenic impact from upstream to downstream showed the range from a very high to medium level of pollution by ERI and from a high to medium level by HEI values, where most of the studied major ions and trace elements often exceeded aquatic life limits. We found significant thermal pollution of the observed river with the decreasing temperature gradient from pollution source down to the river mouth due to hydromorphological factors. Observed thermal pollution leads to the absence of thermally sensitive cold-water fish species and the abundance of ecologically flexible fish species. The water quality assessed by biotic IBI index showed low and very low quality of lower reach of the studied river, which contradicts the results of assessment by HEI and ERI indices. The results show the importance of using aquatic organisms as bioindicators for assessing ecological water quality.
显示更多 [+] 显示较少 [-]Impact of Vehicular Traffic on Single Use Surgical Face Masks as a Source of Environmental Micro-fiber Pollution
2023
Spennemann, Dirk
During the COVID-19 pandemic large numbers of single-use, surgical style face masks were lost or discarded in public spaces, primarily in on public streets and car parking settings. Many of these masks were blown onto the road surfaces where they were subjected to degradation through the tire impact of passing vehicle traffic. As series of field observations as well as experimental simulations show that the three-ply polypropylene mask fabric is subjected to shear forces when compressed between the tire and the road surface. The mechanical action breaks the bonds between the fibers (both spunbonded and meltblown) leading to a continual shedding of microfibers. Wind disperses these into the environment along road sides, while surface water action moves them into stormwater drains and from there into the waterways. As the decay is rapid, municipal agencies only have a short window of time to remove stray face masks from the urban environment if micro-fiber pollution is to be reduced.
显示更多 [+] 显示较少 [-]Trichoderma tomentosum Ts141 as a Potential Candidate for Bioremediation of Cadmium, Lead, and Nickel Ions
2023
Hosseinzadeh, Samira | Aliloo, Ali Asghar | Shahabivand, Saleh | Ghaderi, Mohammad
Fungi are successful microorganisms in the bioremediation of environmental pollution. So, this study aimed to determine the potential of Trichoderma tomentosum to remediate cadmium, lead, and nickel contaminations from potato dextrose agar (PDA) and potato dextrose broth (PDB) media. Growth rates, toxicity tolerance sporulation, bio-sorption capacity, and bio-sorption efficiency of the fungus were evaluated under different concentrations of CdCl2, Pb(NO3)2, and NiCl2. The findings demonstrated that the growth rate of the fungus differed depending on concentration, metal type, and medium. More metals in PDA medium induced more inhibition on fungus growth rates; however, the rate was independent from the heavy metals concentrations in PDB medium. Cadmium was the most toxic metal tested against T. tomentosum, with a 72h LC50 of 37 ppm. It was about 3.16 and 4.24 times as toxic as nickel and lead, respectively. In the control condition, sporulation of the fungus began at 72 hours, but under the heavy metals, it began at 168, 168, and 192 hours, respectively, for Pb, Ni, and Cd. Both the bio-sorption capacity and efficacy of the fungus were significantly enhanced by an increase in metal content and the highest values were obtained at 200 ppm of the salts. The heavy metals total bio-sorption capacity order was Ni < Cd < Pb in the aqueous medium. The conclusion was that T. tomentosum has a greater potential for the biosorption of heavy metals; hence, the fungus may be employed for the bioremediation of heavy metals from polluted sites, particularly wastewater and industrial influents.
显示更多 [+] 显示较少 [-]Identification and Quantification of Antibiotic Residues and Evaluation of Microbial Resistance to Antibiotics in Huatanay River Waters in Peru
2023
Del Castillo De Loayza, Tatiana | Maldonado, Ingrid | Zirena Vilca, Franz
The Huatanay River in Cusco-Peru, is affected by wastewater discharges along its course. In order to evaluate this impact, we evaluate antibiotic residues and their impact on the increase of bacterial resistance in the city of Cusco treatment plant. For this purpose, water samples from the influent and effluent of the treatment plant were analyzed by chromatographic methods; additionally, sensitivity tests were performed with three bacterial strains (Escherichia coli, Salmonella sp., and Klebsiella sp.), which were isolated from the same place. Six antibiotic residues were identified (ceftriaxone, amoxicillin, trimethoprim, sulfamethoxazole, dicloxacillin, and lincomycin). Those found in the highest concentration were: amoxicillin (91495 and 0 µg/L) and lincomycin (33970 and 10800 µg/L) in the influent and effluent, respectively. There is more resistance in the effluent than the influent in the case of E. coli shows resistance in the effluent to cephalexin (30 µg) and azithromycin (15 µg). Salmonella sp. is resistant to amoxicillin (15 µg), dicloxacillin (1 µg), lincomycin (2 µg), ceftriaxone (30 µg), cephalexin (30 µg), and ciprofloxacin (5 µg). Finally, Klebsiella sp. is sensitive to ceftriaxone (30 µg), amoxicillin (15 µg), and cephalexin (30 µg). This confirms that the antibiotic residues contained in the wastewater of Cusco generate resistance in the isolated bacteria.
显示更多 [+] 显示较少 [-]Engineering Properties of Substrate used in Constructed Wetlands Treating low Strength Sewage under Tropical Conditions
2023
Vishwakarma, Smily | Dharmendra, Dharmendra | Singh, Rohit | Bharti, Bharti | Ankita, Ankita
Substrates play a major role to filter, adsorb, sediment, flocculate, precipitate, and exchange ions. In CW (Constructed wetland), selecting substrate or bed materials is not difficult, as locally accessible, cost-effective, and environment-friendly materials can be used based on size, hydraulic conductivity, texture, porosity, etc. CW substrates undergo a multitude of purification processes, including physical filtration and sedimentation, sorption, ion exchange and microbial degradation, precipitation, and bio-immobilization in the substrate, in addition to uptake and metabolism by macrophytes. With constructed wetlands, treatment facilities with well-defined substrates, vegetation species, and flow patterns can be built with greater control than with natural systems. This report details investigations of some of the locally available substrates that all fit the requirements. Based on analysis of parameters which are pH, water absorption capacity, hydraulic conductivity, porosity, surface area, bulk density, particle size distribution, D10 particle diameter, D60 uniformity coefficient, permeability and specific gravity, a comparison of four materials is presented in this paper. The study found that the construction waste materials evaluated showed satisfactory physical properties for use as filler media in constructed wetlands for wastewater treatment.
显示更多 [+] 显示较少 [-]Adsorption and Leaching Behavior of Copper, Zinc and Lead Ions by Three Different River Nile Sediments at Aswan, Egypt
2019
Rashed, M.N. | Toufeek, M. E. F. | Eltaher, M. A. E. | Elbadry, A.O.
The present study was carried out to investigate the adsorption and leaching behavior of Cu2+, Zn2+ and Pb2+ by sediments collected from the western banks of three different sectors along River Nile at Aswan governorate, Egypt. The feasibility of sediments for the removal of Cu2+, Zn2+ and Pb2+ from aqueous solutions was tested under the effect of three conditions (pH, initial metal concentration and contact time). By increasing pH, the adsorption of Cu2+ and Pb2+ by sediments decreased while that of Zn2+ increased. The optimum pH values for Cu2+, Zn2+ and Pb2+ removal were determined as 5, 8.5 and 5, respectively. The adsorption capacities of sediments for metal ions were in the order of Pb2+ > Cu2+ > Zn2+. The maximum uptake for Cu2+, Zn2+ and Pb2+ by sediments occurred at contact times of 48 h, 24 h and 72 h, respectively. Adsorption data were fitted well by Freundlich, Dubinin–Radushkevich and Temkin isotherms. The experimental results obtained were analyzed using two adsorption kinetic models, pseudo-first-order and pseudo-second-order, in which pseudo-second-order equation described the data more than pseudo-first-order one. The average leaching percentages of Cu2+, Zn2+ and Pb2+ from sediments were 0.77%, 2.72% and 0.38%, respectively, with respect to pH, 0.83%, 2.49% and 0.38%, respectively , with respect to temperature, and also 0.79%, 2.34% and 0.38%, respectively with respect to contact time. The leaching percentages of metal ions from sediments were in the order of Zn2+ > Cu2+ > Pb2+.
显示更多 [+] 显示较少 [-]Characterization of tannery effluents of Hazaribagh area, Dhaka, Bangladesh
2017
Kabir, Mohammad | A. N. M, Fakhruddin | M. A.Z, Chowdhury | Z., Fardous | Islam, Rashedul
The present investigation characterizes tannery effluents by determining water quality parameters and some selected trace metallic constituents in order to measure the magnitude of environmental pollution. Effluents and sediments have also been used to isolate chromium-resistant bacteria, collected from Hazaribagh area, Dhaka, claimed to be increasing Cr (VI)-enriched environments, and utilized to reduce Cr (VI). The pH, TDS, DO, and EC values of all investigated samples have been within the range of 4.35 to 9.74, 290 to 9,200 mg/L, 1.5 to 4.90 mg/L, and 587 to 19,000 µs/cm, respectively. The concentrations of trace metallic constituents have been determined by means of Atomic Absorption Spectrophotometer (AAS), giving the following ranges: Cr: 14.282 to 6,769.554 mg/L; Cd: 1.546 to 2.214 mg/L; Pb: 18.808 to 32.026 mg/L; Cu: 1.522 to 2.578 mg/L; Zn: 0.682 to 8.688 mg/L; Fe: 1.37 to 108.556 mg/L; and Mn: 3.494 to 17.17 mg/L. The order of trace metallic constituents in the effluent samples was Cr > Fe > Pb > Mn > Zn > Cd > Cu. The water quality parameters and metallic constituents’ concentration were higher than that of standard permissible limits in all the examined samples. The average number of Cr (VI)-resistant bacteria in the sediment samples with glucose (0.5%, w/v) supplementation was 2.35× 103 CFU/gm at 24h. One of the representative isolate was able to tolerate up to 400 mg/L of K2Cr2O7 as Cr (VI). The bacteria, isolated in the present study, can be used as eco-friendly biological agents for the remediation and/or detoxification of chromium (Cr) pollution from the chromium contaminated environments.
显示更多 [+] 显示较少 [-]Polycyclic aromatic hydrocarbons in air from industrial areas in Lagos and Ogun states, Nigeria
2017
Salaudeen, Ibrahim | Sonibare, Oluwadayo | Sojinu, Samuel | Ekundayo, Olusegun
There is currently scarce information on the occurrence and distributions of Polycyclic Aromatic Hydrocarbons (PAHs) in the air from industrial estates in Nigeria. Hence, the present study aims to evaluate the extent and sources of pollution of polycyclic aromatic hydrocarbons in the air from some industrial estates in Lagos and Ogun States, Nigeria. Ten air samples have been collected from the industrial estates in Lagos (Ogba and Ilupeju) and ten from Ogun (Agbara and Ota) between October and November, 2014, using low volume air sampler. Also five further air samples have been collected from Epe town, located in the outskirts of Lagos, where there are no industrial activities to serve as control. The concentrations and distributions of 20 target Polycyclic Aromatic Hydrocarbons (PAHs) in the air samples have been determined by gas chromatography-mass spectrometry. The concentration of ∑20PAHs ranged from 89.20 to 96.48 ng/m3 (with an average of 92.84 ng/m3) and 72.52 to 142.91 ng/m3 (with an average of 107.72 ng/m3) in the air samples from Lagos and Ogun industrial estates, respectively. The air from the control site has a total ∑20PAHs concentration of 19.55 ng/m3 (9.78 ng/m3 in average). When compared with global data, these values show that the air samples have been moderately polluted. PAHs in most air samples are mainly from pyrolytic sources, which may have resulted from diesel fuel combustion and high vehicular emissions, typical of industrial activities in the area.
显示更多 [+] 显示较少 [-]Evaluation of oil pollution dispersion in an unsaturated sandy soil environment
2017
Abbasi Maedeh, Pouyan | Nasrabadi, Touraj | Wu, Wei | Al Dianty, Marelianda
The current study assesses critical condition of oil dispassion, considering the unsaturated soil condition dispersity behavior for oil dispersion. The numerical model is used as a finite element method to model the oil spill pollution with two different saturated and unsaturated soil conditions chosen and their pollution dispersion results compared. Extracted results from numerical model show that considering the form of unsaturated soil, by changing the matric suction its soil conductivity ratio will differ. Regarding the current study analysis, it has been observed that the pattern of oil dispersion in case of unsaturated soil can be changed, in comparison to saturated soil condition. The vertical penetration of oil pollution in both cases of saturated and unsaturated soil condition will be more than horizontal dispersion pollution speed. As for oil pollution control in soil domain, the condition of unsaturated soil may be controllable, compared to the saturated one. Extracted results show that oil dispersion velocity, considering saturated soil, is more than 10 times greater than unsaturated one.
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