The increasing microplastics (MPs) pollution and continuous acid rain coincide in many areas of the world. However, how MPs interact with acid rain is still unclear. Herein, we conducted a microcosm experiment to decipher the combined effect of polyethylene (PE) MPs (1%, 5%, and 10%) and acid rain (pH 4.0) on the agricultural soil ecosystem of Southern China, in which edaphic property, microbial community, enzymatic activity and CO₂ emission were investigated. The results showed that PE MPs significantly decreased soil water retention and nitrate nitrogen content regardless of acid rain. Soil total nitrogen significantly decreased under the co-exposure of 10% PE MPs and acid rain. However, PE MPs did not alter soil microbial biomass, i.e., the content of microbial biomass carbon, total phospholipid fatty acids, with or without acid rain. 10% PE MPs and acid rain treatment significantly increased the activity of catalase and soil CO₂ emission. PE MPs addition did not affect the temperature sensitivity (Q₁₀) of soil CO₂ emission regardless of acid rain. These findings suggest that MPs may interact with acid rain to affect soil ecosystems, thus underscoring the necessity to consider the interaction between MPs and ambient environmental factors when exploring the impact of MPs on the soil biodiversity and function.

Soil washing has been established as suitable remediation technology, with most research focused on metal removing efficiency and toxic effect on plants, less on the influence on soil physical characteristics, which was the focus of this study. In soil column experiment highly contaminated soil and soil washed with EDTA, mixed with additives (gypsum, hydrogel, manure, peat) were tested. White clover was used as a soil cover. Yield, metal concentration in soil and plant, aggregate fractionation and stability, saturated hydraulic conductivity and soil water retention of the soil were measured. Soil washing decreased metal concentration in soil and plants, but yield of white clover on remediated soil was significantly lower compared to the original soil. Significant differences in water retention characteristics, aggregate fractionation and stability between original and remediated soil have been determined. Gypsum, hydrogel and peat increased plant available water, manure and peat increased yield on remediated soil.

Biochar addition to soil may change the hydrophobicity of amended soil and influence soil hydraulic properties. Soil hydrophobicity, i.e. soil water repellency (SWR) can interrupt water infiltration and form preferential flow leading to a potential risk of soil erosion or groundwater pollution. Up to date, the effect of different biochars on soil hydrophobicity remains unclear and the association of SWR with soil hydraulic properties is still unknown. To link the biochar hydrophobicity to SWR and soil water holding capacity (WHC), the surface structure and chemical composition of 27 biochars with different feedstocks and pyrolysis temperatures were characterized, and the SWR and soil WHC of biochar-added soil were investigated. Carboxylic groups on the biochar surface, surface area and pore volume were mostly influenced by pyrolysis temperature, which suggested the dominant factor determining the severity of biochar hydrophobicity was pyrolysis temperature. Hydrophilic soil became hydrophobic after biochar amendment. A higher addition rate led to a stronger SWR of hydrophilic soil. Biochar addition increased soil WHC of hydrophilic soil with low total organic carbon (TOC) content. Biochar did not have significant influence on SWR and soil WHC of hydrophobic soil with high TOC content. It implied that the influence of biochar on SWR and soil hydraulic properties mainly depended on soil original hydrophobicity and TOC content. Therefore, the properties of biochar and influence on soil hydrophobicity and hydraulic properties should be considered before processing biochar application.

In this study, a method of preparing fertilizers with the fly ash from biomass power plants and the waste acid solution from flue gas desulfurization and denitrification was disclosed. In addition, the study also explored the effects of added fine particles, unburned biochar, and other commercial fertilizers on soil water retention and slow-release effect of fertilizers. The analysis was done by comparing the aggregation degrees of crystalline salt and the variations of the chemical bonds. The experimental results showed that the added fine particles could effectively increase the water absorption of fertilizers, which helped to improve soil water retention. Meanwhile, the fine particles could strengthen the special adsorption of basic compounds containing N, P, and other nutrients by biochar and enhance the slow-release effect of fertilizers. Although adding part commercial fertilizers weakened the water absorption of fertilizers slightly, it had only a relatively small effect on the aggregation of water-soluble crystalline salt on the surfaces of fine particles and biochar. Furthermore, the microwave was applied to promote the absorption of N by unburned biochar, during which only small amounts of volatile were released and lost. The experiments had confirmed that microwave irradiation could promote the agglomeration of biochar on crystalline salt effectively, thus enhancing the slow-release effect of crystalline salt in fertilizers. Finally, pot experiments demonstrated that the self-prepared fertilizer improved plant growth by its better water absorption and slow-release properties during the whole growth period, which had promising application potential as the slow-release fertilizer in the plant growth field.

The retention and movement of water and atrazine (2-chloro-4-ethylamino-6- isopropylamino-s-triazine) was investigated in a calcareous soil (Krome) amended with three types of compost: (1) Clean organic waste (COW)- municipal solid waste cleaned of plastic materials and metal containers, (2) Biosolids (BSD)- sludge from municipal waste and (3) Bedminster (BDM)-a mixture containing 75% COW and 25% BSD. The research was conducted in two phases; a column-leaching study (dynamic) and a batch-equilibrium method (static). The column study demonstrated that while applying simulated rain, atrazine, leached out at a slower rate by 41, 24, and 18% from soil amended with BDM, BSD, and COW composts, respectively, during the first simulated storm event. BDM application resulted in lowest water movement and atrazine-leaching rate compared to the other composts tested. This study suggests that adding 134 t ha-1 of compost to the calcareous soil increased soil water holding capacity, reduced water movement and increased atrazine detention and reduced leaching potential of atrazine thereby reducing the potential for groundwater pollution. This study further demonstrates that soil amendment (particularly BDM) is effective in reducing the leaching potential of atrazine at the low rainfall amounts (corresponding to 0.5 pore volume). However, such amendment may not be effective in preventing leaching under more intense rain conditions or multiple rainfall events (corresponding to 3 or more pore volumes).

Fifteen soil profiles were taken from Ar-Ramtha wastewater treatment plant, 65 km north of Amman. Twelve of them represent soil planted with barley and irrigated with wastewater for the past 2, 5, and 15 years. The remaining three profiles represented a control area that has been only rainfed. Soil samples were collected in four replicates from each depth in each soil profile. Field and laboratory experiments were conducted to study the effect of irrigation with treated wastewater on hydraulic properties of surface and subsurface vertisols. Soil infiltration rate (IR), hydraulic conductivity (HC), and water retention (at 33 kPa and 1.5 MPa) were measured. The application of wastewater for 2, 5, and 15 years reduced soil hydraulic conductivity, whereas the infiltration rate decreased for 2 and 5 years, compared with non-irrigated area. Sites irrigated for 15 years with treated wastewater are characterized by higher percentages of large cracks, therefore revealed the highest infiltration rate. Soil available water changed due to wastewater application in decreasing order of: control (rainfed), 15, 5, 2 years of wastewater application.

Water eutrophication caused by the extensive expansion of slope farming has caused the high attention of the Chinese government. We choose Lake Tianmu basin as the study area because it can represent vast majority of basins plagued by water eutrophication derived from slope tillage in southern China. The water ecosystem in the reservoir Daxi and Shahe within the basin has been seriously threatened by multiple pollution sources related to many intricate human activities especially agricultural production. For the first time, we identified the critical source areas (CSAs) within the basin based on nutrient load and nutrient load intensity (NLI), and on this basis, we further excavated the main causes of pollution and proposed pertinent remediation measures. The results based on the calibrated Soil and Water Assessment Tool model indicated that the TN load of each reservoir remarkably exceeded their respective water environmental capacity from 2014 to 2018. Accordingly, six main tributaries with great nutrient contributions and their corresponding sub-basins were then identified. Overall, tea and rice plantations appear to be the major nutrient contributors to reservoir Daxi. And the main nutrient sources for reservoir Shahe are tea plantations, orchards, farmland, forestland, and point sources. Regarding the CSAs identified only by nutrient load, agronomic measures such as reducing fertilizer amount, biochar application, straw incorporation, and plastic mulch coverage can be employed to improve soil water retention and curb soil erosion. Regarding the CSAs identified by nutrient load intensity (NLI), the CSAs with narrow areas should be turned directly into forestland. For the CSAs with large areas, engineering measures such as constructing ecological riparian zone, filtration, and sedimentation tank can be employed to prevent pollutants from entering downstream reaches. Overall, the present results can provide the decision-making support for the safe and efficient management of watershed land use in southern China.

This study is focused on investigating the impacts of organic carbon on the denitrification process of nitrogen transformation and transport. A numerical model, Nitrogen-2D, is modified by considering the impact of organic carbon in the denitrification equation. The modified model is used to simulate the soil nitrogen (including nitrate and ammonium) dynamics under the primary and secondary sewage water irrigation with different organic carbon concentrations. The simulated results of accumulated drainage water amount, soil nitrogen concentration, and nitrogen concentration in the drainage water show that the simulations and measurements are consistent. The comparison of results from the original and improved models shows the necessity to consider the impact of organic carbon. The nitrogen mass balance is calculated to analyze the nitrogen transformation processes quantitatively under different input organic carbon sources. Furthermore, the effect of different input organic carbon sources on the soil nitrogen dynamics is investigated by using the modified Nitrogen-2D model with the calibrated parameters. The input organic carbon source helps to speed up the mineralization and denitrification, which contributes to the slight increase of ammonium concentration and the decrease of nitrate concentration in the shallow soil. Since a large number of soil water and nitrogen transformation and transport parameters are needed when setting up the model, a local sensitivity method is conducted to evaluate the input parameters by the sewage water irrigation case. The results show that the drainage water amount is very sensitive to the exponent n and the coefficient α of the soil water retention function and that the ammonium concentration is very sensitive to the first-order nitrification rate constant, the decomposition rate coefficient in humus pool, and the soil ammonium adsorption coefficient. The nitrate concentration is sensitive to more parameters, especially to the exponent n and the coefficient α in the soil water retention function and to the denitrification rate constant.

The accumulation, distribution, and speciation of contaminants, such as arsenic, in rice can be affected by soil microorganisms such as arbuscular mycorrhizal fungi (AMF). As a potential measure to control contaminant acquisition in rice, the status and performance of AMF in the field need to be investigated. Root samples of rice plants were collected in seven different cities in Guangdong, Jiangxi, Hubei, and Jiangsu Provinces in China in order to investigate the colonization rate of AMF. The total DNA of the roots was extracted, followed by PCR and sequencing, and further confirmed the existence of AMF. The highest colonization rates (19.5 ± 7.2%) were observed in samples from Huizhou City, Guangdong Province. Sequences of ribosomal DNA derived from Pingtan (PT) and Shuikou (SK) in Huizhou shared a similarity of 73 and 86% to Glomus cf. clarum Att894-7 (FM865542) and “uncultured fungus” (EF434122.1), respectively. The moisture tolerance of the AMF from different sources was tested by subjecting to different levels of water content in the soil. Only AMF from PT, SK, and LJ colonized rice under a condition of 100% of the soil water holding capacity (WHC), but not those isolated from upland plants. The AM colonization rate could be governed by the lighting conditions and temperature. AMF isolated in paddy fields has been shown to have more tolerance to moisture than other upland species. Radial oxygen loss (species and stress dependent) could be an essential factor influencing the colonization rate and requires more investigation.