This study aimed at assessing the effects of increased air temperature and reduced soil moisture content on the multi-generation toxicity of a soil polluted by metal/metalloid mining wastes. Enchytraeus crypticus was exposed to dilution series of the polluted soil in Lufa 2.2 soil under different combinations of air temperature (20 °C and 25 °C) and soil moisture content (50% and 30% of the soil water holding capacity, WHC) over three generations standardized on physiological time. Generation time was shorter with increasing air temperature and/or soil moisture content. Adult survival was only affected at 30% WHC (∼30% reduction at the highest percentages of polluted soil). Reproduction decreased with increasing percentage of polluted soil in a dose-related manner and over generations. Toxicity increased at 30% WHC (>50% reduction in EC50 in F0 and F1 generations) and over generations in the treatments at 20 °C (40–60% reduction in EC50 in F2 generation). At 25 °C, toxicity did not change when combined with 30% WHC and only slightly increased with 50% WHC. So, higher air temperature and/or reduced soil moisture content does affect the toxicity of soils polluted by metal/metalloid mining wastes to E. crypticus and this effect may exacerbate over generations.

The change in land-use from woodland to crop production leads to increased nitrous oxide (N2O) emissions. An understanding of the main N2O sources in soils under a particular land can be a useful tool in developing mitigation strategies. To better understand the effect of land-use on N2O emissions, soils were collected from 5 different land-uses in southeast China: shrub land (SB), eucalyptus plantation (ET), sweet potato farmland (SP), citrus orchard (CO) and vegetable growing farmland (VE). A stable isotope experiment was conducted incubating soils from the different land use types at 60% water holding capacity (WHC), using 15NH4NO3 and NH415NO3 to determine the dominant N2O production pathway for the different land-uses. The average N2O emission rates for VE, CO and SP were 5.30, 4.23 and 3.36 μg N kg−1 dry soil d−1, greater than for SB and ET at 0.98 and 1.10 μg N kg−1 dry soil d−1, respectively. N2O production was dominated by heterotrophic nitrification for SB and ET, accounting for 51 and 50% of N2O emissions, respectively. However, heterotrophic nitrification was negligible (<8%) in SP, CO and VE, where autotrophic nitrification was a primary driver of N2O production, accounting for 44, 45 and 66% for SP, CO and VE, respectively. Denitrification was also an important pathway of N2O production across all land-uses, accounting for 35, 35, 49, 52 and 32% for SB, ET, SP, CO and VE respectively. Average N2O emission rates via autotrophic nitrification, denitrification and heterotrophic nitrification increased significantly with gross nitrification rates, NO3− contents and C:N ratios respectively, indicating that these were important factors in the N2O production pathways for these soils. These results contribute to our understanding and ability to predict N2O emissions from different land-uses in subtropical acidic soils and in developing potential mitigation strategies.

The degradation of metformin (MET) and guanylurea (GUA) fortified separately in freshly collected two top soils (0–10 cm) from New Zealand's pastoral region was studied under controlled laboratory conditions. Incubation studies were carried at 30 °C under aerobic conditions at 60% of maximum water holding capacity and at two (0.5 mg/kg and 5 mg/kg) nominal soil concentrations. Degradation profiles revealed a bi-phasic pattern of both the compounds with an initial rapid degradation followed by slow dissipation rate, resulting in poor fits by simple first order kinetics. However, the use of three non-linear mathematical models sufficiently described the measured data and well supported by an array of statistical indices to judge model's ability to fit the measured datasets. Further evaluation using box-whisker plots showed that double first-order in parallel (DFOP) and first-order two-compartment (FOTC) models best fitted the data points followed by the Bi-exponential (BEXP) model. Mechanistic assumptions from DFOP and FOTC suggest that degradation of MET and GUA proceeds at two different rates, possibly in two compartments. The calculated DT50 using both models were in the range of 2.7–15.5 days and 0.9–4 days, while 90% dissipation time (DT90) varied between 91 and 123 days and 44 and 137 days for MET and GUA, respectively. Degradation of both compounds were dependent on soil types and properties, incubation conditions and initial substrate concentration. Formation of GUA with decrease in MET concentration over time confirmed that GUA is a transformation product concomitantly formed from aerobic degradation of MET in soil.

Biochar addition to soil may change the hydrophobicity of amended soil and influence soil hydraulic properties. Soil hydrophobicity, i.e. soil water repellency (SWR) can interrupt water infiltration and form preferential flow leading to a potential risk of soil erosion or groundwater pollution. Up to date, the effect of different biochars on soil hydrophobicity remains unclear and the association of SWR with soil hydraulic properties is still unknown. To link the biochar hydrophobicity to SWR and soil water holding capacity (WHC), the surface structure and chemical composition of 27 biochars with different feedstocks and pyrolysis temperatures were characterized, and the SWR and soil WHC of biochar-added soil were investigated. Carboxylic groups on the biochar surface, surface area and pore volume were mostly influenced by pyrolysis temperature, which suggested the dominant factor determining the severity of biochar hydrophobicity was pyrolysis temperature. Hydrophilic soil became hydrophobic after biochar amendment. A higher addition rate led to a stronger SWR of hydrophilic soil. Biochar addition increased soil WHC of hydrophilic soil with low total organic carbon (TOC) content. Biochar did not have significant influence on SWR and soil WHC of hydrophobic soil with high TOC content. It implied that the influence of biochar on SWR and soil hydraulic properties mainly depended on soil original hydrophobicity and TOC content. Therefore, the properties of biochar and influence on soil hydrophobicity and hydraulic properties should be considered before processing biochar application.

In this study, the performance of Datura stramonium, an invasive weed of soybean and solanaceous crops, was examined under different elements of climate change. Experiments conducted in CO₂ chambers at ambient CO₂ (400 ppm) and elevated CO₂ (700 ppm) levels under both well-watered and drought conditions exhibited the fertilization effect of elevated CO₂. This was, however, limited by drought. Clearly, growth of D. stramonium will be significantly enhanced by enriched atmospheric CO₂ concentration under well-watered conditions, producing taller plants with greater biomass and higher seed output. Glasshouse experiments were conducted to evaluate the effect of different soil moisture regimes (100%, 75%, 50% and 25% water-holding capacity (WHC)) on the growth and fecundity of D. stramonium. Plants grown in 75% WHC had the highest plant height (15.24 cm) and shoot diameter (4.25 mm). The lowest leaf area (305.91 mm²), fresh weight (14.48 g) and dry weight (4.45 g) were observed in 25% WHC conditions. The ability of D. stramonium plants to grow and complete their life cycle with high seed output, even under limited water availability, shows the weedy nature of this species which is well adapted to survive future inhospitable climatic conditions. Radiant heat treatment on the plants indicated that temperatures of 120 °C and above for more than 180 s were enough to kill the plants, suggesting that thermal weeding or wildfires will be adequate to act as a circuit breaker on the D. stramonium invasion cycle, thus allowing other control measures to be engaged for greater control.

Disposal and management of abattoir wastewater have been a long-term concern in a high meat-consuming country like Australia. Land-based application of wastewater is considered to be the most economically viable disposal method and is widely used by abattoirs. In this study, we assessed the effects of long-term abattoir wastewater irrigation on soil physical and chemical characteristics of calcareous soils. Soil samples were collected from 16 different locations with seven 5 cm depths intervals down to 35 cm. Soil properties including soil type, bulk density, moisture holding capacity, pH, electrical conductivity (EC), nitrogen (N), phosphorus (P), carbon (C) and micronutrients were measured. Soil characteristics were compared with non-irrigated soils. The study area receives annually about 327 ML of wastewater with high concentration of N and P (186 and 30.4 mg/L). Overall, the site retained 0.6 t N/ha, 0.1 t P/ha and 0.4 t of K per hectare. Irrigation for over a decade onto the study site has caused a significant change in the soil fertility. Soil total N was increased by 82% compared to non-irrigated. Similarly, soil total P concentration was increased more than sixfold. The overall results showed that the abattoir wastewater irrigation to soil caused very significant changes in soil nutrient levels. These changes indicate need to recapture the surplus nutrient, in particular N, to avoid potential leaching and off-site effects.

The application of hydroxyapatite (HAP) can transform lead into pyromorphite in the soil. However, it is not clear how the physicochemical properties of soil enhance or reduce the formation of pyromorphite. This study determined that the presence of ferrihydrite or soil moisture condition was a more important factor to enhance the formation of pyromorphite. We also evaluated lead sorption characteristics and stability in soil with HAP in the presence of ferrihydrite. The difference in the maximum lead removal capacity of soil with and without 5 wt% ferrihydrite corresponded to 10.4% of the difference in lead removal between soils with and without HAP. In artificially contaminated soil with a 50% water-holding capacity, the ratio of lead that formed into pyromorphite was compatible between soils with and without ferrihydrite at 22% and 28% of added lead, respectively. In a percolation test, almost all of the added lead was transformed into pyromorphite, despite the presence of ferrihydrite. In both water and a 0.1-M citric acid extraction, the differences in lead extracted from the contaminated soil with HAP with or without ferrihydrite were very small compared with water-soluble lead in soil without HAP. This study indicated that in soil with 5 wt% ferrihydrite, lead was removed and converted into pyromorphite by HAP with a little disturbance by ferrihydrite, and the immobilized lead would be stable. In addition, this study suggested that the soil moisture condition was a more important factor for the formation of pyromorphite than the presence of ferrihydrite.

Effects of low-temperature thermal desorption (LTTD) treatment on the ecological properties of soil contaminated by petroleum hydrocarbons were assessed. For this purpose, various ecological properties related to soil health and physicochemical properties of the oil-contaminated soil before and after LTTD treatment were investigated. Total petroleum hydrocarbon concentration, electrical conductivity, organic matter, and total nitrogen decreased while water-holding capacity and available P₂O₅ increased. The soil color was also changed but textural class was not changed after LTTD. The microbial number and dehydrogenase activity increased following LTTD, but there was no significant difference in the β-glucosidase and acid phosphatase activities. Seed germination succeeded after LTTD, but the germination rate was still lower than that in non-contaminated soil as the growth of plants and earthworms was. The results showed that overall soil health related to biological productivity and environmental functions was improved after LTTD and suggested that LTTD could be a better alternative to other harsh remediation methods. However, ecological indicators still show differences to the adjacent non-contaminated level. Therefore, to ensure safe soil reuse, the change in eco-physiochemical properties as well as contaminant removal efficiency during the remediation process should be considered.

Rhamnolipid is a biosurfactant produced by several Pseudomonas species, and can wet hydrophobic soils by lowering the cohesive and/or adhesive surface tension. Because of its biodegradability, rhamnolipid is believed to have minimal adverse impact on the soil and groundwater after usage. Applications of rhamnolipid to improve irrigation in agricultural soils thus have obvious advantages over other chemical wetting agents, especially under drought conditions. Due to global warming, soil amendment with biochar has been commonly practiced in agricultural soils to increase the soil water-holding capacity. As such, rhamnolipid transport in biochar-amended agricultural soils needs to be characterized. In this research, we found that rhamnolipid transport in biochar-amended agricultural soils was hindered by retardation (equilibrium adsorption) and deposition (kinetic adsorption), which was well represented by the advection-dispersion equation based on a local equilibrium assumption. A linear equilibrium adsorption was assumed in the advection-dispersion equation simulation, which was proved to be acceptable by studying the breakthrough curves. Both rhamnolipid equilibrium adsorption and kinetic adsorption increased with the increase of the biochar content in the agricultural soil.