Trace metal elements are toxic to the environment and human health and can be removed from water through adsorption. Development of low-cost adsorbents would always been a matter of achievement of every adsorption study as usually many adsorbents were found to be expensive in nature. In this regard, biochar adsorbents gained significant attention due to high adsorption capacity, low-cost and environmental sustainability. Pyrolysis is used to produce biochar adsorbents at varying temperature ranged from 300°C-700°C. The adsorption capacities of palm fiber biochar adsorbents are remarkable which was found around ~198 mg/g for cadmium removal. However, bamboo-based biochar had 868 mg/g of adsorption capacity for arsenate removal. This review aims to provide the current discusses the sources and impacts of trace metal elements in water along with properties of biochar including its composition, surface area, pore structure, and surface functional groups. Further, various types of biomasses have also been mentioned for producing biochar such as agricultural wastes, food wastes, forestry residues, etc. The paper also discusses the different types of mechanisms involved in the adsorption of heavy metal biochar adsorbents like electrostatic attraction, ion exchange, surface complexation etc.

The aim of this paper is to find out the most efficient method of determination of toxic PCB in the natural way in aquatic system. According to the preliminary research, positive degradative response of PCBs was obtained by the selection of micro fungi species.

Sawdusts of hardwood - oak and black locust, modified with formaldehyde and/or alkali solution, were used as adsorbents zinc ions from model water. The influence of concentration of alkali solution for modification, on zinc ions adsorption efficiency were investigated. Batch adsorption tests were conducted on ambient temperature. Langmuir and Freundlich adsorption isotherm equations were determinated for some adsorbents investigated. Good improvement of adsorption characteristics is achieved by modification of sawdust with alkali. Modification of sawdusts only with formaldehyde results with good prevention of leaching of organic substances as well as poor increase of adsorption efficiency.

Low flows are a good measure of the waste water recipient self-purification capability. The regional statistical analysis is an objective way of assessment of the required low flows. This paper presents the principles and key phases of the regional statistical analysis. The advantages of this method are a reduction of the outliers influence and the assessment of low flows on ungauged streams and stream profiles. The method is illustrated with the results obtained by the required low flows regional statistical analysis in Serbia (Yugoslavia) with 59 hydrological gauge stations in the scope, which data has the same length of 39 years, from the year 1956 to 1994.

The photocatalytic degradation of the insecticide fenitrothion was performed in the water solution in the presence of TiO2 by UV illumination. NMR spectrocopy showed that the decomposition of the initial substrate and all intermediates formed to the mineralization end products is completed in 66.3 hours. This fact was used to establish the possible mechanisms of the degradation process. The obtained results show that this method may have an important application in the removal of fenitrothion from water.

In this paper we have pointed out the hydrogeological condition in the catchment area of the Jablanica river in the south Serbia (Yugoslavia). The two units are separately presented here. The first one is mountainous part of the catchment area upstream of the gaging station of Lebane and the second one is the part of the terrain in the plain down stream to the river mounth near Pecenjevac. The hydrogeological characteristics of the two mentioned regions are given to explain the reasons of existing the constant flow of the Jablanica to Lebane and its disappearing course in the period of recession in the plain downstream. The quality of water in the Jablanica river at Lebane is good. Down stream of this gaging station the waste water collector flows into the river. In the part of recession period the ratio between them is unfavourable. We have also discussed the quality of water at the gaging station of Pecenjevac and pointed out the function of sandy-gravel deposits in the process of natural purification of the Jablanica flow.

Removal of natural organic matter (NOM) from groundwater by aluminium sulphate and polyaluminium chloride (PACl) was investigated. The maximal decrease of UV absorbance at 254 nm was near 70%. Decrease of permanganate value about 50% was achieved by PACl coagulation. Similar effect can be achieved using 2.5 fold higher concentration of aluminium sulphate. Coagulation process at pH 5.5 was successful with 3-5 times less concentration of coagulant. The heterogenous composition of NOM in water had been changing by coagulation. The total trihalomethane formation potential is 50-60% lower in coagulated water. The greatest removal was success for chloroform precursors.

In our previous papers, it is concluded that wood sawdust can be applied as adsorbent for heavy metals removing from water. All earlier investigations are done in batches, while it is confirmed that different heavy metals are adsorbing with various efficacy on sawdust of different kind of wood. Adsorption of copper ions from model water is investigated in this paper, by its passing throw column filled with poplar and fir sawdust, granulation in the range 0.5-1 mm. Starting concentration of copper ions was the same in all experiments, and flowrates of model water and column geometry are varied. Certain volumes of water are taken on the column outlet, and copper ions concentration are determinated in this samples. On the basis of these results breakthrough curves are obtained, and adsorption parameters in dynamic conditions are determinated.

Removal of natural organic matter from water was investigated using granulated activated carbon. Groundwater from northern Banat region (Serbia, Yugoslavia) was used. Samples of raw water and water after coagulation were ozonated and than GAC adsorption was performed. The investigation was carried out under the static conditions to determine the GAC adsorption capacity and kinetic coefficients.

Significant concerns have been raised regarding to the pollution of antibiotics in recent years due to the abuse of antibiotics and their high detection rate in water. Herein, a novel super adsorbent, boronic acid-modified bacterial cellulose microspheres with a size of 415 μm in diameter was prepared through a facile water-in-oil emulsion method. The adsorbent was characterized by atomic force microscopy, scanning electron microscopy, and fourier transform infrared spectroscopy analyses to confirm its properties. The microspheres were applied as packing materials for the adsorption of tetracycline (TC) from an aqueous solution and hoggery sewer via the reversible covalent interaction between cis-diol groups in TC molecules and the boronic acid ligand. TC adsorption performance had been systemically investigated under various conditions, including the pH, temperature, TC concentration, contact time, and ionic strength. Results showed that the adsorption met pseudo-second-order, Elovich kinetic model and Sips, Redlich-Peterson isothermal models. And the adsorption process was spontaneous and endothermic, with the maximum TC adsorption capacity of 614.2 mg/g. After 18 adsorption-desorption cycles, the adsorption capacity remained as high as 84.5% compared with their original adsorption capacity. Compared with other reported adsorption materials, the microspheres had high adsorption capacity, a simple preparation process, and excellent recovery performance, demonstrating great potential in application on TC removal for water purification and providing new insights into the antibiotic's adsorption behavior of bacterial cellulose-based microspheres.