Drinking water shortage has become worse in recent decades. A new capacitive deionization (CDI) method for increasing water supplies through the effective desalination of seawater has been developed. Silver as nano Ag and Ag@C which was prepared by carbonization of the Ag+-β-cyclodextrin complex at 573K for 30min can add the antimicrobial function into the CDI process. The Ag@C and Ag nanoparticles dispersed on reduced graphene oxide (Ag@C/rGO and nano Ag/rGO) were used as the CDI electrodes. The nano Ag/rGO and Ag@C/rGO electrodes can reduce the charging resistant, and enhance the electrosorption capability. Better CDI efficiencies with the nano Ag/rGO and Ag@C/rGO electrodes can therefore be obtained. When reversed the voltage, the electrodes can be recovered up to 90% within 5min. This work presents the feasibility for the nano Ag and Ag@C on rGO electrodes applied in CDI process to produce drinking water from seawater or saline water.

Concentrations of heavy metals in river water and sediment were investigated in nine estuaries along the coast of Bohai Bay, Northern China. Multivariate statistical techniques such as principal component analysis and cluster analysis, in combination with metal concentration analysis and correlation analysis, were used to identify the possible sources of the metals and the pollution pattern in nine estuaries along the coast of Bohai Bay. The environmental risks of metals, evaluated by sediment quality guidelines and background values, revealed Hg contamination in the estuaries. However, levels of Cd in estuarine sediments were low, and they were less than those levels in river sediments, partly due to the high mobility and dilution of river or seawater. Cd did not contribute to sediment deposits in estuaries. High organic matter from effluents from large municipal sewage treatment plants was predominantly responsible for restricting Hg mobility from the river to Bohai Bay.

The Guaxindiba Estuarine System is located in the northeast portion of Guanabara Bay. Despite the location inside an environmental protection zone, the main affluent of the river runs through the extremely urbanized area of the cities of Niterói and São Gonçalo. In order to understand the contamination levels of the estuary, 35 surface sediment samples were collected along the river and estuarine area and analyzed for the presence of heavy metals, PAHs, organochlorated pesticides, polychlorinated biphenyl and other contaminants. The analyzed data revealed a greatly affected environment with respect to most of these substances. The results suggested propitious deposits of contaminants, with high concentrations of organic matter and fine sediment. The levels of heavy metal in the entire estuarine system were high compared with the local background. The total mean concentrations of As, Cd, Pb, Cu, Zn, Hg, Cr and Ni in the surface sediments were: 3.74; 0.03; 19.3; 15.0; 99.0; n.d.; 29.0; and 22.0mg/kg, respectively, confirming, in certain cases, the high capacity of the environment to concentrate pollution.

A considerable amount of research has been conducted on the impacts of recreational boating activities on fishes but little or no synthesis of the information has been undertaken. This review shows that motor boats impact on the biology and ecology of fishes but the effects vary according to the species and even particular size classes. Direct hits on fishes by propellers are an obvious impact but this aspect has been poorly documented. Alterations in the wave climate and water turbidity may also influence fishes and their habitats, especially submerged and emergent plant beds. Sound generated by boat motors can also influence the communication and behaviour of certain species. Pollution arising from fuel spillages, exhaust emissions and antifouling paints all have detrimental effects on fishes. Finally, the use of recreational boats as vectors of aquatic invasive organisms is very real and has created major problems to the ecology of aquatic systems.

Genome resources have advantages for understanding diverse areas such as biological patterns and functioning of organisms. Omics platforms are useful approaches for the study of organs and organisms. These approaches can be powerful screening tools for whole genome, proteome, and metabolome profiling, and can be used to understand molecular changes in response to internal and external stimuli. This methodology has been applied successfully in freshwater model fish such as the zebrafish Danio rerio and the Japanese medaka Oryzias latipes in research areas such as basic physiology, developmental biology, genetics, and environmental biology. However, information is still scarce about model fish that inhabit brackish water or seawater. To develop the self-fertilizing killifish Kryptolebias marmoratus as a potential model species with unique characteristics and research merits, we obtained genomic information about K. marmoratus. We address ways to use these data for genome-based molecular mechanistic studies. We review the current state of genome information on K. marmoratus to initiate omics approaches. We evaluate the potential applications of integrated omics platforms for future studies in environmental science, developmental biology, and biomedical research. We conclude that information about the K. marmoratus genome will provide a better understanding of the molecular functions of genes, proteins, and metabolites that are involved in the biological functions of this species. Omics platforms, particularly combined technologies that make effective use of bioinformatics, will provide powerful tools for hypothesis-driven investigations and discovery-driven discussions on diverse aspects of this species and on fish and vertebrates in general.

In this study, 75 samples of two 210Pb-dated cores from the southwest of the Caspian Sea were analysed for 30 compounds of polycyclic aromatic hydrocarbons (PAHs). The TPAH29 flux of the last six centuries ranged from 16.3 to 177.3 and 22.3 to 426.2ngcm−2y−1 in the Rezvanshahr and Anzali core sediments, respectively. Prior to 1840, four distinct maxima in PAH fluxes (61–426.2ngcm−2y−1) with a low weathered petrogenic pattern were found in each of the core sediments. Simultaneity of distinct peaks of PAH fluxes before 1840 and Caspian Sea level high-stands during the Little Ice Age (LIA), revealed the high importance of this phenomenon in washing and transport of land-based oil pollution into the Caspian Sea. An overall increase in some diagnostic ratios (Flu/202, IP/276 and BaA/228), especially after 1940, indicated increase of pyrogenic PAHs as a result of industrial development in the catchment area.

Life Cycle Assessment (LCA) has been introduced in the evaluation of chemical processes and or products in order to take into account the Supply Chain and its environmental constraints and burdens. Regarding to the environmental assessment of chemical processes and/or products two main variables need to be taken into account: Natural Resources Sustainability (NRS) and Environmental Burdens Sustainability (EBS). NRS includes the use of energy, water and materials whereas EBS is given by the environmental sustainability metrics developed by the Institution of Chemical Engineers (IChemE). The main components of EBS have been classified in 5 environmental impacts to the atmosphere (acidification, global warming, human health effects, stratospheric ozone depletion and photochemical ozone formation), 5 aquatic media impacts (aquatic acidification, aquatic oxygen demand, ecotoxicity (metals), ecotoxicity (others) and eutrophication) and 2 land impacts (hazardous and non-hazardous waste disposal). To reduce the number of variables and thus, the complexity, the development of a normalisation and weighting procedure is required. This work proposes the normalization of EB based on the threshold values of the European Pollutant Release and Transfer Register (E-PRTR) and a similar procedure based on the values given by the BREF document on waste incineration for the NRS normalisation. This procedure will help in the decision making process in the waste management field and in the particular, in Municipal Solid Waste Incineration (MSWI).

The aim of this work is to develop an integrated process for the sustainable management of reverse osmosis brines generated in desalination plants. The core of the proposed process is the bipolar membrane electrodialysis (BMED), which has proved to be a technically feasible option for the conversion of RO desalination brines into HCl and NaOH. However, the overall process should also integrate the brine purification treatment. Precipitation with NaOH, using the reactant produced in BMED, would be the most suitable option for hardness removal. On the other hand, the presence of sulphate affects negatively the quality of the hydrochloric acid product and the current efficiency of BMED. Therefore, in this work nanofiltration (NF) has been applied in order to retain sulphate. This work reports the mathematical model that describes the transport of binary aqueous solutions of chloride and sulphate anions through the NF270 nanofiltration membrane. The relevance and the difficulty of the task lie on the high concentrations of both anions, as it occurs in the RO brines generated in the desalination of brackish water, and the variety of valence charge of the species, monovalent chloride and divalent sulphate, that introduces significant differences in the interaction of both anions with the charged membrane surface. | This work has been financially supported by projects CTQ2008-0690, ENE2010-15585 and CTM2011-23912 (co-financed by ERDF Funds).

Seed priming effects on Trifolium repens were analysed both in Petri dishes and in two soils (one unpolluted soil and a soil polluted with Cd and Zn). Priming treatments were performed with gibberellic acid 0.1 mM at 22 °C during 12 h or with polyethylene glycol (−6.7 MPa) at 10 °C during 72 h. Both priming treatments increased the germination speed and the final germination percentages in the presence of 100 μM CdCl₂or 1 mM ZnSO₄. Flow cytometry analysis demonstrated that the positive effect of priming was not related with any advancement of the cell cycle in embryos. Seed imbibition occurred faster for primed seeds than for control seeds. X-ray and electronic microscopy analysis suggested that circular depressions on the seed coat, in addition to tissue detachments inside the seed, could be linked to the higher rate of imbibition. Priming treatments had no significant impact on the behaviour of seedlings cultivated on non-polluted soil while they improved seedling emergence and growth on polluted soil. The two priming treatments reduced Zn accumulation. Priming with gibberellic acid increased Cd accumulation by young seedlings while priming with polyethylene glycol reduced it. Priming improved the light phase of photosynthesis and strengthened the antioxidant system of stressed seedlings. Optimal priming treatment may thus be recommended as efficient tools to facilitate revegetation of former mining area.