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The vital function of humic acid with different molecular weight in controlling Cd and Pb bioavailability and toxicity to earthworm (Eisenia fetida) in soil 全文
2020
Bai, Hongcheng | Luo, Mei | Wei, Shiqiang | Jiang, Zhenmao | He, Mingjing
Humic acid (HA) plays vital roles in regulating the environmental behaviors of metals and thus their toxicity to biota. However, the inner relation between metal bioavailability to soil organisms and the presence of HA with different molecular weight (Mw) is not well documented. In this study, we separated HAs into four fractions with Mw range of 5-30k Da, and discussed their ability to alleviating the toxicity of Cd and Pb to earthworm. The bioaccumulation capacities (Cₘₐₓ) increased in order of: UF1<UF2<UF3<UF4, which is in line with the variations of bioavailable concentrations of Cd and Pb in soil. Variations of Mw and binding capacities of HA determine the accumulation behavior in soil solution. The unsatisfactory of biotic ligand model fitting and the differences in fractions of the total biotic ligand sites (f) in earthworm bound by Cd and Pb suggested that only free species of Cd could be considered as biological available to earthworm, while the Pb–HAs complexes have potential ability to interact with earthworm membrane. Antioxidant enzymes are effective biomarkers, and HA with lower Mw play more important roles in restricting the toxicity of soil Cd and Pb to earthworm. These results reveal the different mechanism for HA controlling metal bioavailability between Cd and Pb in soil environment.
显示更多 [+] 显示较少 [-]Particulate matter pollution and hospital outpatient visits for endocrine, digestive, urological, and dermatological diseases in Nanjing, China 全文
2020
Wang, Ce | Zhu, Guangcan | Zhang, Lei | Chen, Kai
Clinical or pathological evidence demonstrated that air pollution could undermine other organ systems of human body besides respiratory and circulation systems. Investigations that directly relate hospital outpatient visits for endocrine (ENDO), digestive (DIGE), urological (UROL), and dermatological (DERM) diseases categories with ambient particulate matter (PM) are still lacking, particularly in heavily polluted cities. Here, we conducted a time-series analysis using 812,624, 1,111,342, 539,803, and 741,662 hospital visits for ENDO, DIGE, UROL, and DERM, respectively, in Nanjing, China from 2013 to 2019. A generalized additive model was applied to estimate the exposure-response associations. Results showed that a 10 μg/m³ increase in PM₂.₅ concentration on lag 0 day was significantly associated with 0.59% (95% CI: 0.30%, 0.88%), 0.43% (0.15%, 0.70%), 0.36% (0.06%, 0.66%), and 0.65% (0.42%, 0.87%) increase for ENDO, DIGE, UROL, and DERM hospital visits, respectively. The estimated effects of PM₁₀ were slightly smaller but still statistically significant. The magnitude and significance of the associations between PM and four health outcomes were sensitive to additional adjustment for co-pollutants. Exposure-response relationships were linear for PM concentrations lower than 100 μg/m³ but the curves became nonlinear across the full range of exposures due to a flatten slope at higher concentrations. We also explored the effect modifications by season (cold or warm), age (5–18, 18–64, 65–74, or 75+ years), and sex (male or female). Results showed that the DERM-related population aged 65 years or older was more vulnerable to PM exposure, compared with the 5 to 17-year age group; the DERM-related population aged 75 years or older and 65 years or older was more vulnerable to PM₂.₅ and PM₁₀ exposure, respectively, compared with the 18 to 64-year age group. Our study provided suggestive evidence that ambient PM pollution was associated with ENDO, DIGE, UROL, and DERM outpatient hospital visits in Nanjing, China.
显示更多 [+] 显示较少 [-]Comparative removal of As(V) and Sb(V) from aqueous solution by sulfide-modified α-FeOOH 全文
2020
Li, Qiao | Li, Rui | Ma, Xinyue | Sarkar, Binoy | Sun, Xiuyun | Bolan, Nanthi
Efficient elimination of As(V) and Sb(V) from wastewater streams has long been a major challenge. Herein, sulfide-modified α-FeOOH adsorbent was fabricated via a simple sulfidation reaction for removing As(V) and Sb(V) from aqueous media. Compared with the pristine α-FeOOH, sulfide-modified α-FeOOH increased the adsorption of As(V) from 153.8 to 384.6 mg/g, and Sb(V) adsorption from 277.8 to 1111.1 mg/g. The enhanced adsorption of both As(V) and Sb(V) was maintained at the pH range from 2 to 11, and was not interfered by various coexisting anions such as Cl⁻, SO₄²⁻, NO₃⁻, SiO₃²⁻ and PO₄³⁻. The adsorption affinity increased from 0.0047 to 0.0915 and 0.0053 to 0.4091 for As(V) and Sb(V), respectively. X-ray photoelectron spectroscopic investigation demonstrated a reductive conversion of As(V) to As(III) during the adsorption process with sulfide-modified α-FeOOH, but with no obvious variation of Sb(V) speciation. While the removal mechanism for As(V) was reduction followed by adsorption via hydroxyl groups, mainly surface complexation was involved in the removal of Sb(V). This study presented a simple strategy to enhance the adsorption capacity and adsorption affinity of α-FeOOH toward As(V)/Sb(V) via sulfide-modification.
显示更多 [+] 显示较少 [-]Concentration and origin of lead (Pb) in liver and bone of Eurasian buzzards (Buteo buteo) in the United Kingdom 全文
2020
Taggart, Mark A. | Shore, Richard F. | Pain, Deborah J. | Peniche, Gabriela | Martinez-Haro, Mónica | Mateo, Rafael | Homann, Julia | Raab, Andrea | Feldmann, Joerg | Lawlor, Alan J. | Potter, Elaine D. | Walker, Lee A. | Braidwood, David W. | French, Andrew S. | Parry-Jones, Jemima | Swift, John A. | Green, Rhys E.
Ingestion of lead (Pb) derived from ammunition used in the hunting of game animals is recognised to be a significant potential source of Pb exposure of wild birds, including birds of prey. However, there are only limited data for birds of prey in Europe regarding tissue concentrations and origins of Pb. Eurasian buzzards (Buteo buteo) found dead in the United Kingdom during an 11-year period were collected and the concentrations of Pb in the liver and femur were measured. Concentrations in the liver consistent with acute exposure to Pb were found in 2.7% of birds and concentration in the femur consistent with exposure to lethal levels were found in 4.0% of individuals. Pb concentration in the femur showed no evidence of consistent variation among or within years, but was greater for old than for young birds. The Pb concentration in the liver showed no effect of the birds’ age, but varied markedly among years and showed a consistent tendency to increase substantially within years throughout the UK hunting season for gamebirds. The resemblance of the stable isotope composition of Pb from buzzard livers to that of Pb from the types of shotgun ammunition most widely-used in the UK increased markedly with increasing Pb concentration in the liver. Stable isotope results were consistent with 57% of the mass of Pb in livers of all of the buzzards sampled being derived from shotgun pellets, with this proportion being 89% for the birds with concentrations indicating acute exposure to Pb. Hence, most of the Pb acquired by Eurasian buzzards which have liver concentrations likely to be associated with lethal and sublethal effects is probably obtained when they prey upon or scavenge gamebirds and mammals shot using Pb shotgun pellets.
显示更多 [+] 显示较少 [-]Adult exposure to acidified seawater influences sperm physiology in Mytilus galloprovincialis: Laboratory and in situ transplant experiments 全文
2020
Gallo, Alessandra | Esposito, Maria Consiglia | Cuccaro, Alessia | Buia, Maria Cristina | Tarallo, Andrea | Monfrecola, Vincenzo | Tosti, Elisabetta | Boni, Raffaele
Adult exposure to acidified seawater influences sperm physiology in Mytilus galloprovincialis: Laboratory and in situ transplant experiments 全文
2020
Gallo, Alessandra | Esposito, Maria Consiglia | Cuccaro, Alessia | Buia, Maria Cristina | Tarallo, Andrea | Monfrecola, Vincenzo | Tosti, Elisabetta | Boni, Raffaele
The ongoing increase of CO₂ in the atmosphere is inducing a progressive lowering of marine water pH that is predicted to decrease to 7.8 by the end of this century. In marine environment, physical perturbation may affect reproduction, which is crucial for species’ survival and strictly depends on gamete quality. The effects of seawater acidification (SWAc) on gamete quality of broadcast spawning marine invertebrates result largely from experiments of gamete exposure while the SWAc impact in response to adult exposure is poorly investigated. Performing microcosm and in field experiments at a naturally acidified site, we investigated the effects of adult SWAc exposure on sperm quality parameters underlying fertilization in Mytilus galloprovincialis. These animals were exposed to pH 7.8 over 21 days and collected at different times to analyze sperm parameters as concentration, motility, viability, morphology, oxidative status, intra- and extra-cellular pH and mitochondrial membrane potential. Results obtained in the two experimental approaches were slightly different. Under field conditions, we found an increase in total sperm motility and mitochondrial membrane potential on days 7 and 14 from the start of SWAc exposure whereas, in microcosm, SWAc group showed an increase of total motility on day 14. In addition, sperm morphology and intracellular pH were affected in both experimental approaches; whereas oxidative stress was detected only in spermatozoa collected from mussels under natural SWAc. The overall analysis suggests that, in mussels, SWAc toxic mechanism in spermatozoa does not involve oxidative stress. This study represents the first report on mussel sperm quality impairment after adult SWAc exposure, which may affect fertilization success with negative ecological and economic consequences; it also indicates that, although naturally acidified areas represent ideal natural laboratories for investigating the impact of ocean acidification, microcosm experiments are necessary for examining action mechanisms.
显示更多 [+] 显示较少 [-]Seawater carbonate chemistry and sperm physiology in Mytilus galloprovincialis 全文
2020
Gallo, Alessandra | Esposito, Maria Consiglia | Cuccaro, Alessia | Buia, Maria-Cristina | Tarallo, Andrea | Monfrecola, Vincenzo | Tosti, Elisabetta | Boni, Raffaele
The ongoing increase of CO2 in the atmosphere is inducing a progressive lowering of marine water pH that is predicted to decrease to 7.8 by the end of this century. In marine environment, physical perturbation may affect reproduction, which is crucial for species' survival and strictly depends on gamete quality. The effects of seawater acidification (SWAc) on gamete quality of broadcast spawning marine invertebrates result largely from experiments of gamete exposure while the SWAc impact in response to adult exposure is poorly investigated. Performing microcosm and in field experiments at a naturally acidified site, we investigated the effects of adult SWAc exposure on sperm quality parameters underlying fertilization in Mytilus galloprovincialis. These animals were exposed to pH 7.8 over 21 days and collected at different times to analyze sperm parameters as concentration, motility, viability, morphology, oxidative status, intra- and extra-cellular pH and mitochondrial membrane potential. Results obtained in the two experimental approaches were slightly different. Under field conditions, we found an increase in total sperm motility and mitochondrial membrane potential on days 7 and 14 from the start of SWAc exposure whereas, in microcosm, SWAc group showed an increase of total motility on day 14. In addition, sperm morphology and intracellular pH were affected in both experimental approaches; whereas oxidative stress was detected only in spermatozoa collected from mussels under natural SWAc. The overall analysis suggests that, in mussels, SWAc toxic mechanism in spermatozoa does not involve oxidative stress. This study represents the first report on mussel sperm quality impairment after adult SWAc exposure, which may affect fertilization success with negative ecological and economic consequences; it also indicates that, although naturally acidified areas represent ideal natural laboratories for investigating the impact of ocean acidification, microcosm experiments are necessary for examining action mechanisms.
显示更多 [+] 显示较少 [-]An integrated assessment of land-use change impact, seasonal variation of pollution indices and human health risk of selected toxic elements in sediments of River Atuwara, Nigeria 全文
2020
Emenike, PraiseGod Chidozie | Tenebe, Imokhai Theophilus | Neris, Jordan Brizi | Omole, David Olugbenga | Afolayan, Olaniyi | Okeke, Chukwueloka Udechukwu | Emenike, Ikechukwu Kingsley
River sediments contain environmental fingerprints that provide useful ecological information. However, the geochemistry of River Atuwara sediments has received less attention over the years. One hundred and twenty-six sediments from 21 locations were collected over a two-season period from River Atuwara, and a detailed investigation of the land use and land cover (LULC) change between 1990 and 2019, analysis of selected toxic and potentially toxic metal(oid)s (TPTM) (Cu, As, Cd, Pb, Ni, Cr, Zn, Fe, Co and Al) using ICP-OES, pollution index assessment, potential source identification (using center log-transformation approach), potential ecological, and human health risk assessment were conducted. The results of the LULC change revealed that the built-up area increased by 95.58 km², at an average rate of 3.186 km²/year over the past 30 years. The mean concentration of metal(oid)s increased in the order of Cd < As < Cr < Pb < Co < Ni < Cu < Zn < Fe < Al, and Cd < As < Cr < Co < Pb < Ni < Cu < Zn < Fe < Al during the dry and wet seasons, respectively. Meanwhile, the statistical analysis of the data spectrum inferred possible contamination from lithological and anthropogenic sources. According to the pollution load index, 90.48% of the sediment samples are polluted by the metal(oid)s. Potential ecological risk assessment identified Ni, As, and Cd as problematic to the ecological community of River Atuwara. Regarding the metal-specific hazard quotient via ingestion route, the risks are in order of Co ≫ As ≫ Pb > Cr > Cd > Al > Ni > Cu > Zn > Fe for both seasons and the carcinogenic risk for children via ingestion route presented a value higher than the safe limits for As, Cd, Cr, and Ni during both seasons. This outcome highlights the need for prompt action towards the restoration of environmental quality for communities surrounding River Atuwara.
显示更多 [+] 显示较少 [-]Formaldehyde and VOC emissions from plywood panels bonded with bio-oil phenolic resins 全文
2020
Jia, Liangliang | Chu, Jie | Li, Jing | Ren, Jing | Huang, Ping | Li, Dongbing
Pyrolysis bio-oil was used to partially substitute for phenol in reacting with formaldehyde for the production of bio-oil phenol formaldehyde plywood (BPFP) panels, with the phenol substitution ratio being 20%, 40%, or 60%. Emissions of formaldehyde and volatile organic compounds (VOCs) from the BPFP panels were studied using solid-phase micro-extraction (SPME) followed by headspace gas chromatography/mass spectrometry (GC/MS), and were compared to those from the phenol formaldehyde plywood (PFP) panels. The sources for VOCs were analyzed, and the health risks associated with the BPFP were examined. Results showed that at 80 °C: (1) Formaldehyde emissions from the BPFP panels were increased to about 4 times that of PFP; (2) VOCs emissions were significantly reduced by up to 84.9% mainly due to the greatly reduced phenol emissions, although the total number of VOCs was increased from 20 to 35; (3) BPFP presents greatly increased carcinogenic and non-carcinogenic health risks because of its much stronger emissions of formaldehyde, N,N-dimethylformamide, benzofuran, furfural, and many chemicals from the bio-oil. It is highly advisable that the health risks are properly taken care of before the wide application of BPFP, or similar bio-oil based engineered wood products.
显示更多 [+] 显示较少 [-]Degradation of glyphosate in a Colombian soil is influenced by temperature, total organic carbon content and pH 全文
2020
Muskus, Angelica M. | Krauss, Martin | Miltner, Anja | Hamer, Ute | Nowak, Karolina M.
Glyphosate is one of the most used herbicides in the world. The fate of glyphosate in tropical soils may be different from that in soils from temperate regions. In particular, the amounts and types of non-extractable residues (NER) may differ considerably, resulting in different relative contributions of xenoNER (sorbed and sequestered parent compound) and bioNER (biomass residues of degraders). In addition, environmental conditions and agricultural practices leading to total organic carbon (TOC) or pH variation can alter the degradation of glyphosate. The aim of this study is thus to investigate how the glyphosate degradation and turnover are influenced by varying temperature, pH and TOC of sandy loam soil from Colombia. The pH or TOC of a Colombian soil was modified to yield five treatments: control (pH 7.0, TOC 3%), 4% TOC, 5% TOC, pH 6.5, and pH 5.5. Each treatment received 50 mg kg⁻¹ of ¹³C₃¹⁵N-glyphosate and was incubated at 10 °C, 20 °C and 30 °C for 40 days. Rising temperature increased the mineralization of ¹³C₃¹⁵N-glyphosate from 13 to 20% (10 °C) to 32–39% (20 °C) and 41–51% (30 °C) and decreased the amounts of extractable ¹³C₃¹⁵N-glyphosate after 40 days of incubation from 13 to 26% (10 °C) to 4.6–12% (20 °C) and 1.2–3.2% (30 °C). Extractable ¹³C₃¹⁵N-glyphosate increased with higher TOC and higher pH. Total ¹³C-NER were similar in all treatments and at all temperatures (47%–60%), indicating that none of the factors studied affected the amount of total ¹³C-NER. However, ¹³C-bioNER dominated within the ¹³C-NER pool in the control and the 4% TOC treatment (76–88% of total ¹³C-NER at 20 °C and 30 °C), whereas in soil with 5% TOC and pH 6.5 or 5.5 ¹³C-bioNER were lower (47–61% at 20 °C and 30 °C). In contrast, the ¹⁵N-bioNER pool was small (between 14 and 39% of the ¹⁵N-NER). Thus, more than 60% of ¹⁵N-NER is potentially hazardous xenobiotic NER which need careful attention in the future.
显示更多 [+] 显示较少 [-]Glyphosate exposures and kidney injury biomarkers in infants and young children 全文
2020
Trasande, Leonardo | Aldana, Sandra India | Trachtman, Howard | Kannan, Kurunthachalam | Morrison, Deborah | Christakis, Dimitri A. | Whitlock, Kathryn | Messito, Mary Jo | Gross, Rachel S. | Karthikraj, Rajendiran | Sathyanarayana, Sheela
The goal of this study was to assess biomarkers of exposure to glyphosate and assess potential associations with renal function in children. Glyphosate is used ubiquitously in agriculture worldwide. While previous studies have indicated that glyphosate may have nephrotoxic effects, few have examined potential effects on kidney function in children. We leveraged three cohorts across different phases of child development and measured urinary levels of glyphosate. We evaluated associations of glyphosate with three biomarkers of kidney injury: albuminuria (ACR), neutrophil gelatinase-associated lipocalin (NGAL), and kidney injury marker 1 (KIM-1). Multivariable regression analyses examined associations of glyphosate with kidney injury biomarkers controlling for covariates. We identified glyphosate in 11.1% of the total participants. The herbicide was detected more frequently in the neonate population (30%). Multivariable regression models failed to identify significant associations of log-transformed glyphosate with any of the kidney injury biomarkers, controlling for covariates age, sex, and maternal education. While we confirm detectability of glyphosate in children’s urine at various ages and stages of life, there is no evidence in this study for renal injury in children exposed to low levels of glyphosate. Further studies of larger sample size are indicated to better understand putative deleterious effects of the herbicide after different levels of exposure.
显示更多 [+] 显示较少 [-]Response of soil native microbial community to Eschericia coli O157:H7 invasion 全文
2020
Xing, Jiajia | Sun, Shanshan | Wang, Haizhen | Brookes, Philip C. | Xu, Jianming
The presence of Eschericia coli O157:H7 in the natural environment is a serious threat to human health. The native microbial community in soil plays an important role in resisting E. coli O157:H7 invasion. This study examined the responses of soil microbial community to E. coli O157:H7 invasion during a 32-day incubation. The E. coli O157:H7 persisted longer in γ-irradiated soil than non-irradiated soil while glucose addition decreased its persistence in the irradiated soil which was associated with an increasing recovery of the native community. The invasion of E. coli O157:H7 increased soil organic carbon mineralization, an indicator of microbial activity, in both non-irradiated and irradiated soils, while glucose addition significantly promoted the carbon mineralization process. The 16S rRNA sequencing data showed the gradual recovery of the native bacterial population including specific taxa such as proteobacteria and actinobacteria following irradiation. It is concluded that soil microbial function and structure can affect persistence of E. coli O157:H7 and that lower biodiversity of the native community favors its persistence.
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