Gasification and pyrolysis technologies have been widely employed to produce fuels and chemicals from solid wastes. Rare studies have been conducted to compare the particulate emissions from gasification and pyrolysis, and relevant inhalation exposure assessment is still lacking. In this work, we characterized the particles emitted from the gasification and pyrolysis experiments under different temperatures (500, 600, and 700 °C). The collection efficiencies of existing cyclones were compared based on particle respiratory deposition. Sensitivity analysis was conducted to identify the most effective design parameters. The particles emitted from both gasification and pyrolysis process are mainly in the size range 0.25–1.0 μm and 1.0–2.5 μm. Particle respiratory deposition modelling showed that most particles penetrate deeply into the last stage of the respiratory system. At the nasal breathing mode, particles with sizes ranging from 0.25 to 1.0 μm account for around 91%, 74%, 76%, 90%, 84%, and 79% of the total number of particles that deposit onto the last stage in the cases of 500 °C gasification, 600 °C gasification, 700 °C gasification, 500 °C pyrolysis, 600 °C pyrolysis, and 700 °C pyrolysis, respectively. At the oral breathing mode, particles with sizes ranging from 0.25 to 1.0 μm account for around 92%, 77%, 79%, 91%, 86%, and 81% of the total number of particles that deposit onto the last stage in the six cases, respectively. Sensitivity analysis showed that the particle removal efficiency was found to be most sensitive to the cyclone vortex finder diameter (D₀). This work could potentially serve as the basis for proposing health protective measures against the particulate pollution from gasification and pyrolysis technologies.

The upper Columbia River and associated valley systems are highly contaminated with metal wastes from nearby smelting operations in Trail, British Columbia, Canada (Teck smelter), and to a lesser extent, Northport, Washington, USA (Le Roi smelter). Previous studies have investigated depositional patterns of airborne emissions from these smelters, and documented the Teck smelter as the primary metal contamination source. However, there is limited research directed at whether these contaminants are bioavailable to aquatic organisms. This study investigates whether smelter derived contaminants are bioavailable to freshwater zooplankton. Trace metal (Zn, Cd, As, Sb, Pb and Hg) concentrations and Pb isotope compositions of zooplankton and sediment were measured in lakes ranging from 17 to 144 km downwind of the Teck smelter. Pb isotopic compositions of historic ores used by both smelters are uniquely less radiogenic than local geologic formations, so when zooplankton assimilate substantial amounts of smelter derived metals their compositions deviate from local baseline compositions toward ore compositions. Sediment metal concentrations and Pb isotope compositions in sediment follow significant (p < 0.001) negative exponential and sigmoidal patterns, respectively, as distance from the Teck smelting operation increases. Zooplankton As, Cd, and Sb contents were related to distance from the Teck smelter (p < 0.05), and zooplankton Pb isotope compositions suggest As, Cd, Sb and Pb from historic and current smelter emissions are biologically available to zooplankton. Zooplankton from lakes within 86 km of the Teck facility display isotopic evidence that legacy ore pollution is biologically available for assimilation. However, without water column data our study is unable to determine if legacy contaminants are remobilized from lake sediments, or erosional pathways from the watershed.

Metal enrichment of road dust is well characterized but available data on the bioaccessibility of metals in particle size fractions relevant to human respiratory health remain limited. The study goal was to investigate the bioaccessibility of platinum group elements (PGE), which are used as catalysts in automotive exhaust converters, in the inhalable fraction of road dust. Street sweepings were provided by the City of Toronto, Canada, collected as part of its Clean Roads to Clean Air program.The particle size relevance of road dust for inhalation exposures was confirmed using a laser diffraction particle size analyzer (mean Dx(50): 9.42 μm). Total PGE were determined in both bulk and inhalable fractions using nickel sulfide (NiS) fire-assay and instrumental neutron-activation analysis (INAA). PGE lung solubility was examined for the inhalable fraction using Gamble’s extraction. Sample digests were co-precipitated with Te-Sn, to pre-concentrate and isolate PGE, prior to their measurement using inductively coupled plasma mass spectrometry (ICP-MS).Total PGE concentrations were enriched in the inhalable fraction of road sweepings. Geomean concentrations in the inhalable fraction were: palladium (Pd) (152 μg/kg), platinum (Pt) (55 μg/kg), rhodium (Rh) (21 μg/kg) and iridium (Ir) (0.23 μg/kg). Osmium (Os) concentrations were below the limit of detection (LOD). Bioaccessible PGEs (n = 16) using Gamble’s solution were below LOD for Ir and ruthenium (Ru). For the remainder, the geomean % bioaccessibility was highest for platinum (16%), followed by rhodium (14%) and palladium (3.4%). This study provides evidence that PGE in road dust are bioaccessible in the human lung.

Microplastic contamination was investigated in the gut contents of an economically important estuarine top predator, Cynoscion acoupa, according to spatiotemporal and ontogenetic use of a tropical estuary. Microplastic contamination was found in more than half of the analysed fish. Ingested microplastics were classified by type, colour and length with most of the particles consisting of filaments (<5 mm). Longer filaments were more frequently ingested in the upper estuary and smaller filaments in the lower estuary, as a result of differences in hydrodynamic forces and proximity to the probable input sources. The river is likely an important source of filaments to the estuary and filaments ingested in the upper estuary showed little sign of weathering, when compared with those from the lower estuary, which are subject to intense weathering and consequent break-up of particles to smaller sizes. Most filaments, of all colours, accumulated in adults of C. acoupa, which are more susceptible to contamination through both direct ingestion and trophic transference as they shift their feeding mode to piscivory. Moreover, the highest ingestion of filaments in adults occurred in the lower estuary, during the late rainy season, likely associated with the intense fishing activities in this habitat, which results in a greater input of filaments from fishing gear, which are mainly blue in colour. Overall, 44% of the ingested filaments were blue, 20% purple, 13% black, 10% red and 12% white. The next most common colour, the purple filaments, are most likely blue filaments whose colour has weathered to purple. Red filaments were proportionally more ingested in the lower estuary, indicating a coastal/oceanic source. White and black filaments were more commonly ingested in the inner estuary, suggesting that they have a riverine origin and/or were actively ingested by juveniles and sub-adults, which inhabit the inner estuary and have zooplankton as an important food resource.

Contamination of agricultural soils by pharmaceutical and personal care products (PPCPs) resulting from the application of treated wastewater, biosolids and animal wastes constitutes a potential environmental risk in many countries. To date a handful of studies have considered the phytotoxicity of individual PPCPs in crop plants, however, little is known about the effect of PPCPs as mixtures at environmentally relevant levels. This study investigated the uptake and transport, physiological responses and detoxification of a mixture of 17 PPCPs in cucumber seedlings. All PPCPs were detected at higher concentrations in roots compared to leaves, with root activity inhibited in a dose-dependent manner. At 5–50 μg/L, the mature leaves exhibited burnt edges as well as a reduction in photosynthesis pigments. Reactive oxygen species (ROS) production and lipid peroxidation increased with increasing PPCP concentrations; and their contents were greater in roots than in leaves for all PPCP treatments. Enzymes involved in various functions, including oxidative stress (superoxide dismutase and ascorbate peroxidase) and xenobiotic metabolism (peroxidase and glutathione S-transferase), were elevated to different levels depending on the PPCP concentration. Glutathione content gradually increased in leaves, while a maxima occurred at 0.5 μg L⁻¹ PPCPs in roots, followed by a decrease thereafter. This study illustrated the complexity of phytotoxicity after exposure to PPCP mixtures, and provided insights into the molecular mechanisms likely responsible for the detoxification of PPCPs in higher plants.

Organisms have long been treated as receptors in exposure studies of polychlorinated biphenyls (PCBs) and other persistent organic pollutants (POPs). The influences of environmental pollution on organisms are well recognized. However, the impact of biota on PCB transport in an environmental system has not been considered in sufficient detail. In this study, a population-based multi-compartment fugacity model is developed by reconfiguring the organisms as populated compartments and reconstructing all the exchange processes between the organism compartments and environmental compartments, especially the previously ignored feedback routes from biota to the environment. We evaluate the model performance by simulating the PCB concentration distribution in Lake Ontario using published loading records. The lake system is divided into three environment compartments (air, water, and sediment) and several organism groups according to the dominant local biotic species. The comparison indicates that the simulated results are well-matched by a list of published field measurements from different years. We identify a new process, called Facilitated Biotic Intermedia Transport (FBIT), to describe the enhanced pollution transport that occurs between environmental media and organisms. As the hydrophobicity of PCB congener increases, the organism population exerts greater influence on PCB mass flows. In a high biomass scenario, the model simulation indicates significant FBIT effects and biotic storage effects with hydrophobic PCB congeners, which also lead to significant shifts in systemic contaminant exchange rates between organisms and the environment.

Understanding the effect of natural colloidal particles (NCPs) on the photochemistry of organic pollutants is crucial to predict the environmental persistence and fate of them in surface waters, and it is, yet, scarcely elucidated. In this study, the pre-filtered surface water (through a 1 μm capsule filter) from Baiyangdian Lake was further separated into four different size NCPs: F1 (0.65–1.0 μm), F2 (100 kD-0.65 μm), F3 (10–100 kD) and F4 (1–10 kD) by cross-flow ultrafiltration (CFUF), and the photochemical kinetics and mechanisms of ofloxacin (OFL) and enrofloxacin (ENR) were investigated in the presence of those particles under simulated sunlight. Results showed that OFL and ENR underwent both direct and indirect photolysis in F1-F4 solutions, and the observed pseudo first-order rate constants (kobs) for target compounds differed depending on the size of NCPs. Direct photolysis accounted for >50% of the degradation in all cases and was the dominant degradation pathway for the two target antibiotics with the exception of OFL in F1 solution. Except for ENR in both F3 and F4 solutions, nearly all NCPs enhanced the degradation of both target compounds by indirect photolytic pathways, especially in F1 solution that showed the largest reactivity for OFL and ENR, promoting the reactions by 63% and 41%, respectively. The excited state colloidal organic matter (3COM∗) plays a significant role in the indirect photolysis, and the adsorptions of OFL and ENR to NCPs were likely to have a pronounced effect in the photochemistry process. Pearson's correlations analysis showed that the kobs(OFL) was significant positive correlated with binding of Fe (r = 0.963, P < 0.05), and the kobs(ENR) was significant positive correlated with the adsorption percentage of OFL (r = 0.999, P < 0.01).This paper has demonstrated that different size NCPs showed the different photochemical contribution to the reaction rate for OFL and ENR.

A new Land Use Regression model was built to develop pan-European 100 m resolution maps of NO2 concentrations. The model was built using NO2 concentrations from routine monitoring stations available in the Airbase database as dependent variable. Predictor variables included land use, road traffic proxies, population density, climatic and topographical variables, and distance to sea. In order to capture international and inter regional disparities not accounted for with the mentioned predictor variables, additional proxies of NO2 concentrations, like levels of activity intensity and NOx emissions for specific sectors, were also included. The model was built using Random Forest techniques. Model performance was relatively good given the EU-wide scale (R2 = 0.53). Output predictions of annual average concentrations of NO2 were in line with other existing models in terms of spatial distribution and values of concentration. The model was validated for year 2015, comparing model predictions derived from updated values of independent variables, with concentrations in monitoring stations for that year. The algorithm was then used to model future concentrations up to the year 2030, considering different emission scenarios as well as changes in land use, population distribution and economic factors assuming the most likely socio-economic trends. Levels of exposure were derived from maps of concentration. The model proved to be a useful tool for the ex-ante evaluation of specific air pollution mitigation measures, and more broadly, for impact assessment of EU policies on territorial development.

Acetochlor is a widely used chloroacetanilide herbicide and has posed environmental risks in soil and water due to its toxicity and high leaching capacity. Earthworm represents the dominant invertebrate in soil and can promote the decomposition of organic pollutants. The effect of earthworm on acetochlor degradation in soil was studied by soil column experiment with or without acetochlor and earthworm in sterile and natural soils. The degradation capacities of drilosphere components to acetochlor were investigated by microcosm experiments. Bacterial and fungal acetochlor degraders stimulated by earthworm were identified by high-throughput sequencing. The degradation kinetics of acetochlor suggested that both indigenous microorganisms and earthworm played important roles in acetochlor degradation. Acetochlor degradation was quicker in soil with earthworms than without earthworms, with the degradation rates increased by 62.3 ± 15.2% and 9.7 ± 1.7% in sterile and natural treatments respectively. The result was related to the neutralized pH, higher enzyme activities and enhanced soil microbial community diversity and richness in the presence of earthworms. Earthworm cast was the degradation hotpot in drilosphere and exhibited better anaerobic degradation capacity in microcosm experiments. The acetochlor degradation rate of cast in anaerobic environment was 12.0 ± 0.1% quicker than that in aerobic environment. Residual acetochlor in soil conferred a long-term impairment on fungal community, and this inhibition could be repaired by earthworm. Earthworm stimulated indigenous degraders like Sphingomonas and Microascales and carried suspected intestinal degraders like Mortierella and Escherichia_coli to degradation process. Cometabolism between nutrition cycle species and degraders in casts also contributed to its faster degradation rates. The study also presented some possible anaerobic degradation species like Rhodococcus, Pseudomonas_fulva and Methylobacillus.