The current study focuses on the removal of perchlorate in water using single-walled carbon nanotubes (SWCNTs) and granular ferric hydroxide as sorbents. The randomly distributed tubes were observed by scanning electron microscopy. The influence of temperature and content of natural humic acid on the perchlorate adsorption capacity was examined at pH 3. The adsorption data were fitted with three models: modified Freundlich, pseudo-first order, and pseudo-second order. The modified Freundlich model produced the best fit to describe the kinetic adsorption processes. The adsorption capacities of perchlorate measured at 25 °C and pH 3 using single-walled carbon nanotubes and granular ferric hydroxide were about 6 and 3 mg/g, respectively. The influence of natural humic acid on perchlorate adsorption by SWCNTs was examined. Natural humic acid was derived from raw water in Gao-Ping River in south Taiwan. Lower adsorption reaction rates of perchlorate were obtained at higher humic acid concentrations. High humic acid concentrations induce the compression of the electric double layer that consequently reduces the surface potential energy and electrostatic repulsion.

Early-life exposure to pollutants, such as lead, may have long-lasting consequences on health, behavior, and cognition. However, experiments on delayed effects of specific pollutants are very rare in wild animals. We experimentally exposed wild nestling great tits (Parus major) to dietary lead (high, low, or control group) in levels relevant to exposure levels of wild populations in Europe and studied delayed effects on phenotypic and behavioral traits in captivity. We also included a group of birds from a vicinity of a copper smelter, exposed to a mixture of toxic metals and altered food supply during development. This experimental setup allowed us to compare the strength of direct (exposure to lead per se) and indirect (pollution-related changes in diet) effects of pollutants. Our experimental lead treatment significantly increased lead levels in bone and feces compared with controls. However, we found no carry-over effect of early-life dietary lead on morphology, plumage coloration, or heat shock proteins. Treatment did not affect activity, exploration, neophobia, or success in learning and spatial memory task. We conclude that with the exposure levels and relatively short exposure period used, delayed effects on the measured traits were not found. However, it is important to further study other types of behavioral traits and ultimately fitness effects.

Hundreds of millions of people are at risk from drinking arsenic (As)-contaminated groundwater in the world, making As removal from aquatic systems of utmost importance. However, characteristics of As removal by bacteria-induced ferrihydrite and coupled with redox processes are still not clear. Two-line ferrihydrite was formed in the presence of aerobic Fe(II)-oxidizing bacterium, Pseudomonas sp. strain GE-1. Arsenic co-precipitation with and adsorption onto ferrihydrite induced by Pseudomonas sp. strain GE-1 and redox processes of As were investigated. Results demonstrated that co-precipitation performed better in As(V) removal than As(III) removal, while adsorption showed higher capacity for As(III) removal. X-ray absorption near-edge spectroscopy (XANES) indicated that As(III) oxidation occurred in solid phases during co-precipitation and adsorption. Detection of As species in solution showed that As(V) was reduced to As(III) during co-precipitation, although no As(V) reduction occurred during adsorption. Arsenic immobilization by Pseudomonas sp. strain GE-1-induced ferrihydrite in the presence of the strains may be applied as an alternative remediation strategy.

Aeolian dust from hot spots in eastern China and Mongolia can be carried downwind to provinces in China, neighboring countries, the Pacific islands, and cities far beyond the source region. Although dust sources of huge extent have been identified in several countries, few effective countermeasures are available to combat dust emissions in arid regions. We analyzed Moderate Resolution Imaging Spectroradiometer (MODIS) images (1 km spatial resolution) that captured dust emission and dispersion during 2000–2013 to determine dust sources in eastern China and Mongolia. MODIS level 1B data and the brightness temperature difference (BTD) algorithm provided efficient discrimination of dust in this study. The derived dust information, in conjunction with the MODIS land cover product (1 km spatial resolution) and high-resolution Landsat data (30 m spatial resolution; Landsat 8, Operational Land Imager sensor) were used to identify the locations and specific sources of dust. Dust emissions appear to be sporadic in time and space, controlled by both environmental factors and human activity, although past studies have indicated that many dust emissions are from consistently active hot spots. Analysis of MODIS data indicated that three subregions of the eastern China and Mongolia source region are the dominant sources of dust: Horqin Sandy Land, Otintag Sandy Land, and the southeastern Mongolian Gobi; each of these subregions contains dust emission hot spots. We identified the locations of consistent hot spots and verified that some individual dust emissions originated from those hot spots. Our data also indicated that hot spots in southeastern Mongolia have migrated northward since 2006. Our study showed that hot spots such as dry lakes, river beds, mines, and croplands contribute to dust emissions in the eastern China and Mongolia source region. Dust hot spots coincide with regions of expanding industry in Otintag Sandy Land and in some areas of the Mongolian Gobi and with agricultural areas in Horqin Sandy Land and in some parts of the Mongolian Gobi. In Horqin and Otintag sandy lands, dust sources are associated with ephemeral water bodies. Water conservation can be an important countermeasure for initial dust emissions in the Horqin Sandy Land. In the Otintag Sandy Land, attention should be paid to human activities, for example, minimizing the effects of mining disturbances, improving dust suppression in industrial areas, and controlling water use by industry. In Mongolia, protective farming techniques and water conservation in dust emitting basins, and dust suppression and water resource protection in mining zones, must be considered to combat dust emission. MODIS level 1B data can be used to locate dust hot spots and to identify future sources of dust entrainment. Dust hot spots identified from MODIS level 1B data provide small-scale information about dust emission that can be used to locate pollution hot spots, increase understanding of the global dust cycle, and improve dust modeling.

Carbamazepine (CBZ) is a representative of a group of compounds found in our rivers that have been classified as upcoming contaminants. Its pharmacological activity to treat mood and neurological disorders is based on its effects on ion channels, but effects on aquatic organisms have not yet been thoroughly investigated.In our initial analysis, we compared CBZ effects on two microalgae species differing in CBZ sensitivity: Parachlorella kessleri and Neochloris pseudoalveolaris. While we observed a stimulation in the growth rate in cultures of P. kessleri in the presence of 10 μg L⁻¹ CBZ, no effect on growth rates of N. pseudoalveolaris cultures could be documented at this concentration. Any higher tested CBZ concentration led to growth inhibition.To gain insight into these effects, biochemical and physiological parameters of these two microalgae species were measured in the presence of CBZ in a concentration-dependent manner.As the severe inhibition of growth rate correlated with a significant inhibition of most tested parameters in cultures of N. pseudoalveolaris, the primary reason for the adverse effect of CBZ on cultures of this microalgae species could not be identified. In cultures of N. pseudoalveolaris, experimental data indicate that inhibition of growth rate occurs when the microalgae are no longer able to compensate for adverse CBZ-induced ROS effects.Analysis of the CBZ response of cultures of P. kessleri showed a reduction of growth stimulatory effect if the CBZ concentration exceeds a threshold value. In general, cultures of P. kessleri show a great potential to withstand CBZ as an environmental pollutant.

The presence of pharmaceuticals and personal care products (PPCPs) as trace pollutants in natural surface water bodies, ground water and drinking water has recently led to some concern. Advanced oxidation processes (AOPs), which utilize free radical reactions to degrade chemical contaminates, are an alternative to traditional water treatment. Anti-inflammatory drug balsalazide (as model compounds) besides actual wastewater samples were UV photodegraded using suspended titanium silicon oxide (TiSiO₄) or UV/H₂O₂/O₂ systems. The photodegradation was favourable in the pH 8–12.8 range. The effect of various parameters such as photocatalyst amount, balsalazide (BSZ) concentration, pH of aqueous solution, irradiation time, addition of H₂O₂ and temperature on photocatalytic oxidation was investigated. The kinetics of the photocatalytic oxidation of BSZ in aqueous TiSiO₄ suspensions was investigated as a function of catalyst loading (2–12 mg/L) and the concentration of BSZ (0.01–0.05 mg/mL) at pH 11.5. The optimum conditions for the degradation of the BSZ have been found as 0.045 mg/mL drug concentration, pH 11.5 and 0.1 g/L catalyst dose. The results indicated that the photocatalytic degradation of BSZ was well described by pseudo-first-order kinetics according to the Langmuir–Hinshelwood model. The effect of temperature on the efficiency of photodegradation of BSZ was also studied in the range 278–298 K. The activation energy was calculated according to Arrhenius plot and was found equal to 24 ± 1 kJ mol⁻¹ for TiSiO₄. Decolourization and mineralization of BSZ in the absence of light and/or catalyst were performed to demonstrate that the presence of light and catalyst is essential for the decolourization of this BSZ. This work adds to the global discussion on the role of the advanced oxidation processes in water treatment.

Despite the decreased emission loads of mercury, historical deposits of this metal in various compartments of the environment may become an additional diffuse source in the future. Global climate change manifests itself in the temperate zone in several ways: warmer winters, shorter icing periods, increased precipitation and heightened frequency of extreme events such as strong gales and floods, all of which cause disturbances in the rate and direction of mercury biogeochemical cycling. The present study was conducted at two sites, Oslonino and Gdynia Orlowo (both in the coastal zone of the Gulf of Gdansk), from which samples were collected once a month between January 2012 and December 2012. In the Southern Baltic region, climate changes can certainly enhance coast to basin fluxes of mercury and the transfer of bioavailable forms of this metal to the food web. They may also, in the future, contribute to uncontrollable increases of mercury in the seawater.

This study aimed to decolourise different dyes using two Klebsiella strains (Bz4 and Rz7) in different concentrations and incubation conditions. Azo (Evans blue (EB)) and triphenylmethane (brilliant green (BG)) dyes were used individually and in mixture. The toxicity of the biotransformation products was estimated. Both strains had a significant potential to decolourise the dyes in the fluorone, azo and triphenylmethane classes. The type and concentration of dye affects the decolourisation effectiveness. Differences in the dye removal potential were observed particularly in the main experiment. The best results were obtained for Bz4 in the samples with EB (up to 95.4 %) and dye mixture (up to 99 %) and for Rz7 with BG (100 %). The living and dead biomass of the strain Bz4 highly absorbs the dyes. Significant effect of the process conditions was noticed for both strains. The best results were obtained in static and semistatic samples (89–99 %) for the removal of EB and a mixture of dyes and in static samples (100 %) for BG. The decrease in zootoxicity (from class IV/V) was noticed in all samples with living biomass of the strain Bz4 (to class III/IV) and in samples with single dyes for Rz7 (to class III/IV). The decrease in phytotoxicity (from class III/IV) was noticed for Bz4 in the samples with BG and a mixture (to class III) and for Rz7 in the samples with BG (to class III). The process conditions did not affect the changes in toxicity after the process.

This study aimed to evaluate the removal of polychlorinated biphenyls, with a vermicomposting system, using the following as components: the earthworm Eisenia fetida, peat moss and rabbit excrement and a compound called decachlorobiphenyl, for a period of 91 days under non-sterile conditions. The results obtained were a removal of decachlorobiphenyl 79.6 % with an initial concentration of 100 mg L⁻¹, 89.7 % with 150 mg L⁻¹and 95.38 % with 200 mg L⁻¹; the earthworms bioaccumulated less than 5 mg L⁻¹in all concentrations of decachlorobiphenyl analysed without apparent toxic effect. Weight gain was observed in earthworms that assimilated contaminant during vermicomposting, as the number of cocoons produced in contrast to the control in which both the weight and the number of cocoons were lower. To our knowledge, this is the first study which suggests that vermicomposting may be a suitable mechanism for removal of decachlorobiphenyl with high recalcitrance from contaminated sediment or soils.

Cr interactions with TiO₂were systematically studied using batch and spectroscopic investigations. Sorption of chromium on TiO₂at pH 4.5 increases with increasing Cr concentration. The sorption of Cr(III) is in good agreement with Langmuir isotherm model, whereas that of Cr(VI) is better accounted for by the Freundlich model. At pH 7.0, however, the uptake of Cr(III) by TiO₂is over 95 %, while the extent of Cr(VI) sorption on TiO₂is much less than that of pH 4.5. These results are consistent with SEM observations showing that precipitates of Cr(III) are dominant under neutral pH. The sorption of Cr(VI) on TiO₂decreases with increasing pH. However, Cr(VI) sorption decreases with increasing ionic strength below pH 4.5 whereas the sorption increases with ionic strength above pH 4.5. These observations suggest that Cr(VI) sorption is sensitive to ionic strength, and Cr(VI) could form weakly bound adsorption complexes at the TiO₂–water interface. Phosphate competes with Cr(VI) for TiO₂surface sites during sorption processes, and Cr(VI) desorption accelerates and increases in the presence of phosphate. It is noted that the reduction of Cr(VI) is induced by sunlight on the TiO₂surface, but not detected in acidic solution throughout batch experiments at pH ≥ 4.5 for 24 h.