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A review of polymer nanofibres by electrospinning and their application in oil–water separation for cleaning up marine oil spills
2016
Sarbatly, Rosalam | Krishnaiah, Duduku | Kamin, Zykamilia
The growths of oil and gas exploration and production activities have increased environmental problems, such as oil spillage and the resulting pollution. The study of the methods for cleaning up oil spills is a critical issue to protect the environment. Various techniques are available to contain oil spills, but they are typically time consuming, energy inefficient and create secondary pollution. The use of a sorbent, such as a nanofibre sorbent, is a technique for controlling oil spills because of its good physical and oil sorption properties. This review discusses about the application of nanofibre sorbent for oil removal from water and its current developments. With their unique physical and mechanical properties coupled with their very high surface area and small pore sizes, nanofibre sorbents are alternative materials for cleaning up oil spills.
显示更多 [+] 显示较少 [-]Optimization of hard clams, polychaetes, physical disturbance and denitrifying bacteria of removing nutrients in marine sediment
2016
Shen, Hui | Thrush, Simon F. | Wan, Xihe | Li, Hui | Qiao, Yi | Jiang, Ge | Sun, Ruijian | Wang, LiBao | He, Peimin
Marine organisms are known to play important roles in transforming nutrients in sediments, however, guidelines to optimize sediment restoration are not available. We conducted a laboratory mesocosm experiment to investigate the role of hard clams, polychaetes, the degree of physical disturbance and denitrifying bacterial concentrations in removing total nitrogen (TN), total phosphorus (TP), and total organic carbon (TOC) in marine sediments. Response surface methodology was employed to analyze the results of initial experiments and in a subsequent experiment identified optimal combinations of parameters. Balancing the TN, TP, TOC removal efficiency, our model predicted 39% TN removal, 33% TP removal, and 42% TOC removal for a 14-day laboratory bioremediation trial using hard clams biomass of 1.2kgm−2, physical disturbance depth of 16.4cm, bacterial density of 0.18Lm−2, and polychaetes biomass of 0.16kgm−2, respectively. These results emphasize the value of combining different species in field-based bioremediation.
显示更多 [+] 显示较少 [-]Priority pesticides in sediments of European coastal lagoons: A review
2016
Pinto, M.I. | Burrows, Hugh | Sontag, G. | Vale, C. | Noronha, J.P.
This review summarizes the legislation applied to pesticides and highlights the physicochemical properties of the past and recently listed PPs under Water Framework Directive (WFD). It reports important information regarding the analysis, occurrence and long-term screening of PPs in sediments of European coastal lagoons. Among the entire list of PPs, those analyzed have been the organochloride insecticides, such as lindane, hexachlorobenzene and DDT. Although flood events pointed to the possible redistribution of pesticides, which may increase under climate change conditions, few studies are available concerning PPs screening in sediments of European coastal lagoons. Data is scarce not only in terms of the number of listed PPs that have been analyzed but also in terms of their long-term screening. This lack of data on PP concentrations is probably a consequence of the fact that less importance is given to the sediments contamination/quality.
显示更多 [+] 显示较少 [-]Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments from the Bering Sea and western Arctic Ocean
2016
Zhao, Mengwei | Wang, Weiguo | Liu, Yanguang | Dong, Linsen | Jiao, Liping | Hu, Limin | Fan, Dejiang
To analyze the distribution and sources of polycyclic aromatic hydrocarbons (PAHs) and evaluate their potential ecological risks, the concentrations of 16 PAHs were measured in 43 surface sediment samples from the Bering Sea and western Arctic Ocean. Total PAH (tPAH) concentrations ranged from 36.95 to 150.21ng/g (dry weight). In descending order, the surface sediment tPAH concentrations were as follows: Canada Basin>northern Chukchi Sea>Chukchi Basin>southern Chukchi Sea>Aleutian Basin>Makarov Basin>Bering Sea shelf. The Bering Sea and western Arctic Ocean mainly received PAHs of pyrogenic origin due to pollution caused by the incomplete combustion of fossil fuels. The concentrations of PAHs in the sediments of the study areas did not exceed effects range low (ERL) values.
显示更多 [+] 显示较少 [-]Historical record of lead accumulation and source in the tidal flat of Haizhou Bay, Yellow Sea: Insights from lead isotopes
2016
Zhang, Rui | Guan, Minglei | Shu, Yujie | Shen, Liya | Chen, Xixi | Zhang, Fan | Li, Tiegang
In order to investigate the historical records of lead contamination and source in coastal region of Haizhou Bay, Yellow Sea, a sediment core was collected from tidal flat, dated by 210Pb and 137Cs. Lead and its stable isotopic ratios were determined. The profiles of enrichment factor (EF) and Pb isotope ratios showed increasing trend upward throughout the core, correlating closely with the experience of a rapid economic and industrial development of the catchment. According to Pb isotopic ratios, coal combustion emission mainly contributed to the Pb burden in sediments. Based on end-member model, coal combustion emission dominated anthropogenic Pb sources in recent decades contributing from 48% to 67% in sediment. And the contribution of leaded gasoline was lower than 20%. A stable increase of coal combustion source was found in sediment core, while the contribution of leaded gasoline had declined recently, with the phase-out of leaded gasoline in China.
显示更多 [+] 显示较少 [-]Total petroleum hydrocarbon degradation by hybrid electrobiochemical reactor in oilfield produced water
2016
Mousa, Ibrahim E.
The crude oil drilling and extraction operations are aimed to maximize the production may be counterbalanced by the huge production of contaminated produced water (PW). PW is conventionally treated through different physical, chemical, and biological technologies. The efficiency of suggested hybrid electrobiochemical (EBC) methods for the simultaneous removal of total petroleum hydrocarbon (TPH) and sulfate from PW generated by petroleum industry is studied. Also, the factors that affect the stability of PW quality are investigated. The results indicated that the effect of biological treatment is very important to keep control of the electrochemical by-products and more TPH removal in the EBC system. The maximum TPH and sulfate removal efficiency was achieved 75% and 25.3%, respectively when the detention time was about 5.1min and the energy consumption was 32.6mA/cm2. However, a slight increasing in total bacterial count was observed when the EBC compact unit worked at a flow rate of average 20L/h. Pseudo steady state was achieved after 30min of current application in the solution. Also, the results of the study indicate that when the current intensity was increased above optimum level, no significant results occurred due to the release of gases.
显示更多 [+] 显示较少 [-]Effect analysis on regeneration speed of continuous regeneration-diesel particulate filter based on NO2-assisted regeneration
2016
E, Jiaqiang | Xie, Longfu | Zuo, Qingsong | Zhang, Guiju
In order to improve the regeneration speed of Continuous Regeneration-Diesel Particulate Filter (CR-DPF) based on NO2-assisted regeneration, a mathematic model of the NO2-assisted regeneration is developed and verified by experiments and numerical simulation. Furthermore, the influences on regeneration speed from exhaust airflow and filter structure are studied in NO2-assisted regeneration process of CR-DPF. The results show that: the regeneration speed will be increased due to the increase of the volume of the exhaust gas, the temperature of the exhaust gas, the concentration of the NO2 and the concentration of the O2 in exhaust gas, but the regeneration speed will be decreased under other conditions such as m(NO2)/m(PM) being less than its threshold in exhaust gas, the increase of the filter length in CR-DPF or the increase of the channel density when initial amount of the carbon particles in filter being less than its threshold, moreover, thickness of channel wall has no effect on regeneration speed. And the suitable range of values for some key parameters being useful for enhancing regeneration speed and reducing pressure drop of CR-DPF has been provided.
显示更多 [+] 显示较少 [-]Assessment of polycyclic aromatic hydrocarbons (PAHs) in mussels (Mytilus galloprovincialis) of Prince Islands, Marmara Sea
2016
Balcıoğlu, Esra Billur
In this study, PAH analyses have been conducted on indigenous mussels. Mussel samples (Mytilus galloprovincialis) have been collected from seven stations of Prince Islands during September 2015. Concentrations of total determined PAHs (sum of 16 compounds) ranged between 664 and 9083ngg−1. The origin of PAHs has been found to be pyrolytic according to the PHE/ANT and FA/PYR ratios in Büyükada. For other islands, PAH origins have been observed as pyrolytic and petrogenic together according to the PHE/ANT, FA/PYR and BaA/CHR ratios.
显示更多 [+] 显示较少 [-]Bioaccumulation of heavy metals in marine organisms and sediments from Admiralty Bay, King George Island, Antarctica
2016
Trevizani, Tailisi Hoppe | Figueira, Rubens Cesar Lopes | Ribeiro, Andreza Portella | Theophilo, Carolina Yume Sawamura | Majer, Alessandra Pereira | Petti, Mônica Angélica Varella | Corbisier, Thais Navajas | Montone, Rosalinda Carmela
The Antarctic continent is considered a low-impact environment; however, there is a tendency to increase the contaminants' levels due to human activities in the research stations. In this study, As, Cd, Cr, Cu, Hg, Ni, Pb and Zn levels in sediment and biota were determined in the environmental samples from Admiralty Bay (King George Island, Antarctica) collected in 2003. The results demonstrated high concentrations of Cu and Zn in the sediments. There was bioaccumulation of As in the biota from Admiralty Bay and bioaccumulation of Zn specifically in the biota from Martel Inlet. In addition, the results were useful in order to understand the heavy metal levels for the pre-accident condition of Comandante Ferraz Antarctic Station, where an accident occurred in 2012, and also for the comparison with current conditions within the monitoring work developed by INCT-APA (National Institute of Science and Technology for Environmental Research Antarctic).
显示更多 [+] 显示较少 [-]Assessment of perfluorooctanoic acid and perfluorooctane sulfonate in surface water - Tamil Nadu, India
2016
Sunantha, Ganesan | Vasudevan, Namasivayam
As an emerging class of environmentally persistent organic pollutants, perfluorinated compounds (PFCs), particularly perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS); have been universally found in the environment. Wastewater and untreated effluents are likely the major causes for the accumulation of PFCs in surface water. There are very few reports on the contamination of PFCs in the developing countries, particularly in India. This study reports the quantitative analysis of PFOA and PFOS in Noyyal, Cauvery, and also lakes in and around Chennai, using Ultra-Fast liquid chromatograph. The concentration of PFOA and PFOS ranged from 4 to 93ng/L and 3 to 29ng/L, respectively. The concentration of PFOS was below detectable limit in Cauvery River. A reliable concentration of PFOA was recorded at all sites of River Cauvery (5ng/L). The present study could be useful for the assessment of future monitoring programs of PFOA and PFOS in the surface water.
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