We comprehensively investigated sedimentary Hg in Yellow and East China Seas (YECSs), which constitute potentially important depocenters for large anthropogenic Hg emissions from mainland China. A large dataset of Al-TOC-Hg concentrations led to an in-depth understanding of sedimentary Hg in the entire YECSs, including distribution and its determinants, source-to-sink, background levels, inventory in flux and budget, and accumulation history. Especially, the net atmospheric Hg flux to the sediments was estimated to be 1.3 × 10−5 g/m2/yr, which corresponded reasonably well to that calculated using a box model. About 21.2 tons of atmospheric Hg (approximately 4% of the total anthropogenic atmospheric Hg emissions from China) were buried annually in the YECS basin. This result implies that most of atmospheric Hg from China is transferred to the surface of the Pacific (including the East/Japan Sea and South China Sea) by the westerlies and, consequently, can play a critical role in open-sea aquatic ecosystems.

The present study evaluates an optical bioassay based on green photosynthetic microalgae as a promising alternative for monitoring of relevant seawater pollutants. Photosystem II fluorescence parameters from several microalgae species were examined in the presence of three common marine pesticides that act as photosynthesis inhibitors. The three pollutants were detected within 10 min in concentrations between ng/L-μg/L. The different algae species showed slightly diverse pesticide sensitivities, being Chlorella mirabilis the most sensitive one. Potential interferences due to oil-spill pollutants were discarded. The lipid content was characterized to identify microorganisms with suitable mechanisms that could facilitate stress acclimatization. C. mirabilis presented elevated content of unsaturated lipids, showing a promising potential for biosensing in saline stress conditions.The optimized microalgae-based bioassay was preliminarily incorporated into a marine buoy for autonomous pre-screening of pesticides in coastal areas, demonstrating its suitability for real-time monitoring of marine water and quantitative evaluation of total biotoxicity.

The increasing global contamination of plastics in marine environments is raising public concerns about the potential hazards of microplastics to environmental and human health. Microplastics formed by the breakdown of larger plastics are typically irregular in shape. The objective of this study was to compare the effects of spherical or irregular shapes of microplastics on changes in organ distribution, swimming behaviors, gene expression, and enzyme activities in sheepshead minnow (Cyprinodon variegatus). Both types of microplastics accumulated in the digestive system, causing intestinal distention. However, when compared to spherical microplastics, irregular microplastics decreased swimming behavior (i.e., total distance travelled and maximum velocity) of sheepshead minnow. Both microplastics generated cellular reactive oxygen species (ROS), while ROS-related molecular changes (i.e., transcriptional and enzymatic characteristics) differed. This study provides toxicological insights into the impacts of environmentally relevant (fragmented) microplastics on fish and improves our understanding of the environmental effects of microplastics in the ecosystem.

The characteristics of phytoplankton assemblages were analyzed by the Utermöhl method in the southern Yellow Sea in summer, 2008. A total of 113 species (including varieties and forms), belonging to 51 genera and 3 phyla, were identified. Diatom was the most dominant group. The dominant species included Eucampia zoodiacus, Leptocylindrus danicus, Chaetoceros affinis, Thalassionema nitzschioides, Skeletonema costatum, Paralia sulcata and Chaetoceros tortissimus, which were eurytopic and temperate species. The cell abundance of phytoplankton ranged from 0.04 to 620.08 cells·mL−1 with an average of 27.52 cells·mL−1. Horizontally, the cell abundance showed a decreasing trend from the south to the north. In terms of vertical distribution, the values in surface and subsurface water layers were higher than those in bottom water layers. Results of correlation analysis showed that phytoplankton cell abundance was positively correlated with water temperature, ammonia and nitrite concentrations, and negatively correlated with salinity and silicate concentration.

Large amounts of ammunition containing 2,4,6-trinitrotoluene (TNT) and other substances were dumped in the Baltic Sea after WWII. Considering progressive corrosion processes, studying the transformation of TNT occurring in the environment constitutes an important aspect of a possible associated risk. This study focused on the transformations of TNT in simulated conditions of the Baltic Sea bottom sediment. Methods of analysis of TNT and selected products of its transformations were developed for that purpose. The developed methods allowed for the determination of selected compounds below 1 ng/g. Systematic monitoring of TNT transformations in the environment of the bottom sediment was performed. This allowed for the determination of the kinetics of TNT degradation and identification of degradation reaction products. Based on the obtained results, the TNT decay half-time in conditions present in the Baltic Sea was estimated to be 16.7 years for the abiotic environment and 5.6 for the biotic environment.

Andaman and Nicobar islands is one of the major tourism hubs of the World. Most travelers visit these islands for historical attractions, beaches, snorkeling, scuba diving, coral reefs, adventure and recreation. Port Blair is the capital and sole entry/exit point of these islands. The coasts of Port Blair Bay (PBB) and Wandoor Creek (WC) are largely populated due to its services offered to different public/private sectors and for the economic significance. Nevertheless, the global recognition of these islands relies on its healthy ecosystem. Effective management of beaches, bays and their environmental services requires knowledge of coastal water quality. This study assesses the datasets of twenty seawater quality parameters of PBB and WC generated during five years (2011–2015) at eight sites. Multivariate statistical techniques were used for (i) analysis and interpretation of water quality parameters (ii) identification of pollution factors/sources and (iii) understanding spatio-temporal variations valuable for coastal water quality management.

The anthropogenic pressure in recent years has driven us to investigate the environmental quality at 22 stations in Parangipettai by collecting seawater samples monthly from 2014 to 2015. The sampling stations were grouped into three different environments, namely, Vellar Estuary (VE), Coleroon Estuary (CE), and Open Sea (OS). Factor analysis showed a total variance of 65.63% and exhibited a strong factor loading for atmospheric temperature (0.914), water temperature (0.917), ammonia (0.767), inorganic phosphate (0.897), total phosphorus (0.783), and phytoplankton (0.829). The index value showed water quality was good in OS (74.18), whereas it was moderate in VE (69.73) and CE (68.47). The visual model developed using Geographical Information System (GIS) displayed a spatial pattern of water temperature and phytoplankton dispersion in a distinct manner. The results obtained through multivariate analysis and GIS-based model are imperative to establish reference for a comparative study with other similar ecosystem for better planning and management of tropical seawaters.

Plastic is produced today in large quantities and used for many purposes. At the end of use, a large part of it gets into the environment, often into the sea and there it is fragmented into the smallest fragments, so-called microplastic (MP). MPs pose a serious challenge to the marine environment such as the sources and properties of MP particles, their impact on marine organisms, and the challenges of environmental pollution. This work, carried out in the fourteen sites in the area, is the first reference to the detection of MP distribution at surface waters in the Sea of Marmara, Turkey. As a result of this study, the average level of MP in the surface was determined to be 1.263 item/m2. The results were higher compared of the most other adjacent regions and show that the Sea of Marmara started to face that problem.

Concentrations of 6 trace metals (Ag, Cd, Cu, Ni, Pb, Zn) in the muscle of 2 sharks (Galeus melastomus and Scyliorhinus canicula), 4 teleosts (Helicolenus dactylopterus, Lepidorhombus boscii, Micromesistius poutassou and Phycis blennoides) and 1 crustacean (Nephrops norvegicus) were compared between the Bay of Biscay (Atlantic Ocean) and the Gulf of Lions (Mediterranean Sea). Although average concentrations and the trace element pollution index were generally higher in the Gulf of Lions, significant differences between the two ecosystems were only found for Zn for Helicolenus dactylopterus, and for Ag and Cu for the crustacean N. norvegicus. Moreover, some relationships between trophic level or size and metal concentrations were found for these two species. The absence of clear pattern may result from the blurring effect of contamination and excretion that may act differentially for all species and all elements.

In order to study the pollution levels and spatiotemporal trend of Dichlorodiphenyltrichloroethanes (DDTs) in the Southern Yellow Sea (SYS), thirty-two surface sediment samples and a sediment core have been analyzed, and our results have been compared with previous reports. DDTs contents in our samples ranged from below detection limit to 5.1ng/gdry weight (d.w.), which presented lower ecological risks in the SYS. Surface sediment results show a seaward increasing trend with high values in the northern region of the central basin of the SYS. Our reconstructed core record and historical data from previous reports reveal an increasing trend from 1905 to 1955 but a decline trend since 1985 for DDTs, which is consistent of the production, usage and banning of DDTs in China. The source identification, based on (DDE+DDD)/DDTs, suggested that aged DDTs were the major contributor, though there were some inputs of fresh DDTs from the usage of 1,1-bis(p-Chlorophenyl)-2,2,2-trichloroethanol (dicofol).