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The geochemical and environmental characteristics of trace metals in surface sediments of the river estuarine mouths around the Taiwan Island and the Taiwan Strait 全文
2022
Fang, Tien Hsi | Huang, Zih Ting | Chang, Fu Wei
The trace metals species in surface sediments of the Taiwanese river estuarine mouths and the Taiwan Strait were examined by sequential extraction method. Based on the metal species present in sediments, trace metals can be divided into three groups: (1) Co, Cr, Fe, Ni and Zn; (2) Cu and Hg; and (3) Mn and Pb. The total concentrations of trace metals in the first two groups are dominated by the residual fraction. While, Cu and Hg their organic species also contributes a significant percentage and reduces the residual fraction portion. Lead and Mn are dominated by the labile fraction. The total metal concentrations in the analyzed sediments seem to be influenced by Fe oxides, TOC and grain size. The metals contamination status assessed by three environmental indices suggests that the analyzed sediments are minor contaminated by trace metals, with a few exceptions of Cu and Hg at some stations.
显示更多 [+] 显示较少 [-]First evaluation of ballast water management systems on operational ships for minimizing introductions of nonindigenous zooplankton 全文
2022
Bailey, Sarah A. | Brydges, Torben | Casas-Monroy, Oscar | Kydd, Jocelyn | Linley, R Dallas | Rozon, Robin M. | Darling, John A.
Ballast water is a leading pathway for the global introduction of aquatic nonindigenous species. Most international ships are expected to install ballast water management systems (BWMS) by 2024 to treat ballast water before release. This study examines if ballast water discharges managed by BWMS are meeting standards for organisms ≥50 μm in minimum dimension (i.e., <10 organisms per m³; typically zooplankton). Representative samples of ballast water were collected from 29 ships (using 14 different BWMS) arriving to Canada during 2017–2018. Fourteen samples (48 %) had zooplankton concentrations clearly exceeding the standard (ranging from 18 to 3822 organisms per m³). Nonetheless, compared to earlier management strategies, BWMS appear to reduce the frequency of high-risk introduction events. BWMS filter mesh size was an important predictor of zooplankton concentration following treatment. Greater rates of compliance may be achieved as ship crews gain experience with operation and maintenance of BWMS.
显示更多 [+] 显示较少 [-]Metal-associated human health risk assessment due to consumption of pelagic and benthic ichthyofaunal resources from the highly contaminated Cuddalore coast in Southern India 全文
2022
Vinothkannan, Anbazhagan | Rajaram, Rajendran | Charles, Partheeban Emmanuel | Ganeshkumar, Arumugam
We present seasonal variation of four metals (Cd, Cu, Pb, and Zn) in nine pelagic and three benthic fish species from the highly polluted Cuddalore coast in Tamil Nadu, India. Metals were assessed using atomic absorption spectrometry and detected in all fish species, in at least one season, except Iniistius cyanifrons where cadmium was not detected throughout. In both benthic and pelagic fish, order of metal concentration was Zn > Cu > Pb > Cd. Multivariate statistical analysis revealed that metals may have originated from both natural and anthropogenic sources. Health risk assessment revealed that consumption of fish from Cuddalore coast does not pose health risk for now; however, hazard index values (pelagic = 0.97; benthic = 0.90) are in borderline. Even a slight increase in metal concentration in fish can prove hazardous for human consumption. Sooner or later, eating fish from Cuddalore coast may pose a considerable health risk to humans if metal pollution is not held at Bay.
显示更多 [+] 显示较少 [-]Bioaccumulation patterns of trace elements by native (M. galloprovincialis) and invasive (X. securis) mussels in coastal systems (Vigo Ria, NW Iberian Peninsula) 全文
2022
Rodríguez-Velarte, P. | Babarro, J.M.F. | Cobelo-García, A.
Bioaccumulation patterns of trace elements by native (M. galloprovincialis) and invasive (X. securis) mussels in coastal systems (Vigo Ria, NW Iberian Peninsula) 全文
2022
Rodríguez-Velarte, P. | Babarro, J.M.F. | Cobelo-García, A.
A number of trace elements (Mn, Fe, Co, Ni, Cu, Zn, As, Nb, Mo, Ag, Cd, Pb, U and the rare earth elements – REE) were analyzed in the dissolved phase, suspended particulate matter and in different organs (gills, hepatopancreas, and the rest of soft tissue) in mussels of the native Mytilus galloprovincialis and invasive Xenostrobus securis species in the Vigo Ria (NW Iberian Peninsula) in order to assess potential differences in their bioaccumulation patterns. Results obtained do not show significant differences in the bioaccumulation of trace elements by M. galloprovincialis and X. securis, except for Zn and Ag. In the case of Zn, a 4-fold enrichment in M. galloprovincialis compared to X. securis was found. The most important differences between species were observed for Ag, with approximately 40-fold higher concentrations in X. securis. Such elevated Ag bioaccumulation by X. securis can be useful for Ag biomonitoring using these invasive species in this area.
显示更多 [+] 显示较少 [-]Bioaccumulation patterns of trace elements by native (M. galloprovincialis) and invasive (X. securis) mussels in coastal systems (Vigo Ria, NW Iberian Peninsula) 全文
2022
Rodríguez-Velarte, Patricia | Babarro, José M. F. | Cabelo-García, A. | Ministerio de Economía, Industria y Competitividad (España) | European Commission
7 pages, 3 tables, 5 figures.-- Under a Creative Commons license | A number of trace elements (Mn, Fe, Co, Ni, Cu, Zn, As, Nb, Mo, Ag, Cd, Pb, U and the rare earth elements – REE) were analyzed in the dissolved phase, suspended particulate matter and in different organs (gills, hepatopancreas, and the rest of soft tissue) in mussels of the native Mytilus galloprovincialis and invasive Xenostrobus securis species in the Vigo Ria (NW Iberian Peninsula) in order to assess potential differences in their bioaccumulation patterns. Results obtained do not show significant differences in the bioaccumulation of trace elements by M. galloprovincialis and X. securis, except for Zn and Ag. In the case of Zn, a 4-fold enrichment in M. galloprovincialis compared to X. securis was found. The most important differences between species were observed for Ag, with approximately 40-fold higher concentrations in X. securis. Such elevated Ag bioaccumulation by X. securis can be useful for Ag biomonitoring using these invasive species in this area | Funding was provided by the Spanish Government including European FEDER funds (project Ref. CTM2016-76146-C3-2-R) | Peer reviewed
显示更多 [+] 显示较少 [-]Bioaccumulation Patterns of Trace Elements by Native (M. galloprovincialis) and Invasive (X. securis) Mussels in Coastal Systems (Vigo Ria, NW Iberian Peninsula). Supporting information 全文
2022
Rodríguez-Velarte, Patricia | Babarro, José M. F. | Cabelo-García, A. | Babarro, José M. F. [0000-0001-6352-1944]
3 pages.-- File includes 2 tables, 1 figure | Table S1. Results obtained (n=3) for the certified reference materials DORM-2 (fish muscle) and BCR-CRM668 (mussel tissue) (NRC, Canada). Values in brackets represent one standard deviation.-- Table S2. Results obtained (n=3) for the certified reference materials CASS-6 (coastal seawater), SLEW-3 (estuarine water) and SLRS-6 (river water) (NRC, Canada). Values in brackets represent one standard deviation. Values for REE in SLEW-3 are not certified; concentrations given were reported by Bayon et al. (2001). Value for Nb in SLRS-6 is not certified; value given was reported by Babechuk et al. (2020).-- Figure S1. Concentrations (µg g-1) of the trace elements analyzed in the hepatopancreas, gills and rest of soft tissue for M. galloprovincialis at Station 3 and X. securis at Station 1 | Peer reviewed
显示更多 [+] 显示较少 [-]“Non-traditional” stable isotopes applied to the study of trace metal contaminants in anthropized marine environments 全文
2022
Araújo, Daniel F. | Knoery, Joël | Briant, Nicolas | Vigier, Nathalie | Ponzevera, Emmanuel
“Non-traditional” stable isotopes applied to the study of trace metal contaminants in anthropized marine environments 全文
2022
Araújo, Daniel F. | Knoery, Joël | Briant, Nicolas | Vigier, Nathalie | Ponzevera, Emmanuel
The advent of Multicollector ICP-MS inaugurated the analysis of new metal isotope systems, the so-called “non-traditional” isotopes. They are now available tools to study geochemical and ecotoxicological aspects of marine metal contamination and hence, to push the frontiers of our knowledge. However, such applications are still in their infancy, and an accessible state-of-the-art describing main applications, obstacles, gaps, and directions for further development was missing from the literature. This paper fills this gap and aims to encourage the marine scientific community to explore the contributions of this newly available information for the fields of chemical risk assessment, biomonitoring, and trophic transfer of metal contaminants. In the current “Anthropocene” epoch, metal contamination will continue to threaten marine aquatic ecosystems, and “non-traditional” isotopes can be a valuable tool to detect human-induced changes across time-space involving metal contaminants, and their interaction with marine biota.
显示更多 [+] 显示较少 [-]"Non-traditional" stable isotopes applied to the study of trace metal contaminants in anthropized marine environments 全文
2022
Ferreira Araujo, Daniel | Knoery, Joel | Briant, Nicolas | Vigier, Nathalie | Ponzevera, Emmanuel
The advent of Multicollector ICP-MS advent inaugurated the analysis of new metal isotope systems, the so-called “non-traditional” isotopes. They are now available tools to study geochemical and ecotoxicological aspects of marine metal contamination and hence, to push the frontiers of our knowledge. However, such applications are still in their infancy, and an accessible state-of-the-art describing main applications, obstacles, gaps, and directions for further development was missing from the literature. This paper fills this gap and aims to encourage the marine scientific community to explore the contributions of this newly available information for the fields of chemical risk assessment, biomonitoring, and trophic transfer of metal contaminants. In the current “Anthropocene” epoch, metal contamination will continue to threaten marine aquatic ecosystems, and “non-traditional” isotopes can be a valuable tool to detect human-induced changes across time-space involving metal contaminants, and their interaction with marine biota.
显示更多 [+] 显示较少 [-]Temporal variations in fecal indicator bacteria in bathing water and sediment in a coastal ecosystem (Aytré Bay, Charente-Maritime, France) 全文
2022
Ndione, Méry | Ory, Pascaline | Agion, Tony | Treilles, Michaël | Vacher, Luc | Simon-Bouhet, Benoit | Le Beguec, Maëlig | Pineau, Philippe | Montanié, Hélène | Agogué, Hélène
This study presents the fecal contamination dynamic at the two bathing sites of Aytré Bay (Charente Maritime, France). We quantified fecal indicator bacteria (FIB) abundances (Escherichia coli and enterococci) from water and sediment samples over one-year survey. Then we measured biological (bacterial abundance, chlorophyll-a), physico-chemical (dissolved nutrients and oxygen, salinity, pH …) and climatic (temperatures, rainfall and tidal coefficient) parameters. Results showed that FIB abundances were occasionally higher than the European regulatory threshold during winter, summer and fall. The “poor quality” of the bathing water was due to high enterococci abundance. We found negative significant correlations between FIB and water temperature and salinity, and positive significant correlations between FIB and rainfall, PO₄, NO₃, NO₂, and SiO₂ mainly in water. Relationships between parameters showed that during summer and spring the main environmental drivers were temperature and salinity, while in fall and winter they were rainfall and dissolved nutrients.
显示更多 [+] 显示较少 [-]Historical mercury contamination in a major Latin American industrial and port complex: The case of the Santos estuary, Southeastern Brazil 全文
2022
Angeli, José Lourenço Friedmann | Sartoretto, Juliê Rosemberg | Kim, Bianca Sung Mi | de Lima Ferreira, Paulo Alves | Benedetti, Beatriz | Mahiques, Michel Michaelovitch de | Figueira, Rubens Cesar Lopes
The present study determined total mercury (Hg) in four ²¹⁰Pb dated sediment cores to assess the historical anthropogenic Hg accumulation in the Santos estuary, Southeastern Brazil. Background levels were identified using the deepest sections of the cores, corresponding to pre-industrial ages. Mercury distribution in the sediment cores (0.02–2.64 mg kg⁻¹) presented a large spatial and temporal variation. Contamination is highest in the upper estuary and indicates that the industrial hub, especially a chlor-alkali plant is the primary source of Hg. A contaminant trap effect is observed in this area associated with high fine sediment accumulation and Hg fluxes. The contamination pattern indicates that the regions not affected by direct inputs are influenced by reworking, resuspension, and transport of contaminated sediments by tidal flows. The Hg enrichment in the upper layers of the sediment cores demonstrates that the environmental actions fulfilled in the 1980s were insufficient to control Hg pollution in the Santos estuary.
显示更多 [+] 显示较少 [-]An assessment of floating marine debris within the breakwaters of the University of the South Pacific, Marine Studies Campus at Laucala Bay 全文
2022
Paris, Andrew | Kwaoga, Alex | Hewavitharane, Chinthaka
An assessment of floating marine debris within the breakwaters of the University of the South Pacific, Marine Studies Campus at Laucala Bay 全文
2022
Paris, Andrew | Kwaoga, Alex | Hewavitharane, Chinthaka
Contributions of Pacific Islands countries to marine plastic debris are disproportionate to the effects on people's connections to the ocean. Plastic waste management initiatives face challenges in containing waste and consequently plastics plague coastal environments. The Seabin, a floating trash skimmer, presents a novel and replicable approach to collecting and cataloguing marine plastics. The objectives of the study were to conduct an audit of marine plastic debris within the breakwaters of the University of the South Pacific, Marine Campus at Laucala Bay while simultaneously gauging the effectiveness of the Seabin and providing recommendations to enhance its utility. Inorganic debris was comprised entirely of plastics while the majority of debris collected was organic. This study provides the first assessment of floating marine plastic debris in an inshore environment of a Pacific Island country. Plastic debris assessments have the potential to inform policy and pivot management efforts to mitigate plastic waste pollution.
显示更多 [+] 显示较少 [-]An assessment of floating marine debris within the breakwaters of the University of the South Pacific, Marine Studies Campus at Laucala Bay 全文
2022
Paris, Andrew | Hewavitharane, Chinthaka A. | Kwaoga, Alex
Contributions of Pacific Islands countries to marine plastic debris are disproportionate to the effects on people's connections to the ocean. Plastic waste management initiatives face challenges in containing waste and consequently plastics plague coastal environments. The Seabin, a floating trash skimmer, presents a novel and replicable approach to collecting and cataloguing marine plastics. The objectives of the study were to conduct an audit of marine plastic debris within the breakwaters of the University of the South Pacific, Marine Campus at Laucala Bay while simultaneously gauging the effectiveness of the Seabin and providing recommendations to enhance its utility. Inorganic debris was comprised entirely of plastics while the majority of debris collected was organic. This study provides the first assessment of floating marine plastic debris in an inshore environment of a Pacific Island country. Plastic debris assessments have the potential to inform policy and pivot management efforts to mitigate plastic waste pollution.
显示更多 [+] 显示较少 [-]Method for acrylic acid monomer detection with recombinant biosensor cells for enhanced plastic degradation monitoring from water environments 全文
2022
Puhakka, Emmi | Santala, Ville
Plastic debris degrades in the water environments due to various factors such as mechanical stress. Small-sized degradation products, including plastic monomers, are currently monitored using equipment which might be unsuitable for screening. Here, we developed a recombinant whole-cell bacterial biosensor, which could be used for this type of monitoring. The Escherichia coli pBAV1K-ACU-lucFF cells contain a luciferase-based reporter system under the control of acrylic acid specific promoter. The biosensor cells were used to detect acrylic acid monomers from both sterile water and spiked lake water samples, indicating usability with environmental samples. Furthermore, poly(acrylic acid) was incubated in salt water, and the biosensor cells could identify acrylic acid monomers originating from it. Thus, the cells could be used to observe similar processes in the environment. The results show that the bacterial biosensors could complement the current research methods of plastic monomer monitoring in water environments with a potential for higher throughputs.
显示更多 [+] 显示较少 [-]Temporal trend of polychlorinated biphenyls contamination in the northwestern Arabian Gulf – Evidence from sediment records 全文
2022
Gevao, Bondi | Uddin, Saif | Behbehani, Montaha | Fowler, Scott W.
This study provides an insight into the polychlorinated biphenyls (PCBs) inventories in the sediments of the northwestern Arabian/Persian Gulf. PCBs can be used as chemical markers that correlate with historical events in the region, to estimate the sedimentation rates in the northern Gulf, and to determine the sources of pollutants in the study area. The concentrations of PCBs were generally patchy in sediments. At Station 1 the ΣPCB concentrations generally fluctuated between 0.100 and 0.400 ng g⁻¹ dw throughout the depositional history measured in a sediment core. There were four peaks in the ΣPCB profile corresponding to 1969, 1979, 1983 and 1991. Station 2 showed a prominent peak at depth of 25 cm. The concentrations of the ΣPCBs and ΣICE congeners at this depth were 28 and 12 ng g⁻¹ dw respectively. Concentrations then dropped dramatically thereafter by a factor of 4. The ΣPCB concentrations at Station 3 were very low compared to the concentrations measured at Stations 1 and 2. The PCB concentration in Core 4 which was taken from open waters was 2–3 orders of magnitude lower than those in the other coastal cores. However, a 1990–91 peak was omnipresent in these cores. There is no record of PCB production within the Gulf region, and PCB releases into the Kuwait marine environment are likely to originate from their use in products. These maxima in early-1990s can be correlated to inputs from war-related activities, including the reported destruction of PCB-containing transformers and military equipment during the occupation of Kuwait. None of the recent sediment core sections at the four stations had a ΣPCB concentration near the effects range-median (ERM) concentration of 180 ng g⁻¹, or permissible exposure limits (PEL) of 189 ng g⁻¹, or were above the effect range-low (ERL) values of 22.7 ng g⁻¹.
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