The estimation of pollution fields, especially in densely populated areas, is an important application in the field of environmental science due to the significant effects of air pollution on public health. In this paper, we investigate the spatial distribution of three air pollutants in Tehran’s atmosphere: carbon monoxide (CO), nitrogen dioxide (NO2), and atmospheric particulate matters less than 10 μm in diameter (PM10μm). To do this, we use four geostatistical interpolation methods: Ordinary Kriging, Universal Kriging, Simple Kriging, and Ordinary Cokriging with Gaussian semivariogram, to estimate the spatial distribution surface for three mentioned air pollutants in Tehran’s atmosphere. The data were collected from 21 air quality monitoring stations located in different districts of Tehran during 2012 and 2013 for 00UTC. Finally, we evaluate the Kriging estimated surfaces using three statistical validation indexes: mean absolute error (MAE), root mean square error (RMSE) that can be divided into systematic and unsystematic errors (RMSES, RMSEU), and D-Willmot. Estimated standard errors surface or uncertainty band of each estimated pollutant surface was also developed. The results indicated that using two auxiliary variables that have significant correlation with CO, the ordinary Cokriginga scheme for CO consistently outperforms all interpolation methods for estimating this pollutant and simple Kriging is the best model for estimation of NO2 and PM10. According to optimal model, the highest concentrations of PM10 are observed in the marginal areas of Tehran while the highest concentrations of NO2 and CO are observed in the central and northern district of Tehran.

The Karnafully is one of the most important rivers due to its profound influence on water chemistry and sediment characteristics. The present study intended to assess the quality of water and sediment from intertidal zone of this river in respect to the pollution index. Seasonal water and sediment samples were collected during four seasons (Monsoon, post-monsoon, winter, and pre-monsoon) of 2014. The result indicates that these investigated parameters ranged as water temperature (21.7-36 °C), pH (8.0-8.7), salinity (2.4-8.8‰), total suspended solid (0.08-0.8 g/L), dissolve oxygen (0.00-4.52 mg/L), soil temperature (21.3-33 °C), pH (5.0-6.8), sand (4.13-44.10%), silt (39.93-75.89%), clay (11.98-21.19%), soil organic matter (4.33-6.21%), organic carbon (2.5-3.6%), nitrite-nitrogen (0.69-3.97 µg/L), and phosphate-phosphorus (0.23-3.44 µg/L). Multivariate statistical analyses like post-hoc LSD test, Cluster Analysis (CA), and Principal Component analysis (PCA) brought out the spatial and temporal changing pattern of water chemistry and sediment characteristics with the effect of uprising pollution. CA ascertained the compatibility among different parameters and categorized the monitoring sites into highly and moderately polluted areas. Moreover, PCA brought out five primary components and highlighted the three dormant factors, enormously regulating the river water chemistry such as municipal waste, carbon based nitrogenous compound, and local geomorphological weathering process. This investigation provided an outline on deterioration of water and sediment quality by high anthropogenic impact and suggests national policy maker to take some initiatives for retaining the quality water and sediment properties.

Surface ozone (Surface O3)is a secondary pollutant and there are only limited studies on ozone in South India. Studies have revealed a strong correlation between higher ozone levels and warmer days. Surface O3 along with its precursors like NO2, CO and CH4 are being measured at Kanyakumari (8.0780° N, 77.5410° E), TamilNadu, India and in this paper we present the summer time variation of ozone from 2010to 2014 . Surface O3 showed a clear diurnal variation, but an irregularity was observed during the night time for all the measuring days of Summer 2014.There was a formation of a well pronounced secondary peak in Surface O3 during 0230 hrs accompanied by relatively strong wind patterns. Since the normal diurnal variation cannot explain this phenomenon,this uncertain behavior is probably attributed tolow NOX titrations and the downward mixing of ozone in the ground layer.The daily mean of Surface O3showed an increasing trend in the study area during the summer monthsand a negative correlation was observed with its precursors. The correlation of Surface O3 with temperature and wind speed for the entire summer season was found as r= +0.68, p= 4.314E-05 and r= +0.63, p

Air pollution is a challenging issue in some of the large cities in developing countries. Air quality monitoring and interpretation of data are two important factors for air quality management in urban areas. Several methods exist to analyze air quality. Among them, we applied the dynamic neural network (TDNN) and Radial Basis Function (RBF) methods to predict the concentrations of ground-level ozone in Karaj City in Iran. Input data included humidity, hour temperature, wind speed, wind direction, PM2.5, PM10 and benzene, which were monitored in 2014. The coefficient of determination between the observed and predicted data was 0.955 and 0.999 for the TDNN and RBF, respectively. The Index of Agreement (IA) between the observed and predicted data was 0.921 for TDNN and 0.9998 for RBF. Both methods determined reliable results. However, the RBF neural network performance had better results than the TDNN neural network. The sensitivity analysis related to the TDNN neural network indicated that the PM2.5 had the greatest and benzene had the minimum effect on prediction of ground-level ozone concentration in comparison with other parameters in the study area.

This study assessed the chemical and microbial contents in the water of public swimming pools in Akwa Ibom State, Nigeria. A total of 16 public pools were selected through probability sampling from the 32 pools that existed in the five urban areas of Akwa Ibom State. Water samples were collected from the sampled pools and tested in the laboratory for chemical and microbial contents. Results showed that the chemical contents of most pools in the study area were less than the values recommended for effective disinfection of the pools. Average free chlorine ranged from 0.05 mg/L to 1.15 mg/L 200 Cfu/ml permissible, except for pools L and M, with 1.8×102 Cfu/ml and 1.7×102 Cfu/ml, respectively. Mean fecal coliform ranged from 2.0×103 Cfu/ml to 4.4×103 Cfu/ml >10 Cfu/100 ml permissible, except for pools L and M, with 0.0 Cfu/ml. It could therefore be concluded that only one out of every eight public swimming pools in Akwa Ibom State meet the minimum requirement for both chemical and microbial contents. This simply implies that most public swimming pools in the study area are not safe for users.

Groundwater is a major source of water for domestic, industrial, and agricultural sectors in many countries. The main objective of this research was to provide an overview of present groundwater quality using parameters such as calcium, magnesium, sodium, chloride, sulfate, pH, and electrical conductivity (EC) in the Mehran plain, Ilam province using GIS and geostatistical techniques. A total of 23 deep and semi-profound wells were selected based on the classified randomized sampling method. The sampling locations were obtained by GPS. Plastic containers were used for the collection of water samples. These samples were transferred to the laboratory for analyzing water quality parameters. Statistical characteristics, qualitative data interpolation, and zoning were investigated using SPSS 20 ،GS+5.3 and ArcGIS10.1. Kolmogorov–Smirnov test were used to test data normality. In order to normalize parameters, logarithm, and 1/x were used for sulfate, EC, cation, and anion. Then the variogram analysis was performed to select the appropriate model. Results showed that co-kriging is the best method for cation and anion, whereas local polynomial interpolation is suitable for sulfate. The results of the interpolation of groundwater quality factors showed that there is approximately good adaption among groundwater factors and geomorphology and topology of the region. Because of inappropriate irrigation system, the highest concentration is in the northwest and western parts of the region, where there is the minimum height and maximum agricultural land. Growth of arable land and agricultural activities has caused increasing concentrations of studied elements, especially EC.

The goal of this research is to study the effect of benzo-alpha-pyrene (BαP) as a pollutant on the plasma levels of cortisol, thyroxin (T4), and triiodothyronine (T3) hormones, and the T3/T4 ratio in the yellowfin sea bream, Acanthopagrus latus. The BαP (50 mg kg-1) in vegetable oil was peritoneally injected. Blood samples were obtained from the treated and control groups after 3 and 72 hr, respectively. The amounts of cortisol, T3, and T4 were measured using the ELISA techniques. The results showed that during both the 3 and 72 hr BαP exposures, the T4 hormone levels significantly decreased, although the cortisol levels increased (P<0.05). However, the T3 hormone levels and T3/T4 ratios compared with their control groups showed a significant difference just after 72 hr (P<0.05). The disruptive effects of the BαP exposure on T4 was stronger than that on the T3, being more evident in long-term stress. Thus, the BαP exerts a significant effect on the thyroid endocrine system and consequently on fish metabolism and growth.

This study was carried out for the purpose of investigating the issue of tailings dams as a potential source of contamination by trace elements in soils at the Sidi Bou Othmane mine in the Marrakech Region, Morocco. Soil samples taken from depths of up to 15 cm and within a radius of 50 m from the tailings dams, were analyzed for Cd, Cu, Pb and Zn using atomic absorption spectrometry. Average concentrations of Cd, Cu, Pb and Zn in soils around the abandoned tailings dams were, respectively, 157.2±8.8, 969.1±38.7, 1640.7±42.7 and 2846.8±84.6 mg/kg. Soils in the vicinity of the decommissioned tailings dams registered increased values for Cd, Cu, Pb and Zn. Contamination factors (CF) and pollution index (PI) were calculated in order to estimate the anthropogenic contribution of target pollutants which determined Cd, Cu, Pb and Zn as the main pollutants in this region. The results revealed the polluted areas in the vicinity of the mine, especially two rural communities apparently linked to the lack of appropriate measures to counteract the effects of these mine tailings, which were causing a progressive contamination of the soil with residues of heavy metal emissions in this region under study. Improved strategies for the management of tailings, among other factors, might have influenced the reduced level of contamination by trace elements at the abandoned mine tailings dam sites.

The surface water chemistry of Thiruvananthapuram Museum Lake was carried out in the period of February 2013 to January 2014. Correlation study of the parameters and overall CCME WQI (Canadian Council of Ministers of the Environment Water quality Index) was also prepared in the study for the lake water. The parameters analysed are cations such as Ca2+, Na+, Mg2+ and K+ and the anions like PO4-, Si4- , NO3- and NO2-. Abiotic factors like water pH, Temperature, Conductivity, TDS, Total Alkalinity and Total Hardness were also analysed. The pH ranged between 6.5 to 7.4. The total hardness ranged between 50.8-99 mg/L which shows the water is moderately hard one. During the pre monsoon period, water temperature showed a positive correlation with total alkalinity (r= 0.915) pH (r= 0.841) and TDS (0.876). Dissolved Oxygen (DO) value showed a positive correlation with Biological Oxygen Demand (BOD) (r= 0.999). The overall CCME water quality index was 80.81 which indicate the water body is protected with only a minor degree of threats. The quality of the water is an essential element of the Thiruvananthapuram Zoo environment with respect to both healths of the ecosystem and zoo tourism enjoyment. Moreover, if maintained properly, this water body can be treated as a major drinking water source for the zoo animals.

The adsorption study was conducted on three Japanese soils with different soil properties to characterize the adsorption pattern of Arsenic (As). Double tube method was used to find out the effect of soil moisture levels on As adsorption. For this study, besides double tube method, conventional batch method also was used. The As adsorption showed two phase kinetics. An initial and rapid adsorption was found at first hour and then gradually preceded before equilibrium in all the three soils in the case of double tube method and in clay loam and light clay soil in the case of batch method. Adsorption seemed to reach equilibrium at 24 h in both methods, though the initial adsorbate load was not the same at the same applied concentration in the methods. Adsorption activity differed according to soil and as well as to the methods. The highest adsorption was found in clay loam soil followed by light clay and sandy loam soil. The linear model of Freundlich adsorption was found better fitted in the case of double tube method than batch method. Suggesting that, under the experimental conditions stated here, the double tube method is more appropriate to describe the adsorption of As in the three Japanese soils under normal field condition. The concentration of As in soil water was slightly increased at different moisture levels from 50%-80% which may contribute significantly to the bioavailability of As at the moisture level below maximum filed capacity.