The quality of the water from Lake Bosomtwe was assessed to aid in the conservation decision on the lake. Twenty-six parameters of physico-chemical, bacteriological, and organic effects and major and trace ions were evaluated using the principal component analysis. The levels of these parameters were also compared with surface water benchmarks of Ghana EPA, WHO, EU, US EPA and CCEM. As prescribed by the benchmarks of these regulatory bodies, the mean levels of temperature, pH, dissolved oxygen, total suspended solids, total dissolved solids, nitrates, phosphate, biochemical oxygen demand, chemical oxygen demand, total hardness, conductivity, alkalinity, turbidity and fluorine did not signal any lake pollution, but sulphate, total and faecal coliforms, chlorophyll-a, cadmium and mercury showed pollution tendencies. Temperature, pH, dissolved oxygen, total suspended solids, total dissolved solids, nitrates, phosphate, sulphate and total coliform bacteria were found to be the main parameters that drive 71.2% of the limnological characteristics of the lake water and deserve careful consideration in designing conservation strategies for the lake.

This study aims to assess the pollution of honey by heavy metals based on the efforts of an urbanization gradient in the city of Annaba (Northeast Algeria) where the dosage of five heavy metals (Fe, Cr, Ni, Cu, Cd) was carried out in four sites.The level of heavy metals was determined by atomic absorption spectrophotometer. The results obtained indicated that even when all the samples were contaminated they were of good quality since the concentrations did not exceed the international standards.According to the results of heavy metal concentrations in the honeys studied, the most abundant element is Fe with an average concentration of 6.956 ± 2.045 (mg/kg), Cr 0.765 ± 0.197 (mg/kg), Ni 0.6005 ± 0.159 (mg/kg), Cu 0.21025 ± 0.065 (mg/kg) and Cd 0.01425 ± 0.005 (mg/kg).The heavy metals studied are present in all samples but trace amounts. Moreover, the comparison of the honey from the four sites indicates to us that the healthiest honey is that of the urban site.

Events such as the emission of toxic gases are possible on floating roof storage tanks. Since gasoline is a high-consumption and volatile product stored in adjacent oil depots or large cities, it is necessary to assess their emission risk. Given that the multi-criteria methods allow the identification of and assessment of the indicators well and allow the participation of expert experts, so the FAHP method has been used to identify and assess the risk before the emission of toxic gases. The results showed the importance of 7 factors among 36 factors, 3 of which were related to equipment error. The DOW'S CEI method was used to assess the emission risk if the event occurred. This method provides safe boundaries based on Emergency Response Planning Guidelines (ERPGs), where the results indicate the settlement placement around the oil repository in the range of the predicted concentration at all three levels of ERPG.

In order to evaluate the impact on water quality of the abandoned Sidi Kamber mine in Skikda, NE Algeria, Pb, Zn, Cd, Fe, Cu, Mn and Ni metals were collected at surface water and groundwater, from twenty eight sites located near the mine. Conventional hydrochemical methods, heavy metal pollution index (HPI) and multivariate statistical analysis techniques: correlation matrix (CM), principal component analysis (PCA) and hierarchical cluster analysis (HCA) were used. Surface water results show that El-Souk River has a high level of pollution, but Guenitra dam water is less contaminated. Regarding the groundwater results, the wells and springs are not suitable for drinking. The overall quality estimated by HPI values of surface and groundwater are poor; they may pose a potential health risk to the local population. The PCA and HCA suggest that surface water and groundwater are contaminated by two sources: anthropogenic and natural. According to the obtained results, surface water and groundwater pollution state of this area raises serious concerns about health and environment.

Mercury pollution is an issue of global concern. In Colombia, the use of contaminated water for food crop irrigation and artisanal mining contributes to mercury pollution in soil, affecting food production and restoration of disturbed areas. Mycorrhizal fungi are symbionts that provide benefits to plants including resistance to heavy metals, but fungal effects on germination remain to be fully described. This study tested the effect of mercury and mycorrhizal fungi on Lactuca sativa seed germination. A 2x5 completely randomized factorial experiment was developed to assess the effect of five HgCl2 polluted treatments, two mycorrhizal treatments (i.e., with inoculum, without inoculum), and the interaction of both factors on seed germination, seedling root colonization, pH, and final water content. In samples with no mercury pollution, mycorrhizal fungi had an inhibitory effect on seed germination. Likewise, the effect of mercury on seed germination is significantly inhibitory. However, pots inoculated with arbuscular mycorrhizal fungi showed constant germination probabilities, independently of mercury concentration. According to the best model determined for the data, a key step in the mitigation of mercury toxicity in seed germination is to prevent substrate pH changes. The environmental conditions of the experiment contributed to densely activate populated biomass of inoculum, which promoted root invasion from various points. Overall, the presence of mycorrhizal fungi in seedbeds could lead to a reduced number of plant individuals. However, the use of fungal inoculum in polluted environments, highly contributes to plant establishment, which is relevant in further vegetable cultivations growing in soil polluted areas.

Lignin rich solid residues after saccharification during the production of ethanol from lignocellulosic substrates are major concern during past times. These solid residues left after the saccharification of Coir pith and Bit fiber waste are pyrolysed at 350 oC to yield biochar, which has been characterized and its potential for removal of Malachite Green, a dye present in the effluents from coir product manufacturing units are studied. FTIR and XRD spectra revealed the diverse functional groups present on the surface of biochar. SEM images showed the porous structure of the biochar. A maximum dye removal efficiency of 99.5% was achieved using Coir Pith Biochar (1 %) within 24 hours of treatment at a dye concentration of 100 mg/l. The removal efficiency was 99.4 % using Bit Fiber Biochar (0.8 %) in the same treatment period. The efficiency of removal was enhanced on adjusting the pH to 4 at which the dye removal of 99.6 % and 99.7 % was achieved using Bit fiber biochar and Coir pith biochar respectively. The residence time was significantly reduced to 2 and 4 hours respectively for bit fiber and coir pith biochar at pH 4 and hence the produced biochars are cost effective adsorbents for removal of dyeing effluents in wastewater. The adsorption fits into pseudo-second order kinetics and is well described by langmuir isotherm model. This would also facilitate the sustainable use of spent solid substrates left after lignocellulosic ethanol production in a more economical way.

The current research study the comprehensive health and environmental hazard levels of Particulate matters originating from natural radionuclides sources collected from different Qassim region locations, Saudi Arabia. Activity concentration for 226Ra, 232Th, and 40K was assessed using a Sodium Iodide detector. Gamma-ray parameters as the Radium equivalent, Gamma level index, absorbed dose, annual effective dose, and lifetime risk were measured to predict the growth of radiological dangers. The average activity concentration for 226Ra, 232Th, and 40K is 35±0.06, 32.6±0.4, and 294.99±1.31 Bq/kg. Ra(eq) ranges from38.3 to 143.1 with an average of 104.37 Bq/kg, absorbed dose ranges from 18 to 66.49 with an average of 48.18 nGy/h, and annual effective dose ranges from 22.09 to 81.58 with an average of 59.11 μSv/y. The relative contribution was 26%, 33%, and 41% for 40K, 226Ra, and 232Th, respectively. The obtained results do not cause apprehensions from the radiation population compatible with permissible public limits. The obtained database helps the investigators follow the future pollution exchange due to Scientific progress in the use of radioactive materials.

A new traiazole derivative (4-amino-5-(((5-methyl-1H-benzo[d]imidazol-2-yl)thio)methyl)-2,4-dihydro-3H-1,2,4-triazole-3-thiol, (L), was employed as a chelating ligand to form a dibutyltin chloride complex and improve the poly(vinyl chloride) (PVC) properties. The doped PVC films were characterized via FT-IR, UV-Vis spectrum, elemental analyses (C, H, N, and M (metallic)), and magnetic susceptibility and conductivity measurements. These characterizations were conducted at room temperature, and it was disclosed that the chelating ligand rules as a bidentate chelate. The photostabilization examination of plain and L-doped PVC films was conducted in the presence of ambient air using the accelerating weather tester, where the doping ratio was fixed to 0.5 wt.%. The photostabilization performance of the additive was evaluated by tracking the indexes of carbonyl (ICO), polyene (IPO), and hydroxyl (IOH), and weight loss relationship with irradiation time. It was noticed that the values of ICO, Ipo, and IOH enhanced with the irradiation time, where this improvement relied on the presence of the Bu2SnL complex.

A mathematical model is presented to simulate the photocatalytic degradation of terbuthylazine in a continuous stirred tank reactor. The flow field is described by the continuity equation and the momentum equation. An advection-diffusion-reaction equation is used to simulate the transport of terbuthylazine.  The chemical reactions take place on the inner wall surface coated with the catalyst, which is described by a third-kind boundary condition.  A transient differential equation is used to describe the variation of inlet concentration with time. All governing equations are solved using the commercial computational fluid software ANSYS Fluent. The simulation results agree with the experimental data at different temperatures and different flow rates. The radial distribution of terbuthylazine in the reactor is discussed in detail. The velocity depicts a parabolic curve with a maximum velocity of  0.0005 m s-1, 0.001 m s-1, 0.00022 m s-1 and 0.0032 m s-1 for 50 mL min-1, 100 mL min-1, 200 mL min-1, and 300 mL min-1, respectively. At the flow rate of 300 mL min-1, concentration of terbuthylazine decreases from 3.6 mg dm-3 to 0.8 mg dm-3 whereas concentration of cyanuric acid increases from 0.05 mg dm-3 to 0.28 mg dm-3. It shows that the radial effect of velocity and concentration should be taken into account. The mathematical model used in this study is suitable for simulating the photocatalytic degradation process of terbuthylazine in continuous stirred tank reactors.

Melanoidin is the hazardous dark brown byproduct generated during palm oil extraction in the crude palm oil industry. In this study, the laccase-producing consortium W3 (Bacillus licheniformis and Bacillus subtilis) was used to degrade melanoidin and decolorize palm oil mill effluent (POME). The microbial fuel cell (MFC) has been applied for enhancing decolorization and generation of electrical energy as a byproduct. The results displayed the maximal melanoidin removal of 95.20±0.10% was gained when the consortium W3 was added into the synthetic wastewater. While the maximal decolorization of 75.10±0.12% and 73.91±0.23% were gained from the sterile POME and raw POME respectively without chemical addition. Moreover, the power output of 2.13±0.05 W/m3 or 0.27±0.01 W/m2 was achieved from the POME-fed MFC with W3. This study gained new knowledge of using the laccase-producing bacterial consortium integrated with MFC for melanoidin removal from the POME and generation of electrical power as an alternative energy source.