Sodium diclofenac (DCF) is a common analgesic and anti-inflammatory drug, which has become an environmental problem due to its growth and accumulation into water bodies. In this work, commercial (with excipients) and analytical (pure) DCF mineralization was studied by means of heterogeneous catalytic ozonation. The process was carried out with magnetite (Fe₃O₄) as a catalyst, which preserves its physical and chemical properties during the process. The best results of mineralization were obtained after a 40-min treatment of 35 mg/L analytical DCF solution, with a 0.5 g/L catalyst concentration. These results showed the highest organic load decrease, measured as dissolved organic carbon (DOC) and chemical oxygen demand (COD), with 94 and 89%, respectively. In addition, the percentage of organic load decrease was compared between the conventional and the catalyzed process. Besides, reaction products were identified by gas chromatography–mass spectrometry (GC-MS) and the catalytic properties were identified by Mössbauer spectroscopy, which showed the catalyst maintained its nature after the process. Finally, the results obtained show that the heterogeneous catalytic process could be an efficient degradation treatment for emerging contaminants such as DCF.

Where surface-functionalized engineered nanoparticles (NP) occur in drinking water catchments, understanding their transport within and between environmental compartments such as surface water and groundwater is crucial for risk assessment of drinking water resources. The transport of NP is mainly controlled by (i) their surface properties, (ii) water chemistry, and (iii) surface properties of the stationary phase. Therefore, functionalization of NP surfaces by organic coatings may change their fate in the environment. In laboratory columns, we compared the mobility of CeO₂ NP coated by the synthetic polymer polyacrylic acid (PAA) with CeO₂ NP coated by natural organic matter (NOM) and humic acid (HA), respectively. The effect of ionic strength on transport in sand columns was investigated using deionized (DI) water and natural surface water with 2.2 mM Ca²⁺ (soft) and 4.5 mM Ca²⁺ (hard), respectively. Furthermore, the relevance of these findings was validated in a near-natural bank filtration experiment using HA-CeO₂ NP. PAA-CeO₂ NP were mobile under all tested water conditions, showing a breakthrough of 60% irrespective of the Ca²⁺ concentration. In contrast, NOM-CeO₂ NP showed a lower mobility with a breakthrough of 27% in DI and < 10% in soft surface water. In hard surface water, NOM-CeO₂ NP were completely retained in the first 2 cm of the column. The transport of HA-CeO₂ NP in laboratory columns in soft surface water was lower compared to NOM-CeO₂ NP with a strong accumulation of CeO₂ NP in the first few centimeters of the column. Natural coatings were generally less stabilizing and more susceptible to increasing Ca²⁺ concentrations than the synthetic coating. The outdoor column experiment confirmed the low mobility of HA-CeO₂ NP under more complex environmental conditions. From our experiments, we conclude that the synthetic polymer is more efficient in facilitating NP transport than natural coatings and hence, CeO₂ NP mobility may vary significantly depending on the surface coating.

Global deterioration of water, air, and soil quality by the release of toxic chemicals from anthropogenic pollutants is becoming a serious global problem. The extensive use of copper oxide nanoparticles (CuO NPs) can be environmentally hazardous when these NPs enter the atmosphere. The present study aimed to evaluate the role of CuO NPs on plant growth, photosynthetic capacity, and bioactive compounds, as well as their transcriptional level changes in Brassica rapa seedlings. Chlorophyll, carotenoid, and sugar content decreased, while proline and anthocyanins were significantly enhanced in the CuO NP-treated seedlings compared with the untreated controls. Reactive oxygen species (ROS), malondialdehyde (MDA), and hydrogen peroxide (H₂O₂) production were also enhanced in the seedlings exposed to CuO NPs, which could have caused DNA damage that was detected by a DNA laddering assay. The glucosinolate (GSL) and phenolic compound content were significantly increased in CuO NP-treated seedlings compared with that in control seedlings. Transcriptional variation of genes associated with oxidative stress (CAT, POD, and GST), R2R3-type MYB involved in GSL (BrMYB28, BrMYB29, BrMYB34, and BrMYB51), and phenolic compounds (ANS, PAP1, PAL, and FLS) biosynthesis was analyzed using real-time polymerase chain reaction. Significant upregulation of CAT, POD, GST, BrMYB28, BrMYB29, BrMYB34, BrMYB51, ANS, PAP1, PAL, and FLS genes was observed in seedlings exposed to different concentrations of CuO NPs relative to the untreated seedlings. Therefore, we suggest that the use of CuO NPs could stimulate the toxic effects and enhance phytochemicals (i.e., glucosinolates and phenolic compounds) in B. rapa.

The increasing scarcity of arable land necessitates the development of effective decontamination techniques to re-gain contaminated areas and make them suitable for agricultural and other activities. Herein, we prepare a ferromanganese binary oxide-biochar composite (FMBC) and compare its potential for remediating Cd-contaminated red soil with that of biochar (BC), showing that (i) the obtained adsorption data are well described by the Langmuir model and (ii) Cd adsorption capacity increases with increasing adsorbent dosage. Specifically, the Cd adsorption capacity of FMBC-amended soil (6.72 mg g⁻¹) is demonstrated to significantly exceed that of BC-amended red soil (4.85 mg g⁻¹) and that of the control (2.28 mg g⁻¹) and increases with increasing temperature and pH, while the results of instrumental analyses indicate that Cd sorption on the soil surface occurs via the formation of CdO and Cd(OH)₂. Thus, FMBCs are concluded to play an important role in the adsorption of Cd, having the potential to prevent red soil acidification and improve soil quality, and are found to be promising remediation materials for mitigating the risks posed by Cd-contaminated red soil.

A bibliometric method was used to evaluate the global scientific publications about sulfur oxides and nitric oxides released by coal-fired flue gas and vehicle exhaust from 1995 to 2018 and to provide insights into the characteristics of the articles and tendencies that may exist in the publications. Performance of publications, research tendency, and hotspots were analyzed. The article number had an explosive growth in 2004 and, then, began to grow steadily. China had an absolutely advantage in publication quantities; however, America had a leading position considering publication cited times. The simultaneous removal of mercury, particulate matter, and CO₂ was a research hotpot in sulfur oxide and nitric oxide control process; oxidation, absorption, and catalytic reduction were the central control methods that had the most strength in relation with sulfur dioxide and nitric oxide. Considering the study of traditional flue gas pollutant control method (limestone-gypsum method, selective catalytic reduction, etc.) was perfection, it was speculated that adsorption by ionic liquid, electricity charging, advanced oxidation progress, and multi-pollutant removal, simultaneously, would be the new research orientation in flue gas pollutant control. One of the hot points of controlling the vehicle exhaust was the application of the “green energy” biodiesel; lots of keywords concerning human health suggested that quite a lot studies were focused on the health hazard brought by sulfur oxides and nitric oxide.

The aims of this study were to analyze biochemical and morphological responses (glutathione S-transferase activity and branchial lesions) in Ucides cordatus (crabs) and to verify how the species is responding to environmental contamination in a port (potentially contaminated area) and mangrove (reference area; Amazon Coast, Maranhão, Brazil). Adult males were captured bimonthly for a period of 1 year. Higher GST activity (1.03 ± 0.07 μmol min⁻¹ mg protein⁻¹) was observed in crabs in the port when compared with those in the reference area (p < 0.05). The greatest number of branchial lesions (serious alterations) was recorded in crabs only in the port area. The GST activity increased until serious lesions appeared; after this limit, GST activity decreased dramatically to very low levels, thus resulting in irreversible lesions (lamella collapse). The mathematical model based on the two parameters evaluated in U. cordatus showed that the port area experienced substantial contamination impact, while the mangroves (reference area) presented moderate environmental quality.

Particle-induced x-ray emission (PIXE) spectroscopy has been used to characterize soil samples from two relatively old gold mine sites (Iperindo and Itagunmodi) in the Ilesha schist belt of Southwestern Nigeria. This is with a view to identifying the indicator or pathfinder elements of gold for fingerprinting and toxicity potential assessment purposes. Average elemental concentrations of 19 major, minor, and trace elements were determined, and the geochemical data of Mn, Ni, Cu, Zn, Ag, As, Pb, and Au together with multivariate factor and cluster statistical analyses allowed to identify As and Ag as the pathfinder elements of gold. The high concentration of the determined pathfinder elements (As and Ag) as well as other toxic metals (Pb and Cu) implies a relatively high metal contamination risk to the miners and the ecosystem. The major hazard is represented by the abandoned mining wastes, pits, and ponds, already serving as fish ponds.

The quantification of heavy metal contents in soils and their sources are essential for contamination monitoring and the assessment of the potential risks to the ecosystems. This study aims to investigate the source of heavy metals and other elements in soils from a uranium-phosphate deposit using integrated multivariate and geostatistics techniques. For this, 50 soil samples in Itataia deposit, Northeastern, Brazil, were collected at 0–0.2-m depth for the determination of U, Fe, Al, Mn, Ti, Zn, Cu, Ni, Mo, Co, Cr, Cd, Pb, As, Se, V, B, and Zr. The Pb, Se, Ni, Cr, As, and Mo mean contents were closer or exceeded The Brazilian Environmental Council (CONAMA) prevention values for soils. Uranium content was about 500 times higher than the mean levels reported for Brazilian soils. The cluster analysis indicates three geochemical groups based on different contamination levels. The first principal component was associated with lithological origin, the second principal component may be related to anthropogenic sources, and the third and fourth principal components indicated a joined source (natural and anthropogenic), indicating different sources of contamination. Mo was not related to other heavy metals, being found independent in the area. The accumulation of heavy metals in soils is associated not only with the parent material but also with the minerals of the soil. In the area of study, calcareous soils favored alkaline conditions that influenced the dynamics of heavy metals. The multivariate and geostatistical analyses were able to provide preliminary information regarding the metal contents in soil for environmental management.

Polycyclic aromatic hydrocarbons (PAHs) are toxic organic pollutants and omnipresent in the aquatic and terrestrial ecosystems. A high-efficient pyrene-degrading strain CP13 was isolated from activated sludge and identified as Mycobacterium gilvum based on the analysis of 16S rRNA gene sequence. More than 95% of pyrene (50 mg L⁻¹) was removed by CP13 within 7 days under the alkaline condition. Pyrene metabolites, including 4-phenanthrenecarboxylic acid, 4-phenanthrenol, 1-naphthol, and phthalic acid, were detected and characterized by GC-MS. Results suggested that pyrene was initially attacked at positions C-4 and C-5, then followed by ortho cleavage, and further degraded following the phthalate metabolic pathway. Analysis of pyrene-induced proteins showed that the extradiol dioxygenase, a key enzyme involved in pyrene degradation, was highly up-regulated in pH 9 incubation condition, which illustrated the high efficiency of CP13 under alkaline environment. The present study demonstrated that the isolated bacterial strain CP13 is a good candidate for bioremediation of alkaline PAH-contaminated sites.

The Sub-Saharan Africa (SSA) is far lag behind the sustainable targets that set out in the United Nation’s Sustainable Development Goals (SDGs), which is highly needed to embark the priorities by their member countries to devise sustainable policies for accessing clean technologies, energy demand, finance, and food production to mitigate high-mass carbon emissions and conserve environmental agenda in the national policy agenda. The study evaluated United Nation’s SDGs for environmental conservation and emission reduction in the panel of 35 selected SSA countries, during a period of 1995–2016. The study further analyzed the variable’s relationship in inter-temporal forecasting framework for the next 10 years’ time period, i.e., 2017–2026. The parameter estimates for the two models, i.e., CO₂ model and PM₂.₅ models are analyzed by Generalized Method of Moment (GMM) estimator that handle possible endogeneity issue from the given models. The results rejected the inverted U-shaped Environmental Kuznets Curve (EKC) for CO₂ emissions, while it supported for PM₂.₅ emissions with a turning point of US$5540 GDP per capita in constant 2010 US$. The results supported the “pollution haven hypothesis” for CO₂ emissions, while this hypothesis is not verified for PM₂.₅ emissions. The major detrimental factors are technologies, FDI inflows, and food deficit that largely increase carbon emissions in a panel of SSA countries. The IPAT hypothesis is not verified in both the emissions; however, population density will largely influenced CO₂ emissions in the next 10 years’ time period. The PM₂.₅ emissions will largely be influenced by high per capita income, followed by trade openness, and technologies, over a time horizon. Thus, the United Nation’s sustainable development agenda is highly influenced by socio-economic and environmental factors that need sound action plans by their member countries to coordinate and collaborate with each other and work for Africa’s green growth agenda.