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Environmental processes and fate of PAHs at a shallow and enclosed bay: West Nanao Bay, Noto Peninsula, Japan
2022
Mundo, Rodrigo | Matsunaka, Tetsuya | Iwai, Hisanori | Ochiai, Shinya | Nagao, Seiya
From August 2019 to August 2020, particulate and dissolved polycyclic aromatic hydrocarbons concentrations (PAHs) were analyzed in the water body of West Nanao Bay, Japan, to determinate their levels, environmental pathways, and ecological risks at this remote but shallow and semi-enclosed bay. The 14 targeted PAHs were analyzed by high performance liquid chromatography-fluorescence detector. Even when water column stratifies, the summatory of 14 targeted dissolved PAHs did not follow significantly change with depth. Results agreed with our previous findings in the surface distribution at the bay and can be attributed to long retention time of the water mass of the semi-enclosed bay. Suspended solids start precipitating according to their size; with biggest particles rapidly settling in the proximities of river mouths. Partition coefficients (Kp) varied from 10³ to 10⁷, according to molecular weights. In general, highest Kp were found in the nepheloid layer. The risk quotients, RQ∑₁₄ PAHₛ ₍NCₛ₎ (1.04–174.08), indicated that PAHs represented a very low to low environmental risks.
显示更多 [+] 显示较少 [-]Seasonal distribution and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in surface sediments from the Giresun coast of southeastern Black Sea
2022
Tepe, Yalçın | Aydın, Handan | Ustaoğlu, Fikret | Kaya, Serdal
Seasonal sediment samples were collected along the Giresun coastline of southeastern Black Sea and analyzed to detect the levels of 16 polycyclic aromatic hydrocarbons (PAHs). The PAH levels, ranging from 28.47 to 444.36 ng g⁻¹ with the mean of 102.57 ng g⁻¹ remained lower than those detected in most of the other sediment studies conducted worldwide. The percentage of three-ring PAHs (38.9%) was rather high, followed by that of 5-ring PAHs (21.8%). Detection rates revealed that PAHs in surface sediments along the Giresun coastline are mainly associated with coal combustion and local emissions. The evaluation with sediment quality guidelines (SQGs) showed that the level of PAHs was comparable to that at which the risk of adverse biological effects cannot be ruled out (≥TEL and <PEL) in some stations. The risk posed by PAHs in Giresun coastal sediments appears to be low to moderate ecological risk according to the risk quotient.
显示更多 [+] 显示较少 [-]Distribution of natural and anthropogenic radionuclides and associated radiation indices in the Southwestern coastline of Caspian Sea
2022
Abbasi, Akbar | Algethami, Merfat | Bawazeer, Omemh | Zakaly, Hesham M.H.
The distribution pattern of natural radionuclides (²²⁶Ra, ²³²Th, and ⁴⁰K) and anthropogenic radionuclide (¹³⁷Cs) in surface sediment samples from the southwestern coastline of the Caspian Sea were determined to estimate the radiation hazard indices using a high-purity germanium HPGe gamma-ray detector. The activity concentrations of the sediment samples ranged from 22.5 ± 1.0 to 47.4 ± 2.2 Bq kg⁻¹ dry weight (dw) for ²²⁶Ra, 6.5 ± 0.1 to 18.7 ± 0.7 Bq kg⁻¹ dw for ²³²Th, 559.9 ± 30.9 to 233.2 ± 19.4 Bq kg⁻¹ dw for ⁴⁰K, and 0.9 MDL (minimum detection limit) to 2.7 ± 0.1 Bq kg⁻¹ dw for ¹³⁷Cs. Based on the measured values, radiological risk indices were estimated. The mean values for absorbed dose rate, ambient dose equivalent rate, and excess lifetime cancer risk, were calculated as 35.7 nGy h⁻¹, 47.9 nSv h⁻¹, and 0.2, respectively.
显示更多 [+] 显示较少 [-]Is it up to business, governments, or individuals to tackle the marine plastic problem? A hybrid mixed logit approach
2022
Meginnis, Keila | Domanski, Adam | Toledo-Gallegos, Valeria M.
Marine plastic pollution is one of the most talked about environmental issues of our time. While marine plastic pollution generally originates from mismanaged waste from land, waste from ships and fishing gear produce a unique threat to the global seas. Using a choice experiment, we explore preference for a marine debris removal and prevention programme focusing on derelict fishing gear. Additionally, we explore preferences for increasing removal efforts of debris in the North Western Hawaiian Islands. We find overwhelming support for these interventions; however, we find evidence that change, and therefore subsequent action, is strongest for individuals who believe that governments hold the majority of the responsibility for reducing and cleaning plastic pollution in marine environments.
显示更多 [+] 显示较少 [-]Ecological risks assessment of sulfur and heavy metals in sediments in a historic mariculture environment, North Yellow Sea
2022
Yi, So-yŏn | Ma, Tao | Sheng, Yanqing
The environment behaviors of sulfur and heavy metals in sediments are closely related to sediment aging in mariculture area. In this study, the distributions and ecological risks of reduced inorganic sulfur (RIS) and heavy metals were investigated, along with the relationships between different occurrences of RIS and heavy metals. The results indicated that the adequate organic matter in mariculture sediments significantly enhanced the accumulation of acid volatile sulfur (AVS) compared to the control area. In shellfish farming area, biological sedimentation contributed to accumulation of AVS. The chromium (II)-reducible sulfur (CRS) was the main component of RIS in mariculture area. The environmental risks of heavy metals in mariculture area presented low levels. Principal component analysis (PCA) showed that distribution of Cu closely related to mariculture activities compared to other heavy metals. For ecological risks of heavy metals, the ratio of ∑(acid-soluble fraction (F1) + reducible fraction (F2) + oxidizable fraction (F3))/AVS was the appropriate index rather than conventional simultaneous extraction of heavy metals (SEM)/AVS, because SEM/AVS would overestimate the toxicity of heavy metals. AVS/RIS ratios significantly positively correlated with Pb (F2/(F1 + F2 + F3 + residual fraction (F4)), F2/∑F), Pb (F3/∑F), and Zn (F3/∑F), while significantly negatively correlated with Pb (F4/∑F) and Cu (F1/∑F). These results indicated that the accumulation of AVS during the mariculture process was conducive to the formation of F2 and F3 of Pb, and F3 of Zn, conversely to the formation for F4 of Pb and F1 of Cu, because it was opposite to the accumulation of CRS.
显示更多 [+] 显示较少 [-]Potentially hazardous metals in the sediment of a subtropical bay in South China: Spatial variability, contamination assessment and source apportionment
2022
Wang, Weili | Lin, Cai | Wang, Lingqing | Liu, Yang | Sun, Xiuwu | Chen, Jinmin | Lin, Hui
Potentially hazardous metals (PHMs) in the coastal environment have become a great concern due to their easy bioaccumulation, poor biodegradability and high toxicity. Surface sediment samples were collected in a subtropical bay in South China to analyse the spatial variations, contamination level and potential sources of PHMs. The results indicated that the order of average contents of PHMs in Qinzhou Bay sediment was Zn > Pb > Cr > Cu > As > Hg > Cd. The most important potential ecological risk factor was Hg pollution in the Qinzhou Bay sediments. The positive matrix factorization (PMF) model results indicated that Cu, Pb, Zn, Cd and Cr mainly originated from natural sources while Hg and As were related to coal fired industrial inputs and petroleum production activities. The results could provide a basis for marine management to formulate relevant pollution prevention and control measures.
显示更多 [+] 显示较少 [-]Influence of seasonal variations on the distribution characteristics of microplastics in the surface water of the Inner Gulf of Thailand
2022
Vibhatabandhu, Pathompong | Srithongouthai, Sarawut
This study collected 100–1000 L of surface water from 70 to 74 sites in the Inner Gulf of Thailand in both dry and wet seasons to investigate the relationship between the spatiotemporal distribution of microplastics and environmental variables. The quantity of microplastics in the wet season (34.59 ± 46.02 pieces/L) was significantly higher than the dry season (8.70 ± 15.34 pieces/L). Spatial distribution revealed an abundance of microplastics in river estuaries and seasonal current circulations. Polymeric characterization results showed that the plastic samples primarily consisted of polypropylene and polyethylene. New functional groups, including carbonyl, hydroxyl, and vinyl groups, were found in the chemical structures of the microplastic samples. The amount of freshwater runoff and the negative relationship with salinity confirmed that the river is the key factor in the transportation of microplastics to the coastal sea.
显示更多 [+] 显示较少 [-]Assessment of heavy metal distribution in seawater of Kakinada Bay, a tropical mangrove-rich coastal environment
2022
Avvari, Lovaraju | Basuri, Charan Kumar | Hari Krishna Chari, N.V. | Tirukkovalluri, Siva Rao | Gollapalli, Nageswara Rao
The main objective of the present study is to estimate the heavy metal concentrations and ecological risk index (ERI) in the seawater of Kakinada Bay. Turbidity, suspended particulate matter (SPM), pH, salinity, dissolved oxygen, along with heavy metals were recorded from twelve locations of the Bay to understand its hydrographical conditions. The distribution of environmental variables and heavy metal concentrations was noticed mostly from the south to north gradient. Significant positive correlations were detected in some pairs of metals such as Cu with Zn (R² = 0.515; p < 0.05), Pb with both Cr (R² = 0.810; p < 0.01) and Cd (R² = 0.511; p < 0.05), and Cr with Ni (R² = 0.573; p < 0.05) indicating their common origin. The ERI values (7.93–35.2) of seawater of Kakinada Bay in the present study were in the ecologically high-risk category. Industrial operations, domestic sewage, and natural processes are the major contaminant sources of Kakinada Bay leading its environment to a potential ecological concern.
显示更多 [+] 显示较少 [-]Tracking the exposure of a pelagic seabird to marine plastic pollution
2022
Blanco, Gabriela S. | Tonini, Mariano H. | Gallo, Luciana | Dell'Omo, Giacomo | Quintana, Flavio
We aimed to describe how debris originated from coastal cities and fisheries circulates and accumulates along the Argentine continental shelf and its potential interaction with southern giant petrels (SGP, Macronectes giganteus). We used tracking data of 31 SGPs (adults and juveniles) from Patagonian colonies. Lagrangian simulations of particles were released from coastal cities and fisheries. Oceanographic features together with plastic input generated a corridor of debris through the Argentine shelf with areas of high debris accumulation, exposing SGP to plastic consumption. During chick provisioning trips 93.9% of petrel's locations overlapped with areas of plastic accumulation. Although early developmental stages were more exposed to particles from cities, the exposure of petrels (all classes) to debris from fisheries was 10% higher than from cities. Measures to reduce debris from fisheries, would reduce plastic ingestion by giant petrels. Proper management of open sky dumpsters would reduce plastic consumption by chicks and juveniles.
显示更多 [+] 显示较少 [-]Size dependent egestion of polyester fibres in the Dublin Bay Prawn (Nephrops norvegicus)
2022
Joyce, Haleigh | Nash, Róisín | Kavanagh, Fiona | Power, Thomas | White, Jonathan | Frias, João
Microplastics (MPs) are an extensive global contaminant in the marine environment, known to be ingested by marine organisms. The presence of MPs in the commercially important marine decapod crustacean Nephrops norvegicus (Dublin Bay Prawn) has been documented for the North-East Atlantic and the Mediterranean, however, uncertainties remain about retention times of MPs in the gastrointestinal tract (GIT) of this species. This study aims to investigate the retention times of polyester MP fibres of three sizes (3, 5, and 10 mm in length) and to determine whether the egestion of MP fibres is size and time dependent. Results suggest that MP fibres of different lengths are retained for different periods of time, with larger MP fibres being retained for longer periods (e.g., minimum 96 h for 10 mm fibres). The present study also assesses for the first time, the size dependent relationship of MP fibres under controlled conditions for N. norvegicus.
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